78 research outputs found

    Self-stresses and Crack Formation by Particle Swelling in Cohesive Granular Media

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    We present a molecular dynamics study of force patterns, tensile strength and crack formation in a cohesive granular model where the particles are subjected to swelling or shrinkage gradients. Non-uniform particle size change generates self-equilibrated forces that lead to crack initiation as soon as strongest tensile contacts begin to fail. We find that the coarse-grained stresses are correctly predicted by an elastic model that incorporates particle size change as metric evolution. The tensile strength is found to be well below the theoretical strength as a result of inhomogeneous force transmission in granular media. The cracks propagate either inward from the edge upon shrinkage and outward from the center upon swelling

    Lithium isotope evidence for enhanced weathering and erosion during the Paleocene-Eocene Thermal Maximum

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    The Paleocene-Eocene Thermal Maximum (PETM; ~55.9 Ma) was a geologically rapid warming period associated with carbon release, which caused a marked increase in the hydrological cycle. Here, we use lithium (Li) isotopes to assess the global change in weathering regime, a critical carbon drawdown mechanism, across the PETM. We find a negative Li isotope excursion of ~3ā€° in both global seawater (marine carbonates) and in local weathering inputs (detrital shales). This is consistent with a very large delivery of clays to the oceans or a shift in the weathering regime toward higher physical erosion rates and sediment fluxes. Our seawater records are best explained by increases in global erosion rates of ~2Ɨ to 3Ɨ over 100 ka, combined with model-derived weathering increases of 50 to 60% compared to prewarming values. Such increases in weathering and erosion would have supported enhanced carbon burial, as both carbonate and organic carbon, thereby stabilizing climate

    Lithium isotope evidence for enhanced weathering and erosion during the Paleocene-Eocene Thermal Maximum

    Get PDF
    The Paleocene-Eocene Thermal Maximum (PETM; ~55.9 Ma) was a geologically rapid warming period associated with carbon release, which caused a marked increase in the hydrological cycle. Here, we use lithium (Li) isotopes to assess the global change in weathering regime, a critical carbon drawdown mechanism, across the PETM. We find a negative Li isotope excursion of ~3ā€° in both global seawater (marine carbonates) and in local weathering inputs (detrital shales). This is consistent with a very large delivery of clays to the oceans or a shift in the weathering regime toward higher physical erosion rates and sediment fluxes. Our seawater records are best explained by increases in global erosion rates of ~2Ɨ to 3Ɨ over 100 ka, combined with model-derived weathering increases of 50 to 60% compared to prewarming values. Such increases in weathering and erosion would have supported enhanced carbon burial, as both carbonate and organic carbon, thereby stabilizing climate

    Response time variability and response inhibition predict affective problems in adolescent girls, not in boys: the TRAILS study

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    The present study examines the relationship between neurocognitive functioning and affective problems through adolescence, in a cross-sectional and longitudinal perspective. Baseline response speed, response speed variability, response inhibition, attentional flexibility and working memory were assessed in a cohort of 2,179 adolescents (age 10ā€“12Ā years) from the TRacking Adolescentsā€™ Individual Lives Survey (TRAILS). Affective problems were measured with the DSM-oriented Affective Problems scale of the Youth Self Report at wave 1 (baseline assessment), wave 2 (after 2.5Ā years) and wave 3 (after 5Ā years). Cross-sectionally, baseline response speed, response time variability, response inhibition and working memory were associated with baseline affective problems in girls, but not in boys. Longitudinally, enhanced response time variability predicted affective problems after 2.5 and 5Ā years in girls, but not in boys. Decreased response inhibition predicted affective problems after 5Ā years follow-up in girls, and again not in boys. The results are discussed in light of recent insights in gender differences in adolescence and stateā€“trait issues in depression

    Mass Spectrometric Sampling of a Liquid Surface by Nanoliter Droplet Generation from Bursting Bubbles and Focused Acoustic Pulses: Application to Studies of Interfacial Chemistry

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    Organic Constituents on the Surfaces of Aerosol Particles from Southern Finland, Amazonia, and California Studied by Vibrational Sum Frequency Generation

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