A Glipse of a New Experiential Learning Theory Paradigm

A pseudo NSIEE Occasional Paper printed as memorabilia for the Wingspread Service Learning History Project Conference, December 2-4, 1995. This was first presented as the closing Keynote address at the 1980 NSIEE conference in San Francisco. It was reworked on the basis of correspondence with Bob Sigmon and conversations with other illuminaries. I reworked it in its present form in June 1988 and submitted it to the then editor of Occasional Papers. For probably several good reasons of which I am not aware, it was not published. So on this occasion I have taken the liberty as a former editor of the Occasional Papers, to publish it mysel

Learning Outcomes: The Measurement and Evaluation of Experimential Learning

The focus of this paper is on measuring and evaluating the learning acquired by students in field experience education, not on program evaluation. This paper serves as an introduction and supplement to the books listed on the last page. One of these, EFFICIENT EVALUATION OF INDIVIDUAL PERFORMANCE IN FIELD PLACEMENT, is provided as part of this PANEL Resource Paper

Bonding, aromaticity and reactivity patterns in some all-metal and non-metal clusters

Several sandwich-like metal clusters have been studied at the B3LYP/6-311 + G* level of theory. Bonding and reactivity have been analysed through various geometrical parameters and conceptual density functional theory based global reactivity descriptors. Aromaticity patterns have been understood in terms of the associated nucleus independent chemical shift values. Possibility of bond-stretch isomerism in some doped clusters is explored. Preferable sites for electrophilic and nucleophilic attacks have been identified using different local reactivity descriptors

Optical Spectroscopy of Galactic Cirrus Clouds: Extended Red Emission in the Diffuse Interstellar Medium

We present initial results from the first optical spectroscopic survey of high latitude Galactic cirrus clouds. The observed shape of the cirrus spectrum does not agree with that of scattered ambient Galactic starlight. This mismatch can be explained by the presence of Extended Red Emission (ERE) in the diffuse interstellar medium, as found in many other astronomical objects, probably caused by photoluminescence of hydrocarbons. The integrated ERE intensity, I_ERE \approx 1.2 x 10^{-5} erg s^{-1} cm^{-2} sr^{-1}, is roughly a third of the scattered light intensity, consistent with recent color measurements of diffuse Galactic light. The peak of the cirrus ERE (lambda_{0} \sim 6000 AA) is shifted towards short (bluer) wavelengths compared to the ERE in sources excited by intense ultraviolet radiation, such as HII regions (lambda_{0} sim 8000 AA); such a trend is seen in laboratory experiments on hydrogenated amorphous carbon films.Comment: 7 pages, 2 figures. Accepted for publication in ApJ Letter

The Photophysics of the Carrier of Extended Red Emission

Interstellar dust contains a component which reveals its presence by emitting a broad, unstructured band of light in the 540 to 950 nm wavelength range, referred to as Extended Red Emission (ERE). The presence of interstellar dust and ultraviolet photons are two necessary conditions for ERE to occur. This is the basis for suggestions which attribute ERE to an interstellar dust component capable of photoluminescence. In this study, we have collected all published ERE observations with absolute-calibrated spectra for interstellar environments, where the density of ultraviolet photons can be estimated reliably. In each case, we determined the band-integrated ERE intensity, the wavelength of peak emission in the ERE band, and the efficiency with which absorbed ultraviolet photons are contributing to the ERE. The data show that radiation is not only driving the ERE, as expected for a photoluminescence process, but is modifying the ERE carrier as manifested by a systematic increase in the ERE band's peak wavelength and a general decrease in the photon conversion efficiency with increasing densities of the prevailing exciting radiation. The overall spectral characteristics of the ERE and the observed high quantum efficiency of the ERE process are currently best matched by the recently proposed silicon nanoparticle (SNP) model. Using the experimentally established fact that ionization of semiconductor nanoparticles quenches their photoluminescence, we proceeded to test the SNP model by developing a quantitative model for the excitation and ionization equilibrium of SNPs under interstellar conditions for a wide range of radiation field densities.Comment: 42 p., incl. 8 fig. Accepted for publication by Ap

The Excitation of Extended Red Emission: New Constraints on its Carrier From HST Observations of NGC 7023

