Luminescence properties and time-resolved spectroscopy of rare-earth doped SrMoO4 single crystals

The work of V. Pankratova was supported by the financial support of Scientific Research Project for Students and Young Researchers (SJZ/2020/05) realized at Institute of Solid State Physics, University of Latvia. The Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2.Luminescence properties of nominally pure and doped with Eu3+ and Pr3+ ions SrMoO4 single crystals grown by the Czochralski method have been studied. Thermal quenching of intrinsic emission of pure and doped SrMoO4 single crystals has been observed, as well as a correlation of thermal quenching activation energies with rare-earth ion concentration has been observed. Tunable laser was used to study time-resolved luminescence in a range from 10 K to room temperature. The effect of dopant nature and concentration on intrinsic emission and decay kinetics has been elucidated. --//-- Viktorija Pankratova, Elizaveta E. Dunaeva, Irina S. Voronina, Anna P. Kozlova, Roman Shendrik, Vladimir Pankratov, Luminescence properties and time-resolved spectroscopy of rare-earth doped SrMoO4 single crystals, Optical Materials: X, Volume 15, 2022, 100169, ISSN 2590-1478, https://doi.org/10.1016/j.omx.2022.100169. Article published under the CC BY-NC-ND licence.Scientific Research Project for Students and Young Researchers (SJZ/2020/05); the Institute of Solid State Physics, University of Latvia as the Center of Excellence has received funding from the European Union’s Horizon 2020 Framework Programme H2020-WIDESPREAD-01-2016-2017-TeamingPhase2 under grant agreement No. 739508, project CAMART2

Stimulated Raman Scattering in Yttrium, Gadolinium, and Calcium Orthovanadate Crystals with Single and Combined Frequency Shifts under Synchronous Picosecond Pumping for Sub-Picosecond or Multi-Wavelength Generation around 1.2 µm

Comparative investigation of stimulated Raman scattering (SRS) characteristics in the YVO4, GdVO4, and Ca3(VO4)2 orthovanadate crystals at both low and high frequency anionic group vibrations is presented. It was found that GdVO4 is the most perspective for SRS generation on both the ν1 stretching and ν2 bending modes of internal anionic group vibrations with the strongest SRS pulse shortening under synchronous picosecond pumping. It is as a result of GdVO4‘s widest linewidth (17cm−1) of the homogeneously broadened scheelite-type component of the bending ν2 Raman line that led to the strongest SRS pulse shortening down to the dephasing time of the widest (scheelite-type) Raman mode at the secondary intracavity short-shifted SRS conversion. It allowed us to achieve SRS pulses with sub-picosecond duration under tens-of-picoseconds pumping due to the strongest 42-fold pulse shortening. Using the Ca3(VO4)2 crystal with essentially wider Raman lines (~50cm−1) did not allow us to generate SRS pulses shorter than 1 ps. It can be explained by inhomogeneous broadening of the Raman lines in Ca3(VO4)2 because of its structural disordering. Using the measured SRS pulse duration, the homogeneous broadening of the inhomogeneously broadened bending Raman line of Ca3(VO4)2 was estimated to be ~9cm−1. Among the orthovanadate crystals, the YVO4 crystal with the highest Raman gain and with homogeneously broadened Raman lines allowed us to realize the most efficient SRS lasing and SRS pulse shortening truly down to inverse half-width of the bending Raman line

Measurement of Multi-Stokes Ultrashort Pulse Shapes of Synchronously Pumped Stimulated Raman Scattering on Combined Vibrational Modes in a BaWO₄ Crystal

Multi-Stokes ultrashort pulse shapes and their relative positions of synchronously pumped stimulated Raman scattering (SRS) on combined primary and secondary vibrational modes in a BaWO4 crystal are investigated. An original method of its simultaneous measurement with the help of a streak camera has been developed. The structure of SRS pulses at the pulse shortening effect down to the pulse duration, close to the dephasing time of the secondary Raman mode of the BaWO4 crystal, is registered and analyzed for the detuning of the Raman laser cavity length