The chemistry of ultrasonic degradation of organic compounds

The destruction of toxic organic molecules using advanced oxidation processes (AOPs) is a potent tool for pollution control and environmental protection. Ultrasound is a convenient and effective method of generating hydroxyl radicals which is the key oxidant in AOPs. This review describes the use of ultrasound and associated chemical reactions, with and without additives, as a powerful means of remediating water contaminated with organic pollutants. After a brief introduction to ultrasound and sonochemistry, their application for the oxidation of polycyclic aromatic hydrocarbons, phenol and substituted phenols is considered. Next is the decomposition of chlorinated phenols, and other chlorinated organics, then removal of recalcitrant smaller organic molecules. A discussion follows of recent work that has investigated the effects of initial concentration of substrates; the use of different ultrasonic frequencies; the inclusion of oxidising species, inorganic particles, or salts and their contribution to enhanced degradation. Finally, brief comments are made on the status of ultrasound as an AOP treatment

Advanced Fenton processing of aqueous phenol solutions:a continuous system study including sonication effects

Our previous report based on a batch reactor system for the Advanced Fenton Process (AFP) showed that pH, hydrogen peroxide and the organic substances treated are among the most important factors affecting the oxidation efficiency. As an extended study towards its commercialisation, this paper reports the effects of the main process parameters including those relating to a new AFP flow-through system. In order to systemise and correlate the results, the Taguchi experimental design method was used. Total organic carbon (TOC) removal was utilised as the measure of the oxidation efficiency and it was found that the removal of phenol from aqueous solution at pH 2.0 and 2.5 was very similar but hydrogen peroxide supply significantly affected the TOC removal with the change of flow rate from 14.4 mL/hr to 60 mL/hr. Also, the initial concentration of phenol was a highly significant factor, with higher concentrations resulting in a lower TOC removal rate. The temperature effects in the range of 14 °C to 42 °C were investigated and it was found that there was accelerated oxidation of phenol in the early stages but after 90 minutes there was no significant difference between the results. Sonication with a bath type sonicator resulted in relatively small enhancements of TOC removal but further studies with cup-horn and probe type sonicators showed that TOC removal increased with higher intensity of sonication on additional input of hydrogen peroxide

Industrial wastewater treatment using hydrodynamic cavitation and heterogeneous advanced Fenton processing

A combination of hydrodynamic cavitation and heterogeneous advanced Fenton process (AFP) based on the use of zero valent iron as the catalyst has been investigated for the treatment of real industrial wastewater. The effect of various operating parameters such as inlet pressure, temperature, and the presence of copper windings on the extent of mineralization as measured by total organic carbon (TOC) content have been studied with the aim of maximizing the extent of degradation. It has been observed that increased pressures, higher operating temperature and the absence of copper windings are more favourable for a rapid TOC mineralization. A new approach of latent remediation has also been investigated where hydrodynamic cavitation is only used as a pre-treatment with an aim of reducing the overall cost of pollutant degradation. It has been observed that approach of latent remediation works quite well with about 50–60% removal of TOC using only minimal initial treatment by hydrodynamic cavitation

Intensification of hydroxyl radical production in sonochemical reactors

The efficacy of sonochemical reactors in chemical processing applications has been well established in the laboratory scale of operation though at a given set of operating parameters and no efforts have been directed in terms of maximizing the free radical production. In the present work, the effect of different operating parameters viz. pH, power dissipation into the system, effect of additives such as air, haloalkanes, titanium dioxide, iron and oxygen on the extent of hydroxyl radical formation in a sonochemical reactor have been investigated using salicylic acid dosimetry. Possible mechanisms for oxidation of salicylic acid in the presence of different additives have also been established. It has been observed that acidic conditions under optimized power dissipation in the presence of iron powder and oxygen result in maximum liberation of hydroxyl radicals as quantified by the kinetic rate constant for production of 2,5- and 2,3-dihydroxybenzoic acid. The study has enabled the optimization of the conditions for maximum efficacy of sonochemical reactors where free radical attack is the controlling mechanism for the chemical processing applications

