Electrochemical generation of oxygen. 1: The effects of anions and cations on hydrogen chemisorption and anodic oxide film formation on platinum electrode. 2: The effects of anions and cations on oxygen generation on platinum electrode

The effects were studied of anions and cations on hydrogen chemisorption and anodic oxide film formation on Pt by linear sweep voltammetry, and on oxygen generation on Pt by potentiostatic overpotential measurement. The hydrogen chemisorption and anodic oxide film formation regions are greatly influenced by anion adsorption. In acids, the strongly bound hydrogen occurs at more cathodic potential when chloride and sulfate are present. Sulfate affects the initial phase of oxide film formation by produced fine structure while chloride retards the oxide-film formation. In alkaline solutions, both strongly and weakly bound hydrogen are influenced by iodide, cyanide, and barium and calcium cations. These ions also influence the oxide film formation. Factors considered to explain these effects are discussed. The Tafel slope for oxygen generation was found to be independent on the oxide thickness and the presence of cations or anions. The catalytic activity indicated by the exchange current density was observed decreasing with increasing oxide layer thickness, only a minor dependence on the addition of certain cations and anions was found

Convective flow during dendritic growth

A review is presented of the major experimental findings obtained from recent ground-based research conducted under the SPAR program. Measurements of dendritic growth at small supercoolings indicate that below approximately 1.5 K a transition occurs from diffusive control to convective control in succinonitrile, a model system chosen for this study. The key theoretical ideas concerning diffusive and convective heat transport during dendritic growth are discussed, and it is shown that a transition in the transport control should occur when the characteristic length for diffusion becomes larger than the characteristic length for convection. The experimental findings and the theoretical ideas discussed suggest that the Fluid Experiment System could provide appropriate experimental diagnostics for flow field visualization and quantification of the fluid dynamical effects presented here

Gamma-Rays Produced in Cosmic-Ray Interactions and the TeV-band Spectrum of RX J1713.7-3946

We employ the Monte Carlo particle collision code DPMJET3.04 to determine the multiplicity spectra of various secondary particles (in addition to $\pi^0$'s) with $\gamma$'s as the final decay state, that are produced in cosmic-ray ($p$'s and $\alpha$'s) interactions with the interstellar medium. We derive an easy-to-use $\gamma$-ray production matrix for cosmic rays with energies up to about 10 PeV. This $\gamma$-ray production matrix is applied to the GeV excess in diffuse Galactic $\gamma$-rays observed by EGRET, and we conclude the non-$\pi^0$ decay components are insufficient to explain the GeV excess, although they have contributed a different spectrum from the $\pi^0$-decay component. We also test the hypothesis that the TeV-band $\gamma$-ray emission of the shell-type SNR RX J1713.7-3946 observed with HESS is caused by hadronic cosmic rays which are accelerated by a cosmic-ray modified shock. By the $\chi^2$ statistics, we find a continuously softening spectrum is strongly preferred, in contrast to expectations. A hardening spectrum has about 1% probability to explain the HESS data, but then only if a hard cutoff at 50-100 TeV is imposed on the particle spectrum.Comment: 3 pages; 4 figures; Contribution to the First GLAST Symposium, Standord, 200

GEOS-3 ocean current investigation using radar altimeter profiling

Both quasi-stationary and dynamic departures from the marine geoid were successfully detected using altitude measurements from the GEOS-3 radar altimeter. The quasi-stationary departures are observed either as elevation changes in single pass profiles across the Gulf Stream or at the crowding of contour lines at the western and northern areas of topographic maps generated using altimeter data spanning one month or longer. Dynamic features such as current meandering and spawned eddies can be monitored by comparing monthly mean maps. Comparison of altimeter inferred eddies with IR detected thermal rings indicates agreement of the two techniques. Estimates of current velocity are made using derived slope estimates in conjunction with the geostrophic equation

Life Tables of Bactrocera cucurbitae (Coquillett) (Diptera: Tephritidae): with a Mathematical Invalidation for Applying the Jackknife Technique to the Net Reproductive Rate

Life table data for the melon fly, Bactrocera cucurbitae (Coquillett), reared on cucumber (Cucumis sativus L.) were collected under laboratory and simulated field conditions. Means and standard errors of life table parameters were estimated for two replicates using the jackknife technique. At 25ºC, the intrinsic rates of increase (_r_) found for the two replicates were 0.1354 and 0.1002 day-1, and the net reproductive rates (_R_~0~) were 206.3 and 66.0 offspring, respectively. When the cucumbers kept under simulated field conditions were covered with leaves, the _r_ and _R_~0~ for the two replicates were 0.0935 and 0.0909 day-1, 17.5 and 11.4 offspring, respectively. However, when similar cucumbers were left uncovered, the _r_ and _R_~0~ for the two replicates were 0.1043 and 0.0904 day-1, and 27.7 and 10.1 offspring, respectively. Our results revealed that considerable variability between replicates in both laboratory and field conditions is possible; this variability should be taken into consideration in data collection and application of life tables. Mathematical analysis has demonstrated that applying the jackknife technique results in unrealistic pseudo-_R_~0~ and overestimation of its variance. We suggest that the jackknife technique should not be used for the estimation of variability of _R_~0~

S-wave quantum entanglement in a harmonic trap

We analyze the quantum entanglement between two interacting atoms trapped in a spherical harmonic potential. At ultra-cold temperature, ground state entanglement is generated by the dominated s-wave interaction. Based on a regularized pseudo-potential Hamiltonian, we examine the quantum entanglement by performing the Schmidt decomposition of low-energy eigenfunctions. We indicate how the atoms are paired and quantify the entanglement as a function of a modified s-wave scattering length inside the trap.Comment: 10 pages, 5 figures, to be apear in PR