924 research outputs found
Phase field modeling of electrochemistry II: Kinetics
The kinetic behavior of a phase field model of electrochemistry is explored
for advancing (electrodeposition) and receding (electrodissolution) conditions
in one dimension. We described the equilibrium behavior of this model in [J. E.
Guyer, W. J. Boettinger, J.A. Warren, and G. B. McFadden, ``Phase field
modeling of electrochemistry I: Equilibrium'', cond-mat/0308173]. We examine
the relationship between the parameters of the phase field method and the more
typical parameters of electrochemistry. We demonstrate ohmic conduction in the
electrode and ionic conduction in the electrolyte. We find that, despite making
simple, linear dynamic postulates, we obtain the nonlinear relationship between
current and overpotential predicted by the classical ``Butler-Volmer'' equation
and observed in electrochemical experiments. The charge distribution in the
interfacial double layer changes with the passage of current and, at
sufficiently high currents, we find that the diffusion limited deposition of a
more noble cation leads to alloy deposition with less noble species.Comment: v3: To be published in Phys. Rev. E v2: Attempt to work around
turnpage bug. Replaced color Fig. 4a with grayscale 13 pages, 7 figures in 10
files, REVTeX 4, SIunits.sty, follows cond-mat/030817
Auswirkungen von PEN, einem Extrakt aus der Biomasse von Penicillium chrysogenum, auf Pathogene und Pflanzen
Der Ersatz von Kupfer und anderen Pestiziden ist eine der dringlichen Aufgaben der Forschung im biologischen Landbau. Beim direkten Pflanzenschutz stehen fungizid wirkende Substanzen, Biocontrol-Organismen und Pflanzenstärkungsmittel zur Diskussion. Das Konzept der Pflanzenstärkung ist seit langem im biologischen Landbau bekannt. Beispielsweise werden Kompostextrakte, Brennesselextrakte, aber auch kommerzialisierte Produkte aus Reynoutria sachalinensis oder Backpulver eingesetzt. Unter den Resistenzinduktoren (Elicitoren) sind vor allem diejenigen von grossem Interesse, die Resistenz gegen Pathogene auslösen, die ansonsten mit Kupfer bekämpft werden (Tamm, 2000).
Der Dünger Agro Biosol (Biochemie GmbH, A-Kundl) weist nebst einer Düngerwirkung auch krankheitsvermindernde Eigenschaften auf. Dies legen Beobachtungen nahe, die bereits in den achtziger Jahren auf Grasflächen gemacht wurden, die mit Fusarium nivale befallen waren. Das aus der Penicillinproduktion gewonnene Trockenmycel ist frei von Penicillin. Agro Biosol enthält 6 % Gesamtstickstoff, 1 % Gesamtphosphor, 1 % Kali, sowie Spurenelemente und Vitamine (Naschberger, pers. Mitteilung). In der Schweiz ist Agro Biosol als Dünger im biologischen Landbau zugelassen (Tamm, Maurer & Alföldi, 2000). E. Mösinger (Sandoz Agro, CH - Witterswil) führte erste Versuche über die krankheitsunterdrückende Wirkung von Agro Biosol durch. Dazu wurde ein Extrakt des Trockenmycels von P. chrysogenum hergestellt, der die Kurzbezeichnung ‚PEN’ erhielt. Diese Untersuchungen von Mösinger und Mitarbeitern wiesen darauf hin, dass PEN an Tomaten und Gurken Resistenz induzieren kann. Ab 1997 wurde das Thema am FiBL weiterverfolgt. Mit den vorliegenden Untersuchungen wurden die Teilziele angestrebt (i) Verifizieren und Charakterisieren der resistenzinduzierenden Eigenschaften von PEN, (ii) Abklären des Potentials für eine Weiterentwicklung von PEN als kommerzialisierbaren Resistenzinduktor und (iii) Charakterisierung der phytotoxischen Eigenschaften von PEN als Ausgangspunkt für die Optimierung von Agro Biosol.
