Ecological and temperature controls on Mg/Ca ratios of Globigerina bulloides from the southwest Pacific Ocean

We present Mg/Ca data for Globigerina bulloides from 10 core top sites in the southwest Pacific Ocean analyzed by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Mg/Ca values in G. bulloides correlate with observed ocean temperatures (7 degrees C-19 degrees C), and when combined with previously published data, an integrated Mg/Ca-temperature calibration for 7 degrees C-31 degrees C is derived where Mg/Ca (mmol/mol) = 0.955 x e(0.068 x T) (r(2) = 0.95). Significant variability of Mg/Ca values (20%-30%) was found for the four visible chambers of G. bulloides, with the final chamber consistently recording the lowest Mg/Ca and is interpreted, in part, to reflect changes in the depth habitat with ontogeny. Incipient and variable dissolution of the thin and fragile final chamber, and outermost layer concomitantly added to all chambers, caused by different cleaning techniques prior to solution-based ICPMS analyses, may explain the minor differences in previously published Mg/Ca-temperature calibrations for this species. If the lower Mg/Ca of the final chamber reflects changes in depth habitat, then LA-ICPMS of the penultimate (or older) chambers will most sensitively record past changes in near-surface ocean temperatures. Mean size-normalized G. bulloides test weights correlate negatively with ocean temperature (T = 31.8 x e(-30.5xwtN); r(2) = 0.90), suggesting that in the southwest Pacific Ocean, temperature is a prominent control on shell weight in addition to carbonate ion levels

Multi-proxy validation of glacial-interglacial rainfall variations in southwest Sulawesi

Speleothem δ18O is widely used as a proxy for rainfall amount in the tropics on glacial-interglacial to interannual scales. However, uncertainties in the interpretation of this renowned proxy pose a vexing problem in tropical paleoclimatology. Here, we present paired multi-proxy geochemical measurements for stalagmites from southwest Sulawesi, Indonesia, and confirm changes in rainfall amount across ice age terminations. Collectively, the stalagmites span two glacial-interglacial transitions from ~380,000 to 330,000 and 230,000 to 170,000 years ago. Mg/Ca in the slow-growing stalagmites is affected by water moving through the karst and prior calcite precipitation, making it a good proxy for changes in local rainfall. When paired, Mg/Ca and δ18O corroborate prominent shifts from drier glacials to wetter interglacials in the core of the Australasian monsoon domain. These shifts in rainfall occur 4,000-7,000 years later than glacial-interglacial increases in global temperature and the associated response of Sulawesi vegetation, determined by speleothem δ13C

Sensitivity of the West Antarctic Ice Sheet to +2 °C (SWAIS 2C)

The West Antarctic Ice Sheet (WAIS) presently holds enough ice to raise global sea level by 4.3 m if completely melted. The unknown response of the WAIS to future warming remains a significant challenge for numerical models in quantifying predictions of future sea level rise. Sea level rise is one of the clearest planet-wide signals of human-induced climate change. The Sensitivity of the West Antarctic Ice Sheet to a Warming of 2 ∘C (SWAIS 2C) Project aims to understand past and current drivers and thresholds of WAIS dynamics to improve projections of the rate and size of ice sheet changes under a range of elevated greenhouse gas levels in the atmosphere as well as the associated average global temperature scenarios to and beyond the +2 ∘C target of the Paris Climate Agreement. Despite efforts through previous land and ship-based drilling on and along the Antarctic margin, unequivocal evidence of major WAIS retreat or collapse and its causes has remained elusive. To evaluate and plan for the interdisciplinary scientific opportunities and engineering challenges that an International Continental Drilling Program (ICDP) project along the Siple coast near the grounding zone of the WAIS could offer (Fig. 1), researchers, engineers, and logistics providers representing 10 countries held a virtual workshop in October 2020. This international partnership comprised of geologists, glaciologists, oceanographers, geophysicists, microbiologists, climate and ice sheet modelers, and engineers outlined specific research objectives and logistical challenges associated with the recovery of Neogene and Quaternary geological records from the West Antarctic interior adjacent to the Kamb Ice Stream and at Crary Ice Rise. New geophysical surveys at these locations have identified drilling targets in which new drilling technologies will allow for the recovery of up to 200 m of sediments beneath the ice sheet. Sub-ice-shelf records have so far proven difficult to obtain but are critical to better constrain marine ice sheet sensitivity to past and future increases in global mean surface temperature up to 2 ∘C above pre-industrial levels. Thus, the scientific and technological advances developed through this program will enable us to test whether WAIS collapsed during past intervals of warmth and determine its sensitivity to a +2 ∘C global warming threshold (UNFCCC, 2015)

