281 research outputs found
Effect of Sr substitution on superconductivity in Hg2(Ba1-ySry)2YCu2O8-d (part2): bond valence sum approach of the hole distribution
The effects of Sr substitution on superconductivity, and more particulary the
changes induced in the hole doping mechanism, were investigated in
Hg2(Ba1-ySry)2YCu2O8-d by a "bond valence sum" analysis with Sr content from y
= 0.0 to y = 1.0. A comparison with CuBa2YCu2O7-d and Cu2Ba2YCu2O8 systems
suggests a possible explanation of the Tc enhancement from 0 K for y = 0.0 to
42 K for y = 1.0. The charge distribution among atoms of the unit cell was
determined from the refined structure, for y = 0.0 to 1.0. It shows a charge
transfer to the superconducting CuO2 plane via two doping channels pi(1) and
pi(2), i.e. through O2(apical)-Cu and Ba/Sr-O1 bonds respectively.Comment: 13 pages, 5 figures, accepted for publication in Journal of Physics:
Condensed Matte
Dopant-dependent impact of Mn-site doping on the critical-state manganites: R0.6Sr0.4MnO3 (R=La, Nd, Sm, and Gd)
Versatile features of impurity doping effects on perovskite manganites,
SrMnO, have been investigated with varying the doing
species as well as the -dependent one-electron bandwidth. In
ferromagnetic-metallic manganites (=La, Nd, and Sm), a few percent of Fe
substitution dramatically decreases the ferromagnetic transition temperature,
leading to a spin glass insulating state with short-range charge-orbital
correlation. For each species, the phase diagram as a function of Fe
concentration is closely similar to that for SrMnO
obtained by decreasing the ionic radius of site, indicating that Fe doping
in the phase-competing region weakens the ferromagnetic double-exchange
interaction, relatively to the charge-orbital ordering instability. We have
also found a contrastive impact of Cr (or Ru) doping on a spin-glass insulating
manganite (=Gd). There, the impurity-induced ferromagnetic magnetization is
observed at low temperatures as a consequence of the collapse of the inherent
short-range charge-orbital ordering, while Fe doping plays only a minor role.
The observed opposite nature of impurity doping may be attributed to the
difference in magnitude of the antiferromagnetic interaction between the doped
ions.Comment: 7 pages, 6 figure
3D atom probe tomography of swift heavy ion irradiated multilayers
International audienceNanometer scale layered systems are well suited to investigate atomic transport processes induced by high-energy electronic excitations in materials, through the characterization of the interface transformation. In this study, we used the atom probe technique to determine the distribution of the different elements in an (amorphous-FeTb 5 nm/hcp-Co 3 nm) multilayer before and after irradiation with Pb ions in the electronic stopping power regime. Atom probe tomography is based on reconstruction of a small volume of a sharp tip evaporated by field effect. It has unique capabilities to characterize internal interfaces and layer chemistry with sub-nanometer scale resolution in three dimensions. Depth composition profiles and 3D element mapping have been determined, evidencing for asymetric interfaces in the as-deposited sample, and very efficient Fe-Co intermixing after irradiation at the fluence ion cm. Estimation of effective atomic diffusion coefficients after irradiation suggests that mixing results from interdiffusion in a molten track across the interface in agreement with the thermal spike model
Interplay of disorder and antiferromagnetism in TlFe1.6+(Se1−xSx )2 probed by neutron scattering
International audienceThe effect of selenium substitution by sulphur on the structural and physical properties of antiferromagnetic TlFe1.6+δSe2 has been investigated via neutron, x-ray and electron diffraction, and transport measurements. The 5 sqrt(a)× 5sqrt(a)×c super-cell related to the iron vacancy ordering found in the pure TlFe1.6Se2 selenide is also present in the S-doped TlFe1.6+δ(Se1−xSx)2 compounds. Neutron scattering experiments show the occurrence of the same long range magnetic ordering in the whole series i.e. the 'block checkerboard' antiferromagnetic structure. In particular, this is the first detailed study where the crystal structure and the 5 a× 5 a antiferromagnetic structure is characterized by neutron powder diffraction for the pure TlFe1.6+δS2 sulphide over a large temperature range. We demonstrate the strong correlation between occupancies of the crystallographic iron sites, the level of iron vacancy ordering and the occurrence of block antiferromagnetism in the sulphur series. Introducing S into the Se sites also increases the Fe content in TlFe1.6+δ(Se1−xSx)2 which in turn leads to the disappearance of the Fe vacancy ordering at x = 0.5 ± 0.15. However, by reducing the nominal Fe content, the same 5 a× 5 a×c vacancy ordering and antiferromagnetic order can be recovered also in the pure TlFe1.6+δS2 sulphide with a simultaneous reduction in the Néel temperature from 435 K in the selenide TlFe1.75Se2 to 330 K in the sulphide TlFe1.5S2. The magnetic moment remains high at low temperature throughout the full substitution range, which contributes to the absence of superconductivity in these compounds
