729 research outputs found
Dehydrogenated polycyclic aromatic hydrocarbons and UV bump
Recent calculations have shown that the UV bump at about 217.5 nm in the
extinction curve can be explained by a complex mixture of PAHs in several
charge states. Other studies proposed that the carriers are a restricted
population made of neutral and singly-ionised dehydrogenated coronene molecules
(C24Hn, n less than 3), in line with models of the hydrogenation state of
interstellar PAHs predicting that medium-sized species are highly
dehydrogenated. To assess the observational consequences of the latter
hypothesis we have undertaken a systematic study of the electronic spectra of
dehydrogenated PAHs. We use our first results to see whether such spectra show
strong general trends upon dehydrogenation. We used state-of-the-art techniques
in the framework of the density functional theory (DFT) to obtain the
electronic ground-state geometries, and of the time- dependent DFT to evaluate
the electronic excited-state properties. We computed the absorption
cross-section of the species C24Hn (n=12,10,8,6,4,2,0) in their neutral and
cationic charge-states. Similar calculations were performed for other PAHs and
their fullydehydrogenated counterparts. pi electron energies are always found
to be strongly affected by dehydrogenation. In all cases we examined,
progressive dehydrogenation translates into a correspondingly progressive blue
shift of the main electronic transitions. In particular, the pi-pi* collective
resonance becomes broader and bluer with dehydrogenation. Its calculated energy
position is therefore predicted to fall in the gap between the UV bump and the
far-UV rise of the extinction curve. Since this effect appears to be
systematic, it poses a tight observational limit on the column density of
strongly dehydrogenated medium-sized PAHs.Comment: 5 pages, 7 figures, Astronomy & Astrophysics, in pres
CC116 Suggestions for Handling Summer Fallowed Land which will not be Planted to Winter Wheat
Extension Circular CC116 This circular contains suggestions for handling summer fallowed land which will not be planted to winter wheat
EC171 Stubble Mulch Farming
Extension circular 171 discusses the importance and details of stubble mulch farming
EC171 Stubble Mulch Farming
Extension circular 171 discusses the importance and details of stubble mulch farming
Optical Spectroscopy of Galactic Cirrus Clouds: Extended Red Emission in the Diffuse Interstellar Medium
We present initial results from the first optical spectroscopic survey of
high latitude Galactic cirrus clouds. The observed shape of the cirrus spectrum
does not agree with that of scattered ambient Galactic starlight. This mismatch
can be explained by the presence of Extended Red Emission (ERE) in the diffuse
interstellar medium, as found in many other astronomical objects, probably
caused by photoluminescence of hydrocarbons. The integrated ERE intensity,
I_ERE \approx 1.2 x 10^{-5} erg s^{-1} cm^{-2} sr^{-1}, is roughly a third of
the scattered light intensity, consistent with recent color measurements of
diffuse Galactic light. The peak of the cirrus ERE (lambda_{0} \sim 6000 AA) is
shifted towards short (bluer) wavelengths compared to the ERE in sources
excited by intense ultraviolet radiation, such as HII regions (lambda_{0} sim
8000 AA); such a trend is seen in laboratory experiments on hydrogenated
amorphous carbon films.Comment: 7 pages, 2 figures. Accepted for publication in ApJ Letter
EC58-123 Questions and Answers about Stubble Mulching
Extension Circular 58-123 provides questions and answers about Stubble Mulch farming
EC58-123 Questions and Answers about Stubble Mulching
Extension Circular 58-123 provides questions and answers about Stubble Mulch farming
Master Equation for Hydrogen Recombination on Grain Surfaces
Recent experimental results on the formation of molecular hydrogen on
astrophysically relevant surfaces under conditions similar to those encountered
in the interstellar medium provided useful quantitative information about these
processes. Rate equation analysis of experiments on olivine and amorphous
carbon surfaces provided the activation energy barriers for the diffusion and
desorption processes relevant to hydrogen recombination on these surfaces.
However, the suitability of rate equations for the simulation of hydrogen
recombination on interstellar grains, where there might be very few atoms on a
grain at any given time, has been questioned. To resolve this problem, we
introduce a master equation that takes into account both the discrete nature of
the H atoms and the fluctuations in the number of atoms on a grain. The
hydrogen recombination rate on microscopic grains, as a function of grain size
and temperature, is then calculated using the master equation. The results are
compared to those obtained from the rate equations and the conditions under
which the master equation is required are identified.Comment: Latex document. 14 pages of text. Four associated figs in in PS
format on separate files that are "called-in" the LaTeX documen
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