The carrier of the dust-associated photoluminescence process causing the extended red emission (ERE) in many dusty interstellar environments remains unidentified. Several competing models are more or less able to match the observed broad, unstructured ERE band. We now constrain the character of the ERE carrier further by determining the wavelengths of the radiation that initiates the ERE. Using the imaging capabilities of the Hubble Space Telescope, we have resolved the width of narrow ERE filaments appearing on the surfaces of externally illuminated molecular clouds in the bright reflection nebula NGC 7023 and compared them with the depth of penetration of radiation of known wavelengths into the same cloud surfaces. We identify photons with wavelengths shortward of 118 nm as the source of ERE initiation, not to be confused with ERE excitation, however. There are strong indications from the well-studied ERE in the Red Rectangle nebula and in the high-|b| Galactic cirrus that the photon flux with wavelengths shortward of 118 nm is too small to actually excite the observed ERE, even with 100% quantum efficiency. We conclude, therefore, that ERE excitation results from a two-step process. While none of the previously proposed ERE models can match these new constraints, we note that under interstellar conditions most polycyclic aromatic hydrocarbon (PAH) molecules are ionized to the di-cation stage by photons with E > 10.5 eV and that the electronic energy level structure of PAH di-cations is consistent with fluorescence in the wavelength band of the ERE. Therefore, PAH di-cations deserve further study as potential carriers of the ERE. (abridged)Comment: Accepted for Publication in the Ap

Parents' experiences and satisfaction with care during the birth of their very preterm baby: a qualitative study

Objective: To assess parents' experiences and satisfaction with care during very preterm birth and to identify domains associated with positive and negative experiences of care. Design: Qualitative study using semi-structured interviews. Setting: Three neonatal units in tertiary care hospitals in South-East England. Population: Thirty-two mothers and seven fathers who had a baby born before 32 weeks of gestation and spoke English well. Methods: Semi-structured interviews were conducted. Results were analysed using thematic analysis. Main outcome measures Participants' experiences and satisfaction with care during the birth of their preterm baby. Results: Overall, 80% of participants were extremely satisfied with the care during the birth of their preterm baby, seven were generally satisfied but felt some things could be improved and one was dissatisfied. Four key determinants of experiences of care were identified: staff professionalism, which included information and explanation, being calm in a crisis, appearing confident and in control, and conversely not listening to the woman; staff empathy, which included caring and emotional support, and encouragement and reassurance; involvement of the father; and birth environment. Conclusions: Although the determinants of experiences of care are generally consistent with previous research on term births, unique factors to preterm birth were identified. These were the importance of the staff appearing calm during the birth, and the staff portraying confidence and taking control during the birth. Women valued being listened to, and both they and their partners valued staff helping fathers to feel involved during the birth

Spatial Separation of the 3.29 micron Emission Feature and Associated 2 micron Continuum in NGC 7023

We present a new 0.9" resolution 3.29 micron narrowband image of the reflection nebula NGC 7023. We find that the 3.29 micron IEF in NGC 7023 is brightest in narrow filaments NW of the illuminating star. These filaments have been seen in images of K', molecular hydrogen emission lines, the 6.2 and 11.3 micron IEFs, and HCO+. We also detect 3.29 micron emission faintly but distinctly between the filaments and the star. The 3.29 micron image is in contrast to narrowband images at 2.09, 2.14, and 2.18 micron, which show an extended emission peak midway between the filaments and the star, and much fainter emission near the filaments. The [2.18]-[3.29] color shows a wide variation, ranging from 3.4-3.6 mag at the 2 micron continuum peak to 5.5 mag in the filaments. We observe [2.18]-[3.29] to increase smoothly with increasing distance from the star, up until the filament, suggesting that the main difference between the spatial distributions of the 2 micron continuum and the the 3.29 micron emission is related to the incident stellar flux. Our result suggests that the 3.29 micron IEF carriers are likely to be distinct from, but related to, the 2 micron continuum emitters. Our finding also imply that, in NGC 7023, the 2 micron continuum emitters are mainly associated with HI, while the 3.29 micron IEF carriers are primarily found in warm molecular hydrogen, but that both can survive in HI or molecular hydrogen. (abridged)Comment: to appear in ApJ, including 1 table and 8 figures, high resolution figures available at http://www.ast.cam.ac.uk/~jin/n7023