Growth kinetics of physical vapor transport processes: Crystal growth of the optoelectronic material mercurous chloride

Physical vapor transport processes were studied for the purpose of identifying the magnitude of convective effects on the crystal growth process. The effects of convection on crystal quality were were studied by varying the aspect ratio and those thermal conditions which ultimately affect thermal convection during physical vapor transport. An important outcome of the present study was the observation that the convection growth rate increased up to a certain value and then dropped to a constant value for high aspect ratios. This indicated that a very complex transport had occurred which could not be explained by linear stability theory. Better quality crystals grown at a low Rayleigh number confirmed that improved properties are possible in convectionless environments

Local and Global Bifurcations of Flow Fields During Physical Vapor Transport: Application to a Microgravity Experiment

The local bifurcation of the flow field, during physical vapor transport for a parametric range of experimental interest, shows that its dynamical state ranges from steady to aperiodic. Comparison of computationally predicted velocity profiles with laser doppler velocimetry measurements shows reasonable agreement in both magnitude and planform. Correlation of experimentally measured crystal quality with the predicted dynamical state of the flow field shows a degradation of quality with an increase in Rayleigh number. The global bifurcation of the flow field corresponding to low crystal quality indicates the presence of a traveling wave for Ra = 1.09 x 10(exp 5). For this Rayleigh number threshold a chaotic transport state occurs. However, a microgravity environment for this case effectively stabilizes the flow to diffusive-advective and provides the setting to grow crystals with optimal quality

Heat Entrapment Effects Within Liquid Acquisition Devices

We introduce a model problem to address heat entrapment effects or the local accumulation of thermal energy within liquid acquisition devices. We show that the parametric space consists of six parameters, namely the Rayleigh and Prandtl numbers, the aspect ratio, and heat flux ratios for the bottom, side, and top boundaries of the enclosure. For the range of Ra considered 1 to 10(sup 9), beyond Ra on the order of 10(sup 5), convective instability is the dominant mode of convection in comparison to natural convection. The flow field transitions to asymmetric modes at Ra on the order of 10(sup 7). Direct numerical simulation of a large geometric length scale prototype for Ra on the order of 10(sup 9) shows that the flow field evolves from small wavelength instability which gives rise to nonlinear growth of thermals, propagation of the instability occurs via growth of secondary and tertiary modes, and a travelling wave mode occurs prior to asymmetry. The effect of a large aspect ratio is to increase the number of modes in the vertical direction. Due to the slow diffusion of heat in the prototype, asymptotic states are not readily attained, we show that dynamical similarity can be used for a model which allows the attainment of asymptotic states and that transition to a chaotic state occurs for Ra on the order of 10(sup 9) via a broadband power spectrum. These dynamical events show that for the baseline condition in which heat is absorbed from background laboratory environment, higher heat flux is absorbed at the top and bottom boundaries of the enclosure than a nominal value of 34.9 ergs per square centimeter -second

Non-commuting coordinates, exotic particles, & anomalous anyons in the Hall effect

Our previous ``exotic'' particle, together with the more recent anomalous anyon model (which has arbitrary gyromagnetic factor $g$) are reviewed. The non-relativistic limit of the anyon generalizes the exotic particle which has $g=0$ to any $g$.When put into planar electric and magnetic fields, the Hall effect becomes mandatory for all $g\neq2$, when the field takes some critical value.Comment: A new reference added. Talk given by P. Horvathy at the International Workshop "Nonlinear Physics: Theory and Experiment. III. July'04, Gallipoli (Lecce, Italy). To be published in Theor. Math. Phys. Latex 9 pages, no figure

Generalized Massive Gravity and Galilean Conformal Algebra in two dimensions

Galilean conformal algebra (GCA) in two dimensions arises as contraction of two copies of the centrally extended Virasoro algebra ($t\rightarrow t, x\rightarrow\epsilon x$ with $\epsilon\rightarrow 0$). The central charges of GCA can be expressed in term of Virasoro central charges. For finite and non-zero GCA central charges, the Virasoro central charges must behave as asymmetric form $O(1)\pm O(\frac{1}{\epsilon})$. We propose that, the bulk description for 2d GCA with asymmetric central charges is given by general massive gravity (GMG) in three dimensions. It can be seen that, if the gravitational Chern-Simons coupling $\frac{1}{\mu}$ behaves as of order O($\frac{1}{\epsilon}$) or ($\mu\rightarrow\epsilon\mu$), the central charges of GMG have the above $\epsilon$ dependence. So, in non-relativistic scaling limit $\mu\rightarrow\epsilon\mu$, we calculated GCA parameters and finite entropy in term of gravity parameters mass and angular momentum of GMG.Comment: 9 page