Fast and selective super-resolution ultrasound in vivo with acoustically activated nanodroplets
Perfusion by the microcirculation is key to the development, maintenance and pathology of tissue. Its measurement with high spatiotemporal resolution is consequently valuable but remains a challenge in deep tissue. Ultrasound Localization Microscopy (ULM) provides very high spatiotemporal resolution but the use of microbubbles requires low contrast agent concentrations, a long acquisition time, and gives little control over the spatial and temporal distribution of the microbubbles. The present study is the first to demonstrate Acoustic Wave Sparsely-Activated Localization Microscopy (AWSALM) and fast-AWSALM for in vivo super-resolution ultrasound imaging, offering contrast on demand and vascular selectivity. Three different formulations of acoustically activatable contrast agents were used. We demonstrate their use with ultrasound mechanical indices well within recommended safety limits to enable fast on-demand sparse activation and destruction at very high agent concentrations. We produce super-localization maps of the rabbit renal vasculature with acquisition times between 5.5 s and 0.25 s, and a 4-fold improvement in spatial resolution. We present the unique selectivity of AWSALM in visualizing specific vascular branches and downstream microvasculature, and we show super-localized kidney structures in systole (0.25 s) and diastole (0.25 s) with fast-AWSALM outdoing microbubble based ULM. In conclusion, we demonstrate the feasibility of fast and selective measurement of microvascular dynamics in vivo with subwavelength resolution using ultrasound and acoustically activatable nanodroplet contrast agents
Coulomb Explosion and Thermal Spikes
A fast ion penetrating a solid creates a track of excitations. This can
produce displacements seen as an etched track, a process initially used to
detect energetic particles but now used to alter materials. From the seminal
papers by Fleischer et al. [Phys. Rev. 156, 353 (1967)] to the present [C.
Trautmann, S. Klaumunzer and H. Trinkaus, Phys. Rev. Lett. 85, 3648 (2000)],
`Coulomb explosion' and thermal spike models are treated as conflicting models
for describing ion track effects. Here molecular dynamics simulations of
electronic-sputtering, a surface manifestation of ion track formation, show
that `Coulomb explosion' produces a `heat' spike so that these are early and
late aspects of the same process. Therefore, differences in scaling are due to
the use of incomplete spike models.Comment: Submitted to PRL. 4 pages, 3 figures. For related movies see:
http://dirac.ms.virginia.edu/~emb3t/coulomb/coulomb.html PACS added in new
versio
Electron gas polarization effect induced by heavy H-like ions of moderate velocities channeled in a silicon crystal
We report on the observation of a strong perturbation of the electron gas
induced by 20 MeV/u U ions and 13 MeV/u Pb ions channeled in
silicon crystals. This collective response (wake effect) in-duces a shift of
the continuum energy level by more than 100 eV, which is observed by means of
Radiative Electron Capture into the K and L-shells of the projectiles. We also
observe an increase of the REC probability by 20-50% relative to the
probability in a non-perturbed electron gas. The energy shift is in agreement
with calculations using the linear response theory, whereas the local electron
density enhancement is much smaller than predicted by the same model. This
shows that, for the small values of the adiabaticity parameter achieved in our
experiments, the density fluctuations are not strongly localized at the
vicinity of the heavy ions
Energy deposition by heavy ions: Additivity of kinetic and potential energy contributions in hillock formation on CaF2
The formation of nano-hillocks on CaF2 crystal surfaces by individual ion
impact has been studied using medium energy (3 and 5 MeV) highly charged ions
(Xe19+ to Xe30+) as well as swift (kinetic energies between 12 and 58 MeV)
heavy ions. For very slow highly charged ions the appearance of hillocks is
known to be linked to a threshold in potential energy while for swift heavy
ions a minimum electronic energy loss is necessary. With our results we bridge
the gap between these two extreme cases and demonstrate, that with increasing
energy deposition via electronic energy loss the potential energy threshold for
hillock production can be substantially lowered. Surprisingly, both mechanisms
of energy deposition in the target surface seem to contribute in an additive
way, as demonstrated when plotting the results in a phase diagram. We show that
the inelastic thermal spike model, originally developed to describe such
material modifications for swift heavy ions, can be extended to case where
kinetic and potential energies are deposited into the surface.Comment: 12 pages, 4 figure
- …