45 research outputs found
Neutron-Diffraction Measurements of an Antiferromagnetic Semiconducting Phase in the Vicinity of the High-Temperature Superconducting State of KFeSe
The recently discovered K-Fe-Se high temperature superconductor has caused
heated debate regarding the nature of its parent compound. Transport,
angle-resolved photoemission spectroscopy, and STM measurements have suggested
that its parent compound could be insulating, semiconducting or even metallic
[M. H. Fang, H.-D. Wang, C.-H. Dong, Z.-J. Li, C.-M. Feng, J. Chen, and H. Q.
Yuan, Europhys. Lett. 94, 27009 (2011); F. Chen et al. Phys. Rev. X 1, 021020
(2011); and W. Li et al.,Phys. Rev. Lett. 109, 057003 (2012)]. Because the
magnetic ground states associated with these different phases have not yet been
identified and the relationship between magnetism and superconductivity is not
fully understood, the real parent compound of this system remains elusive.
Here, we report neutron-diffraction experiments that reveal a semiconducting
antiferromagnetic (AFM) phase with rhombus iron vacancy order. The magnetic
order of the semiconducting phase is the same as the stripe AFM order of the
iron pnictide parent compounds. Moreover, while the root5*root5 block AFM phase
coexists with superconductivity, the stripe AFM order is suppressed by it. This
leads us to conjecture that the new semiconducting magnetic ordered phase is
the true parent phase of this superconductor.Comment: 1 table, 4 figures,5 page
Universal magnetic and structural behaviors in the iron arsenides
Commonalities among the order parameters of the ubiquitous antiferromagnetism
present in the parent compounds of the iron arsenide high temperature
superconductors are explored. Additionally, comparison is made between the well
established two-dimensional Heisenberg-Ising magnet, KNiF and iron
arsenide systems residing at a critical point whose structural and magnetic
phase transitions coincide. In particular, analysis is presented regarding two
distinct classes of phase transition behavior reflected in the development of
antiferromagnetic and structural order in the three main classes of iron
arsenide superconductors. Two distinct universality classes are mirrored in
their magnetic phase transitions which empirically are determined by the
proximity of the coupled structural and magnetic phase transitions in these
materials.Comment: 6 pages, 4 figure
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Development of ZnO:Ga as an Ultrafast Scintillator
We report on several methods for synthesizing the ultra-fast scintillator ZnO(Ga), and measurements of the resulting products. This material has characteristics that make it an excellent alpha detector for tagging the time and direction of individual neutrons produced by t-d and d-d neutron generators (associated particle imaging). The intensity and decay time are strongly dependent on the method used for dopant incorporation. We compare samples made by diffusion of Ga metal to samples made by solid state reaction between ZnO and Ga2O3 followed by reduction in hydrogen. The latter is much more successful and has a pure, strong near-band-edge fluorescence and an ultra-fast decay time of the x-ray-excited luminescence. The luminescence increases dramatically as the temperature is reduced to 10K. We also present results of an alternate low-temperature synthesis that produces luminescent particles with a more uniform size distribution. We examine possible mechanisms for the bright near-band-edge scintillation and favor the explanation that it is due to the recombination of Ga3+ donor electrons with ionization holes trapped on H+ ion acceptors
Structural and Antiferromagnetic Properties of Ba(Fe1−x−yCoxRhy)2As2 compounds
We present a systematic investigation of the electrical, structural, and antiferromagnetic properties for the series of Ba(Fe1 −x−yCoxRhy)2As2 compounds with fixed x ≈ 0.027 and 0 ≤ y ≤ 0.035. We compare our results for the Co-Rh doped Ba(Fe1−x−yCoxRhy)2As2 compounds with the Co doped Ba(Fe1−xCox)2As2 compounds. We demonstrate that the electrical, structural, antiferromagnetic, and superconducting properties of the Co-Rh doped compounds are similar to the properties of the Co doped compounds. We find that the overall behaviors of Ba(Fe1−x−yCoxRhy)2As2 and Ba(Fe1−xCox)2As2 compounds are very similar when the total number of extra electrons per Fe/TM (TM=transition metal) site is considered, which is consistent with the rigid band model. Despite the similarity, we find that the details of the transitions, for example, the temperature difference between the structural and antiferromagnetic transition temperatures and the incommensurability of the antiferromangetic peaks, are different between Ba(Fe1−x−yCoxRhy)2As2 and Ba(Fe1−xCox)2As2 compounds
The nature of the magnetic and structural phase transitions in BaFeAs
We present the results of an investigation of both the magnetic and
structural phase transitions in a high quality single crystalline sample of the
undoped, iron pnictide compound BaFeAs. Both phase transitions are
characterized via neutron diffraction measurements which reveal simultaneous,
continuous magnetic and structural orderings with no evidence of hysteresis,
consistent with a single second order phase transition. The onset of long-range
antiferromagnetic order can be described by a simple power law dependence
with ; a
value near the expected for a two-dimensional Ising system.
