Photon induced secondary electron emission

Numerical models for predicting photon-induced secondary electron emission are presented. The results are compared with experimental measurements made using a Co-60 gamma ray source

Work hardening behavior in a steel with multiple TRIP mechanisms

Transformation induced plasticity (TRIP) behavior was studied in steel with composition Fe-0.07C-2.85Si-15.3Mn-2.4Al-0.017N that exhibited two TRIP mechanisms. The initial microstructure consisted of both {\epsilon}- and {\alpha}-martensites with 27% retained austenite. TRIP behavior in the first 5% strain was predominately austenite transforming to {\epsilon}-martensite (Stage I), but upon saturation of Stage I, the {\epsilon}-martensite transformed to {\alpha}-martensite (Stage II). Alloy segregation also affected the TRIP behavior with alloy rich regions producing TRIP just prior to necking. This behavior was explained by first principle calculations that revealed aluminum significantly affected the stacking fault energy in Fe-Mn-Al-C steels by decreasing the unstable stacking fault energy and promoting easy nucleation of {\epsilon}-martensite. The addition of aluminum also raised the intrinsic stacking fault energy and caused the {\epsilon}-martensite to be unstable and transform to {\alpha}-martensite under further deformation. The two stage TRIP behavior produced a high strain hardening exponent of 1.4 and led to ultimate tensile strength of 1165 MPa and elongation to failure of 35%.Comment: submitted to Met. Mater. Trans. A manuscript E-TP-12-953-

Synthesis and characteristics of polyarylene ether sulfones

A method utilizing potassium carbonate/dimethyl acetamide, as base and solvent respectively, was used for the synthesis of several homopolymers and copolymers derived from various bisphenols. It is demonstrated that this method deviates from simple second order kinetics; this deviation being due to the heterogeneous nature of the reaction. Also, it is shown that a liquid induced crystallization process can improve the solvent resistance of these polymers. Finally, a Monte Carlo simulation of the triad distribution of monomers in nonequilibrium copolycondensation is discussed

Mobile target tracking using a reconfigurable low earth orbit constellation

Traditional Earth-observing satellite constellations must preselect orbits to match established mission objectives, inherently limiting the capability of the system to respond to dynamic events. A more flexible approach to constellation design which maneuvers satellites to new orbits throughout the mission lifetime can enable the tracking of mobile targets; such a concept will be explored and evaluated in the following paper. Currently, an existing approach for creating a reconfigurable constellation of satellites (ReCon) demonstrates some increased functionality. However, the repeating ground track (RGT) orbits used are only well-suited for static ground targets (i.e. particular latitude and longitude points) as they are defined by their repetitious passes over the particular points on the globe; inherently these orbits are not ideal for tracking mobile targets such as ships, oil spills, hurricanes, and other weather events. By addressing this gap and designing the constellation to follow these mobile targets, data return can be of higher quality and quantity leading toward improved predictions of future movements. Traditional non-maneuverable satellites may of course capture mobile feature data; however, the quality and quantity of data returned is driven by the satellites’ orbits which were not designed for the particular mobile target. A proposed concept of operations that models possible sequential satellite maneuvers as a graph has shown promise for tracking mobile targets in the case of a single satellite. In the following paper, this concept is further explored by the addition of an optimizer to this method, applied to both a single satellite and a constellation of maneuverable satellites, like ReCon. Results for a tropical storm case study indicate that with relatively low amounts of delta-V per satellite, many possible maneuver combinations are found which result in improved accesses with greater total access time and closer passes. Trade-offs are shown between total target access time, mean distance to targets upon access, and total delta-V used. The performance of increased constellation size is also explored. By having satellites dynamically respond to mobile targets such as hurricanes, satellite imagery and remote sensing can be of better quality and even contribute to better predictions for developing storms

Looking back: Insider views on the Judicial Inspectorate for Correctional Services

The establishment of a constitutional democracy in South Africa necessitated widespread institutional reforms across state sectors. A key feature of such reforms was the emphasis on oversight and accountability as illustrated in reform endeavours pursued in the South African Police Service, courts and prisons. One such oversight mechanism – the Judicial Inspectorate for Correctional Services (JICS) – is the subject of this article. Drawing on qualitative interviews with people closely involved with the JICS since 1998, this article presents ‘insider views’ regarding the JICS. We conclude with incumbents’ views on the effectiveness of the JICS.

