676 research outputs found

    Complexity reduction of astrochemical networks

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    We present a new computational scheme aimed at reducing the complexity of the chemical networks in astrophysical models, one which is shown to markedly improve their computational efficiency. It contains a flux-reduction scheme that permits to deal with both large and small systems. This procedure is shown to yield a large speed-up of the corresponding numerical codes and provides good accord with the full network results. We analyse and discuss two examples involving chemistry networks of the interstellar medium and show that the results from the present reduction technique reproduce very well the results from fuller calculations.Comment: 9 pages, 7 figures, accepted for publication in Monthly Notices of the Royal Astronomical Society Main Journa

    1-(2-Amino­eth­yl)-3-phenyl­thio­urea

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    In the crystal structure of the title compound, C9H13N3S, mol­ecules are linked through N—H⋯S and N—H⋯N hydrogen bonds, forming hydrogen-bonded tapes along the b axis. The dihedral angle between the phenyl ring and the thiourea group is 44.9 (2)°

    Post-thermal treatment of oriented strandboard (OSB) made from cypress (Cupressus Glauca Lam)

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    The objective of this research was to determine the physical and mechanical properties of oriented strandboard (OSB) using strands of Cupressus glauca Lam., before and after a thermal treatment, as well as to evaluate the susceptibility of the boards to fungi attack. Boards with nominal density of 0.70 g/cm3 were produced with 5% and 8% of urea-formaldehyde (UF) resin. Physical and mechanical properties were evaluated according to ASTM D 1037 (1991) standard and compared with CSA O437.0 and ANSI A.208.1 standards. All mechanical properties were higher than those values required by both standards, except the modulus of elasticity in parallel axis. The thermal treatment slightly reduced the modulus of elasticity and stress at proportional limit, both in perpendicular axis, however improved significantly dimensional stability. Dimensional stability of the treated OSB was improved at the lower resin level but did not reach the maximum value required by the Canadian standard. Biological assay showed that heat-treated cypress OSB exposed to P. sanguineus reduced mass loss from 39% to 50%, while for G. trabeum the reduction was from 40% to 49%. Post thermal treatment of manufactured OSB (190ºC, 720 s) can be the recommended method to reduce the hygroscopicity without great effect on mechanical properties and to protect panels against these fungi

    Transient behavior in Single-File Systems

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    We have used Monte-Carlo methods and analytical techniques to investigate the influence of the characteristics, such as pipe length, diffusion, adsorption, desorption and reaction rates on the transient properties of Single-File Systems. The transient or the relaxation regime is the period in which the system is evolving to equilibrium. We have studied the system when all the sites are reactive and when only some of them are reactive. Comparisons between Mean-Field predictions, Cluster Approximation predictions, and Monte Carlo simulations for the relaxation time of the system are shown. We outline the cases where Mean-Field analysis gives good results compared to Dynamic Monte-Carlo results. For some specific cases we can analytically derive the relaxation time. Occupancy profiles for different distribution of the sites both for Mean-Field and simulations are compared. Different results for slow and fast reaction systems and different distribution of reactive sites are discussed.Comment: 18 pages, 19 figure
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