Factors Associated with Revision Surgery after Internal Fixation of Hip Fractures

Background: Femoral neck fractures are associated with high rates of revision surgery after management with internal fixation. Using data from the Fixation using Alternative Implants for the Treatment of Hip fractures (FAITH) trial evaluating methods of internal fixation in patients with femoral neck fractures, we investigated associations between baseline and surgical factors and the need for revision surgery to promote healing, relieve pain, treat infection or improve function over 24 months postsurgery. Additionally, we investigated factors associated with (1) hardware removal and (2) implant exchange from cancellous screws (CS) or sliding hip screw (SHS) to total hip arthroplasty, hemiarthroplasty, or another internal fixation device. Methods: We identified 15 potential factors a priori that may be associated with revision surgery, 7 with hardware removal, and 14 with implant exchange. We used multivariable Cox proportional hazards analyses in our investigation. Results: Factors associated with increased risk of revision surgery included: female sex, [hazard ratio (HR) 1.79, 95% confidence interval (CI) 1.25-2.50; P = 0.001], higher body mass index (fo

Mineralogy and major element oxide composition of sediments from ODP Hole 172-1063D

Dansgaard-Oeschger (D-O) cycles in sediment at Site 1063 are characterized by distinct fluctuations in physical properties. Stadials are marked by low bulk density and interstadials by high bulk density. Compressional (P-)wave velocity is in phase with bulk density over some but not all depth intervals. Four of the D-O cycles straddling the oxygen isotope Stage 4/5 boundary have been studied in detail to understand the origin of the physical properties changes. Sediment on the Bermuda Rise is comprised of three main components: calcite, aluminosilicate minerals, and biogenic silica. Calcite concentrations vary from 1% to 43% of bulk sediment and are highest during interstadials. Aluminosilicate concentrations vary from 52% to 92% of bulk sediment and are highest during stadials. The major element ratios Al2O3/TiO2 and K2O/Al2O3 show increases across bulk density cycles, suggesting a change in the composition of aluminosilicates. This interpretation is supported by mineralogical analyses, which show a subtle change in clay composition. Biogenic silica concentrations vary from 0% to 23% of bulk sediment and are also highest during stadials. However, the abundance of silica varies significantly from one D-O cycle to another. Silt and fine sand abundance also increase during the first of the four stadials. This coarsening of sediment coincides with the increase in biogenic silica. The low grain density and high porosity associated with biogenic silica result in intervals of low bulk-sediment density. The abundance of biogenic silica closely matches P-wave velocity, suggesting that silica imparts a greater rigidity to the sediment

Late Quaternary shedding of shallow-marine carbonate along a tropical mixed siliciclastic-carbonate shelf: Great Barrier Reef, Australia

The north-east Australian margin is the largest modern example of a tropical mixed siliciclastic/carbonate depositional system, with an outer shelf hosting the Great Barrier Reef (GBR) and an inner shelf dominated by fluvially sourced siliciclastic sediment wedges. The long-term interplay between these sediment components and sea level is recorded in the Queensland Trough, a 1-2 km deep N-S elongate basin situated between the GBR platform and the Queensland Plateau. In this paper, 154 samples from 45 surface grabs and six well-dated piston cores were analysed for total carbonate content, carbonate mineralogy and Sr concentration to establish spatial and temporal patterns of carbonate accumulation in the Queensland Trough over the last 300 kyr. Surface carbonate contents are lowest on the inner-shelf (<5%) and in the trough axis (<60%) because of siliciclastic dilution. Carbonate on the shelf is mostly Sr-rich aragonite and high-Mg calcite (HMC), whereas that in the basin is mostly low-Mg calcite. Once normalized to remove the effects of siliciclastic dilution, surface Sr-rich aragonite and HMC abundances decrease linearly to background levels 100 km seaward of the shelf edge. Core samples show that, over time, normalized aragonite and Sr abundances are greatest during periods of shelf flooding and lowest when sea level drops below the shelf edge. This is consistent with changes in the production of coral and calcareous algae, and the shedding of their debris from the shelf. Interestingly, normalized HMC concentrations on the slope peak during periods of major transgression, perhaps because of maximum off-shelf transport from inter-reef areas or intermediate water dissolution. After accounting for siliciclastic dilution, there are strong similarities in both spatial and temporal patterns of carbonate minerals between slopes and basins of the north-east Australian margin and those of pure carbonate margins such as the Bahamas. A limited set of basic processes, including the formation and breakdown of carbonate on the shelf, the transport of carbonate off the shelf and eustatic sea level, probably controls carbonate accumulation in slope and basin settings of tropical environments, irrespective of proximal siliciclastic sediment sources