Biquadratic coupling between the structural and magnetic order parameters is
also inferred along with evidence of three-dimensional critical scattering in
this system.Comment: New figure and discussion added. Length: 11 pages, 7 figure
Antiferromagnetic Critical Fluctuations in BaFeAs
Magnetic correlations near the magneto-structural phase transition in the
bilayer iron pnictide parent compound, BaFeAs, are measured. In close
proximity to the antiferromagnetic phase transition in BaFeAs, a
crossover to three dimensional critical behavior is anticipated and has been
preliminarily observed. Here we report complementary measurements of
two-dimensional magnetic fluctuations over a broad temperature range about
T. The potential role of two-dimensional critical fluctuations in the
magnetic phase behavior of BaFeAs and their evolution near the
anticipated crossover to three dimensional critical behavior and long-range
order are discussed.Comment: 6 pages, 4 figures; Accepted for publication in Physical Review
Magnetic order tuned by Cu substitution in Fe1.1-zCuzTe
We study the effects of Cu substitution in Fe1.1Te, the non-superconducting
parent compound of the iron-based superconductor, Fe1+yTe1-xSex, utilizing
neutron scattering techniques. It is found that the structural and magnetic
transitions, which occur at \sim 60 K without Cu, are monotonically depressed
with increasing Cu content. By 10% Cu for Fe, the structural transition is
hardly detectable, and the system becomes a spin glass below 22 K, with a
slightly incommensurate ordering wave vector of (0.5-d, 0, 0.5) with d being
the incommensurability of 0.02, and correlation length of 12 angstrom along the
a axis and 9 angstrom along the c axis. With 4% Cu, both transition
temperatures are at 41 K, though short-range incommensurate order at (0.42, 0,
0.5) is present at 60 K. With further cooling, the incommensurability decreases
linearly with temperature down to 37 K, below which there is a first order
transition to a long-range almost-commensurate antiferromagnetic structure. A
spin anisotropy gap of 4.5 meV is also observed in this compound. Our results
show that the weakly magnetic Cu has large effects on the magnetic
correlations; it is suggested that this is caused by the frustration of the
exchange interactions between the coupled Fe spins.Comment: 7 pages, 7 figures, version as appeared on PR
Bandwidth and Electron Correlation-Tuned Superconductivity in RbFe(SeS)
We present a systematic angle-resolved photoemission spectroscopy study of
the substitution-dependence of the electronic structure of
RbFe(SeS) (z = 0, 0.5, 1), where
superconductivity is continuously suppressed into a metallic phase. Going from
the non-superconducting RbFe(SeS) to
superconducting RbFeSe, we observe little change of the Fermi
surface topology, but a reduction of the overall bandwidth by a factor of 2 as
well as an increase of the orbital-dependent renormalization in the
orbital. Hence for these heavily electron-doped iron chalcogenides, we have
identified electron correlation as explicitly manifested in the quasiparticle
bandwidth to be the important tuning parameter for superconductivity, and that
moderate correlation is essential to achieving high