Effective Actions, Boundaries and Precision Calculations of Casimir Energies

We perform the matching required to compute the leading effective boundary contribution to the QED lagrangian in the presence of a conducting surface, once the electron is integrated out. Our result resolves a confusion in the literature concerning the interpretation of the leading such correction to the Casimir energy. It also provides a useful theoretical laboratory for brane-world calculations in which kinetic terms are generated on the brane, since a lot is known about QED near boundaries.Comment: 5 pages. revtex; Added paragraphs describing finite-conductivity effects and effects due to curvatur

Intensification of oxidation capacity using chloroalkanes as additives in hydrodynamic and acoustic cavitation reactors

The effect of the presence and absence of the chloroalkanes, dichloromethane (CH2Cl2), chloroform (CHCl3) and carbon tetrachloride (CCl4) on the extent of oxidation of aqueous I- to I3- has been investigated in (a) a liquid whistle reactor (LWR) generating hydrodynamic cavitation and (b) an ultrasonic probe, which produces acoustic cavitation. The aim has been to examine the intensification achieved in the extent of oxidation due to the generation of additional free radicals/oxidants in the reactor as a result of the presence of chloroalkanes. It has been observed that the extent of increase in the oxidation reaction is strongly dependent on the applied pressure in the case of the LWR. Also, higher volumes of the chloroalkanes favour the intensification and the order of effectiveness is CCl4> CHCl3 > CH2Cl2. However, the results with the ultrasonic probe suggest that an optimum concentration of CH2Cl2 or CHCl3 exists beyond which there is little increase in the extent of observed intensification. For CCl4, however, no such optimum concentration was observed and the extent of increase in the rates of oxidation reaction rose with the amount of CCl4 added. Stage wise addition of the chloroalkanes was found to give marginally better results in the case of the ultrasonic probe as compared to bulk addition at the start of the run. Although CCl4 is the most effective, its toxicity and carcinogenicity may mean that CH2Cl2 and CHCl3 offer a safer viable alternative and the present work should be useful in establishing the amount of chloroalkanes required for obtaining a suitable degree of intensification

Initial states and infrared physics in locally de Sitter spacetime

The long wavelength physics in a de Sitter region depends on the initial quantum state. While such long wavelength physics is under control for massive fields near the Hartle-Hawking vacuum state, such initial states make unnatural assumptions about initial data outside the region of causal contact of a local observer. We argue that a reasonable approximation to a maximum entropy state, one that makes minimal assumptions outside an observer's horizon volume, is one where a cutoff is placed on a surface bounded by timelike geodesics, just outside the horizon. For sufficiently early times, such a cutoff induces secular logarithmic divergences with the expansion of the region. For massive fields, these effects sum to finite corrections at sufficiently late times. The difference between the cutoff correlators and Hartle-Hawking correlators provides a measure of the theoretical uncertainty due to lack of knowledge of the initial state in causally disconnected regions. These differences are negligible for primordial inflation, but can become significant during epochs with very long-lived de Sitter regions, such as we may be entering now.Comment: 19 pages, 4 figures, references adde

Field Tests of Insecticides against \u3ci\u3ePlagiotrochus cornigerus\u3c/i\u3e

Pin oaks, Quercus palustris Muenchhausen, are one of the important shade trees in west Tennessee. The horned oak-gall wasp, Plagiotrochus cornigerus Osten Sacken, causes a deformation of the twigs and leaves of the tree. In 1965, K. E. Stewart, an entomologist at the University of Toronto, Ontario, Canada, injected pin oaks with systemic insecticides to evaluate their effectiveness in controlling the leaf gall and the stem gall caused by the horned oak-gall wasp. He found oxydemeton-methyl ec at a rate of 25 g AI/in. diameter and technical demeton at a rate of 3 g AI/in. diameter were the best materials tested, each resulting in 83% control. In the present study we attempted to evaluate effectiveness of several systemic insecticides by applying them at the base of the tree

Electromagnetic Response and Approximate SO(5) Symmetry in High-Tc Superconductors

It has been proposed that the effective Hamiltonian describing high T_c superconductivity in cuprate materials has an approximate SO(5) symmetry relating the superconducting (SC) and antiferromagnetic (AF) phases of these systems. We show that robust consequences of this proposal are potentially large optical conductivities and Raman scattering rates in the AF phase, due to the electromagnetic response of the doubly-charged pseudo Goldstone bosons which must exist there. This provides strong constraints on the properties of the bosons, such as their mass gap and velocity.Comment: 4 pages, 3 figure