Modeling Light Trapping in Nanostructured Solar Cells

The integration of nanophotonic and plasmonic structures with solar cells offers the ability to control and confine light in nanoscale dimensions. These nanostructures can be used to couple incident sunlight into both localized and guided modes, enhancing absorption while reducing the quantity of material. Here we use electromagnetic modeling to study the resonances in a solar cell containing both plasmonic metal back contacts and nanostructured semiconductor top contacts, identify the local and guided modes contributing to enhanced absorption, and optimize the design. We then study the role of the different interfaces and show that Al is a viable plasmonic back contact material

Arrival processes in port modeling: insights from a case study

This paper investigates the impact of arrival processes on the ship handling process. Two types of arrival processes are considered: controlled and uncontrolled. Simulation results show that uncontrolled arrivals of ships perform worst in terms of both ship delays and required storage capacity. Stock-controlled arrivals perform best with regard to large vessel delays and storage capacity. The combination of stock-controlled arrivals for large vessels and equidistant arrivals for barges also performs better than the uncontrolled process. Careful allocation of ships to the mooring points of a jetty further improves the efficiency.supply chain management;logistics;simulation;transportation;case study

Other People’s Money: Money’s Perceived Purchasing Power Is Smaller for Others Than for the Self

Nine studies find that people believe their money has greater purchasing power than the same quantity of others’ money. Using a variety of products from socks to clocks to chocolates, we found that participants thought the same amount of money could buy more when it belonged to themselves versus others – a pattern that extended to undesirable products. Participants also believed their money – in the form of donations, taxes, fines, and fees – would help charities/governments more than others’ money. We tested six mechanisms based on psychological distance, the endowment effect, wishful thinking, better-than-average biases, pain-of-payment, and beliefs about product preferences. Only a psychological distance mechanism received support. Specifically, we found that the perceived purchasing power of other people’s money decreased logarithmically as others’ psychological distance from the self increased, consistent with psychological distance’s subadditive property. Further supporting a psychological distance mechanism, we found that framing one’s own money as distant (vs. near) reduced the self-other difference in perceived purchasing power. Our results suggest that beliefs about the value of money depend on who owns it, and we discuss implications for marketing, management, psychology, and economics

Tuning the emission wavelength of Si nanocrystals in SiO2 by oxidation

Si nanocrystals (diameter 2–5 nm) were formed by 35 keV Si + implantation at a fluence of 6 × 1016 Si/cm2 into a 100 nm thick thermally grown SiO2 film on Si (100), followed by thermal annealing at 1100 °C for 10 min. The nanocrystals show a broad photoluminescence spectrum, peaking at 880 nm, attributed to the recombination of quantum confined excitons. Rutherford backscattering spectrometry and transmission electron microscopy show that annealing these samples in flowing O2 at 1000 °C for times up to 30 min results in oxidation of the Si nanocrystals, first close to the SiO2 film surface and later at greater depths. Upon oxidation for 30 min the photoluminescence peak wavelength blueshifts by more than 200 nm. This blueshift is attributed to a quantum size effect in which a reduction of the average nanocrystal size leads to emission at shorter wavelengths. The room temperature luminescence lifetime measured at 700 nm increases from 12 µs for the unoxidized film to 43 µs for the film that was oxidized for 29 min

Loss mechanisms of surface plasmon polaritons on gold probed by cathodoluminescence imaging spectroscopy

We use cathodoluminescence imaging spectroscopy to excite surface plasmon polaritons and measure their decay length on single crystal and polycrystalline gold surfaces. The surface plasmon polaritons are excited on the gold surface by a nanoscale focused electron beam and are coupled into free space radiation by gratings fabricated into the surface. By scanning the electron beam on a line perpendicular to the gratings, the propagation length is determined. Data for single-crystal gold are in agreement with calculations based on dielectric constants. For polycrystalline films, grain boundary scattering is identified as additional loss mechanism, with a scattering coefficient SG=0.2%

Improved red-response in thin film a-Si:H solar cells with soft-imprinted plasmonic back reflectors

The impact of controlled nanopatterning on the Ag back contact of an n-i-p a-Si:H solar cell was investigated experimentally and through electromagnetic simulation. Compared to a similar reference cell with a flat back contact, we demonstrate an efficiency increase from 4.5% to 6.2%, with a 26% increase in short circuit current density. Spectral response measurements show the majority of the improvement between 600 and 800 nm, with no reduction in photocurrent at wavelengths shorter than 600 nm. Optimization of the pattern aspect ratio using electromagnetic simulation predicts absorption enhancements over 50% at 660 nm

Light trapping in ultrathin plasmonic solar cells

We report on the design, fabrication, and measurement of ultrathin film a-Si:H solar cells with nanostructured plasmonic back contacts, which demonstrate enhanced short circuit current densities compared to cells having flat or randomly textured back contacts. The primary photocurrent enhancement occurs in the spectral range from 550 nm to 800 nm. We use angle-resolved photocurrent spectroscopy to confirm that the enhanced absorption is due to coupling to guided modes supported by the cell. Full-field electromagnetic simulation of the absorption in the active a-Si:H layer agrees well with the experimental results. Furthermore, the nanopatterns were fabricated via an inexpensive, scalable, and precise nanopatterning method. These results should guide design of optimized, non-random nanostructured back reflectors for thin film solar cells

Local density of states, spectrum, and far-field interference of surface plasmon polaritons probed by cathodoluminescence

The surface plasmon polariton (SPP) field intensity in the vicinity of gratings patterned in an otherwise planar gold surface is spatially resolved using cathodoluminescence (CL). A detailed theoretical analysis is presented that successfully explains the measured CL signal based upon interference of transition radiation directly generated by electron impact and SPPs launched by the electron and outcoupled by the grating. The measured spectral dependence of the SPP yield per incoming electron is in excellent agreement with rigorous electromagnetic calculations. The CL emission is shown to be similar to that of a dipole oriented perpendicular to the surface and situated at the point of electron impact, which allows us to establish a solid connection between the CL signal and the photonic local density of states associated to the SPPs

Collectieve versus individuele contracten voor natuurbeheer

In dit onderzoek staat de vraag centraal of collectieve contracten in vergelijking met individuele contracten efficiënter zijn en/of een grotere ecologische effectiviteit hebben. Daarbij is bijzondere aandacht gegeven aan de rol die agrarische natuurverenigingen kunnen spele

Adapting Practices of Science Journalism to Foster Science Literacy

In this paper, the authors describe how the practices of expert science journalists enable them to act as \u22competent outsiders\u22 to science. We assert that selected science journalism practices can be used to design reform-based science instruction; these practices not only foster science literacy that is useful in daily life, but also complement practices of scientists that already have been incorporated into science education. We describe and illustrate science journalism practices for educational activities that can be adapted and used. We argue that such experiences enable students to better use science information for personal decision-making and help them contribute meaningfully to public discourse long after high school graduation. Finally, we describe the design of a learning environment that facilitates research and development based on this model