Fazit: PEN, der Extrakt von Penicillium chrysogenum, kann bei zahlreichen Wirt- Pathogen-Systemen den Krankheitsbefall markant reduzieren. Dies ist insbesondere bei Krankheitserregern von Interesse, die ansonsten mit biotauglichen Produkten nur schwer kontrollierbar sind. Das Ausgangsmaterial wird als biotauglich eingeschätzt und steht in genügenden Mengen in konstanter Qualität zur Verfügung. Dies sind günstige Voraussetzungen, um einen neuartigen Resistenzinduktor für den biologischen Anbau bis zur Praxisreife zu entwickeln. PEN kann allerdings phytotoxische Effekte auslösen, die eine Praxisanwendung als Resistenzinduktor vorerst ausschliessen. Unsere Forschung hat gegenwärtig zwei Stossrichtungen. Einerseits werden die Effekte von PEN auf die Pflanzenphysiologie untersucht und die involvierten Stoffwechselprozesse detailliert abgeklärt. Andererseits suchen wir nach den aktiven Prinzipien, die für Resistenzinduktion und Phytotoxizität verantwortlich sind
Epitaxial growth in dislocation-free strained alloy films: Morphological and compositional instabilities
The mechanisms of stability or instability in the strained alloy film growth
are of intense current interest to both theorists and experimentalists. We
consider dislocation-free, coherent, growing alloy films which could exhibit a
morphological instability without nucleation. We investigate such strained
films by developing a nonequilibrium, continuum model and by performing a
linear stability analysis. The couplings of film-substrate misfit strain,
compositional stress, deposition rate, and growth temperature determine the
stability of film morphology as well as the surface spinodal decomposition. We
consider some realistic factors of epitaxial growth, in particular the
composition dependence of elastic moduli and the coupling between top surface
and underlying bulk of the film. The interplay of these factors leads to new
stability results. In addition to the stability diagrams both above and below
the coherent spinodal temperature, we also calculate the kinetic critical
thickness for the onset of instability as well as its scaling behavior with
respect to misfit strain and deposition rate. We apply our results to some real
growth systems and discuss the implications related to some recent experimental
observations.Comment: 26 pages, 13 eps figure
Phase field modeling of electrochemistry I: Equilibrium
A diffuse interface (phase field) model for an electrochemical system is
developed. We describe the minimal set of components needed to model an
electrochemical interface and present a variational derivation of the governing
equations. With a simple set of assumptions: mass and volume constraints,
Poisson's equation, ideal solution thermodynamics in the bulk, and a simple
description of the competing energies in the interface, the model captures the
charge separation associated with the equilibrium double layer at the
electrochemical interface. The decay of the electrostatic potential in the
electrolyte agrees with the classical Gouy-Chapman and Debye-H\"uckel theories.
We calculate the surface energy, surface charge, and differential capacitance
as functions of potential and find qualitative agreement between the model and
existing theories and experiments. In particular, the differential capacitance
curves exhibit complex shapes with multiple extrema, as exhibited in many
electrochemical systems.Comment: v3: To be published in Phys. Rev. E v2: Added link to
cond-mat/0308179 in References 13 pages, 6 figures in 15 files, REVTeX 4,
SIUnits.sty. Precedes cond-mat/030817
Capillary condensation in disordered porous materials: hysteresis versus equilibrium behavior
We study the interplay between hysteresis and equilibrium behavior in
capillary condensation of fluids in mesoporous disordered materials via a
mean-field density functional theory of a disordered lattice-gas model. The
approach reproduces all major features observed experimentally. We show that
the simple van der Waals picture of metastability fails due to the appearance
of a complex free-energy landscape with a large number of metastable states. In
particular, hysteresis can occur both with and without an underlying
equilibrium transition, thermodynamic consistency is not satisfied along the
hysteresis loop, and out-of-equilibrium phase transitions are possible.Comment: 4 pages, 4 figure
A new echocardiographic model for quantifying three-dimensional endocardial surface area
A new technique for quantitatively mapping the three-dimensional left ventricular endocardial surface was developed, using measurements from standard cross-sectional echocardiographic images. To validate the accuracy of this echocardiographic mapping technique in an animal model, the endocardial areas of 15 excised canine ventricles were calculated using measurements made from echocardiographic studies of the hearts and compared with areas determined with latex casts of the same ventricles. Close correlation (r = 0.87, p < 0.001) between these two measures of endocardial area provided preliminary confirmation of the accuracy of the maps.To further characterize the mapping algorithm, it was translated into computer format and used to map the surfaces of idealized hemiellipsoids. Areas measured with this mapping technique closely approximated the actual areas of idealized surfaces with a wide spectrum of shapes; maps were particularly accurate for ellipsoids with shapes similar to those of undistorted human ventricles. Also, the accuracies of area calculations were relatively insensitive to deviation from the assumed positions of the echocardiographic short-axis planes. Finally, although the accuracy of the mapping technique improved as data from more transverse planes were added, the procedure proved reliable for estimating surface areas when data from only three planes were used. These studies confirm the accuracy of the echocardiographic mapping technique, and they suggest that the resulting planar plots might be useful as templates for localizing and quantifying the overall extent of abnormal wall motion
Stress-driven instability in growing multilayer films
We investigate the stress-driven morphological instability of epitaxially
growing multilayer films, which are coherent and dislocation-free. We construct
a direct elastic analysis, from which we determine the elastic state of the
system recursively in terms of that of the old states of the buried layers. In
turn, we use the result for the elastic state to derive the morphological
evolution equation of surface profile to first order of perturbations, with the
solution explicitly expressed by the growth conditions and material parameters
of all the deposited layers. We apply these results to two kinds of multilayer
structures. One is the alternating tensile/compressive multilayer structure,
for which we determine the effective stability properties, including the effect
of varying surface mobility in different layers, its interplay with the global
misfit of the multilayer film, and the influence of asymmetric structure of
compressive and tensile layers on the system stability. The nature of the
asymmetry properties found in stability diagrams is in agreement with
experimental observations. The other multilayer structure that we study is one
composed of stacked strained/spacer layers. We also calculate the kinetic
critical thickness for the onset of morphological instability and obtain its
reduction and saturation as number of deposited layers increases, which is
consistent with recent experimental results. Compared to the single-layer film
growth, the behavior of kinetic critical thickness shows deviations for upper
strained layers.Comment: 27 pages, 11 figures; Phys. Rev. B, in pres
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