Toughening of BIS maleimide resins: Synthesis and characterization of maleimide terminated poly(arylene ether) oligomers and polymers

Amine functional poly(arylene ether) sulfones were previously reported. Herein, the chemistry was extended to amorphous poly(arylene ether) ketones because of their higher fracture toughness values, relative to the polysulfones. It was demonstrated that the amino functional oligomers undergo a self-crosslinking reaction at temperatures above about 220 C. This produces an insoluble, but ductile network that has excellent resistance. A ketamine structure hypothesis was proposed and verified using solid state magic angle NMR. In most cases, the water generated upon ketamine formation is too low to produce porosity and solid networks are obtained. The stability of the ketamine networks towards hydrolysis is excellent. The chemistry was further demonstrated to be able to crosslink preformed nonfunctional poly(arylene ether) ketones if a difunctional amine was utilized. This concept has the possibility of greatly improving the creep resistance of thermoplastics. Also, a new technique was developed for converting the amine functional oligomers cleanly into maleimide structures. This method involves reacting maleic anhydride with monomeric aminophenols in the presence of solvent mixtures

Examination of offsite radiological emergency protective measures for nuclear reactor accidents involving core melt

"Date published: June 1978. --Reissued: October 1979."MITNE series handwritten on title-page"SAND78-0454."Originally issued as a Ph. D. thesis by the first author and supervised by the second and third author, MIT, Dept. of Nuclear Engineering, 1978Originally issued as anIncludes bibliographical referencesEvacuation, sheltering followed by population relocation, and iodine prophylaxis are evaluated as offsite public protective measures in response to nuclear reactor accidents involving core-melt. Evaluations were conducted using a modified version of the Reactor Safety Study consequence model. Models representing each measure were developed and are discussed. Potential PWR core-melt radioactive material releases are separated into two categories, "Melt-through" and "Atmospheric," based upon the mode of containment failure. Protective measures are examined and compared for each category in terms of projected doses to the whole body and thyroid. Measures for "Atmospheric" accidents are also examined in terms of their influence on the occurrence of public health effects. For "Melt-through" accidents, few, if any, early public health effects are likely, and doses in excess of Protective Action Guides (PAGs) are "confined" to areas within 10 miles of the reactor.Evacuation appears to provide the largest reduction in whole body dose for this category. However, sheltering, particularly when basements are readily available, may be an acceptable alternative. Both evacuation and iodine prophylaxis can substantially reduce the dose to the thyroid. For "Atmospheric" accidents, PAGs are likely to be exceeded at very large distances, and significant numbers of early public health effects are possible. However, most early fatalities occur within 10 miles of the reactor. Within 5 miles, evacuation appears to be more effective than sheltering in reducing the number of early health effects. Beyond 5 miles, this distinction is less, or not, apparent. Within 10 miles, early health effects are strongly influenced by the speed and efficiency with which protective measures are implemented. Outside of 10 miles, they are not.The projected total number of thyroid nodules is not substantially reduced unless iodine prophylaxis is administered over very large areas (distances). The qualitative effects of weather conditions on the above conclusions are also briefly discussed.Prepared for Office of Nuclear Regulatory Research, Probabilistic Staff, U.S. Nuclear Regulatory Commission, under Interagency Agreement DOE-40-550-75 NRC FIN no. A103

The earth's climate at the end of the century

Local climate is dependent on the global climate. Here, a global picture on climate change is presented using predictions from the EC-Earth simulations for the end of the century. The results indicate a general rise in annual mean temperature everywhere: 2-4 degrees (global average), 1-6 degrees (over Europe) and 1-4 degrees (Ireland). Changes in precipitation are more varied: large increases (>100%) at high northern latitudes and in the equatorial Pacific but decreases of more than 50% over the subtropics; winters in Europe are predicted to be up to 20% wetter and summers up to 20% drier. Changes in extremes are also presented in this chapter

Polyaryl ethers and related polysiloxane copolymer molecular coatings preparation and radiation degrdation

Poly(arylene ether sulfones) comprise a class of materials known as engineering thermoplastics which have a variety of important applications. These polymers are tough, rigid materials with good mechanical properties over a wide temperature range, and they are processed by conventional methods into products typically having excellent hydrolytic, thermal, oxidative and dimensional stability. Wholly aromatic random copolymers of hydroquinone and biphenol with 4.4 prime dichlorodiphenyl sulfone were synthesized via mechanical nucleophilic displacement. Their structures were characterized and mechanical behavior studied. These tough, ductile copolymers show excellent radiation resistance to electron beam treatment and retain much of the mechanical properties up to at least 700 Mrads under argon

Extremely Red Objects in Two Quasar Fields at z ~ 1.5

We present an investigation of the properties and environments of bright extremely red objects (EROs) found in the fields of the quasars TXS 0145+386 and 4C 15.55, both at z ~ 1.4. There is marginal evidence from Chandra ACIS imaging for hot cluster gas with a luminosity of a few 10^44 ergs/s in the field of 4C 15.55. The TXS 0145+386 field has an upper limit at a similar value, but it also clearly shows an overdensity of faint galaxies. None of the EROs are detected as X-ray sources. For two of the EROs that have spectral-energy distributions and rest-frame near-UV spectra that show that they are strongly dominated by old stellar populations, we determine radial-surface-brightness profiles from adaptive-optics images. Both of these galaxies are best fit by profiles close to exponentials, plus a compact nucleus comprising ~30% of the total light in one case and 8% in the other. Neither is well fit by an r^1/4-law profile. This apparent evidence for the formation of massive ~2 X 10^11 disks of old stars in the early universe indicates that at least some galaxies formed essentially monolithically, with high star-formation rates sustained over a few 10^8 years, and without the aid of major mergers.Comment: 25 pages, 13 figures, accepted to Ap