Coarsening in Solid-liquid Mixtures: Overview of Experiments on Shuttle and ISS

The microgravity environment on the Shuttle and the International Space Station (ISS) provides the ideal condition to perform experiments on Coarsening in Solid-Liquid Mixtures (CSLM) as deleterious effects such as particle sedimentation and buoyancy-induced convection are suppressed. For an ideal system such as Lead-Tin in which all the thermophysical properties are known, the initial condition in microgravity of randomly dispersed particles with local clustering of solid Tin in eutectic liquid Lead-Tin matrix, permitted kinetic studies of competitive particle growth for a range of volume fractions. Verification that the quenching phase of the experiment had negligible effect of the spatial distribution of particles is shown through the computational solution of the dynamical equations of motion, thus insuring quench-free effects from the coarsened microstructure measurements. The low volume fraction experiments conducted on the Shuttle showed agreement with transient Ostwald ripening theory, and the steady-state requirement of LSW theory was not achieved. More recent experiments conducted on ISS with higher volume fractions have achieved steady-state condition and show that the kinetics follows the classical diffusion limited particle coarsening prediction and the measured 3D particle size distribution becomes broader as predicted from theory

Flight Experiment to Study Double-Diffusive Instabilities in Silver-Doped Lead Bromide Crystals

A detailed study on the effect of convection on crystal quality was carried out by growing lead bromide crystals in transparent Bridgman furnace. Direct observations were made on the solid-liquid interface and a new kind of instability was observed. This could be explained on the basis of toroidal flow in the AgBr-doped lead bromide sample. With the increasing translation velocity, the interface changed from flat to depressed, and then formed a cavity in the center of the growth tube. The crystal grown at the lowest thermal Rayleigh number showed the highest quality and crystal grown at the largest thermal Rayleigh number showed the worst quality. Numerical studies were carried out to provide a framework for interpreting the observed convective and morphological instabilities, and to determine the critical (limiting) concentration of dopant for a particular growth velocity and gravity level. Theoretical instability diagrams were compared with data obtained from the experimental studies. These studies provided basic data on convective behavior in doped lead bromide crystals grown by the commercially important Bridgman process

Celestial Mechanics, Conformal Structures, and Gravitational Waves

The equations of motion for $N$ non-relativistic particles attracting according to Newton's law are shown to correspond to the equations for null geodesics in a $(3N+2)$-dimensional Lorentzian, Ricci-flat, spacetime with a covariantly constant null vector. Such a spacetime admits a Bargmann structure and corresponds physically to a generalized pp-wave. Bargmann electromagnetism in five dimensions comprises the two Galilean electro-magnetic theories (Le Bellac and L\'evy-Leblond). At the quantum level, the $N$-body Schr\"odinger equation retains the form of a massless wave equation. We exploit the conformal symmetries of such spacetimes to discuss some properties of the Newtonian $N$-body problem: homographic solutions, the virial theorem, Kepler's third law, the Lagrange-Laplace-Runge-Lenz vector arising from three conformal Killing 2-tensors, and motions under inverse square law forces with a gravitational constant $G(t)$ varying inversely as time (Dirac). The latter problem is reduced to one with time independent forces for a rescaled position vector and a new time variable; this transformation (Vinti and Lynden-Bell) arises from a conformal transformation preserving the Ricci-flatness (Brinkmann). A Ricci-flat metric representing $N$ non-relativistic gravitational dyons is also pointed out. Our results for general time-dependent $G(t)$ are applicable to the motion of point particles in an expanding universe. Finally we extend these results to the quantum regime.Comment: 26 pages, LaTe

On the Plants Leaves Boundary, "Jupe \`a Godets" and Conformal Embeddings

The stable profile of the boundary of a plant's leaf fluctuating in the direction transversal to the leaf's surface is described in the framework of a model called a "surface \`a godets". It is shown that the information on the profile is encoded in the Jacobian of a conformal mapping (the coefficient of deformation) corresponding to an isometric embedding of a uniform Cayley tree into the 3D Euclidean space. The geometric characteristics of the leaf's boundary (like the perimeter and the height) are calculated. In addition a symbolic language allowing to investigate statistical properties of a "surface \`a godets" with annealed random defects of curvature of density $q$ is developed. It is found that at $q=1$ the surface exhibits a phase transition with critical exponent $\alpha=1/2$ from the exponentially growing to the flat structure.Comment: 17 pages (revtex), 8 eps-figures, to appear in Journal of Physics

Dynamics of semiclassical Bloch wave - packets

The semiclassical approximation for electron wave-packets in crystals leads to equations which can be derived from a Lagrangian or, under suitable regularity conditions, in a Hamiltonian framework. In the plane, these issues are studied %in presence of external fields using the method of the coadjoint orbit applied to the ``enlarged'' Galilei group.Comment: 15 pages, Talk given at Nonlinear Physics. Theory and Experiment. IV,Gallipoli (Lecce), Italy - June 22 - July 1, 200