36,369 research outputs found
Numerical simulation of two-phase cross flow in the gas diffusion layer microstructure of proton exchange membrane fuel cells
The cross flow in the under-land gas diffusion layer (GDL) between 2 adjacent channels plays an important role on water transport in proton exchange membrane fuel cell. A 3-dimensional (3D) two-phase model that is based on volume of fluid is developed to study the liquid water-air cross flow within the GDL between 2 adjacent channels. By considering the detailed GDL microstructures, various types of air-water cross flows are investigated by 3D numerical simulation. Liquid water at 4 locations is studied, including droplets at the GDL surface and liquid at the GDL-catalyst layer interface. It is found that the water droplet at the higher-pressure channel corner is easier to be removed by cross flow compared with droplets at other locations. Large pressure difference Δp facilitates the faster water removal from the higher-pressure channel. The contact angle of the GDL fiber is the key parameter that determines the cross flow of the droplet in the higher-pressure channel. It is observed that the droplet in the higher-pressure channel is difficult to flow through the hydrophobic GDL. Numerical simulations are also performed to investigate the water emerging process from different pores of the GDL bottom. It is found that the amount of liquid water removed by cross flow mainly depends on the pore's location, and the water under the land is removed entirely into the lower-pressure channel by cross flow
Coexistence of localized and itinerant electrons in BaFe2X3 (X = S and Se) revealed by photoemission spectroscopy
We report a photoemission study at room temperature on BaFe2X3 (X = S and Se)
and CsFe2Se3 in which two-leg ladders are formed by the Fe sites. The Fe 2p
core-level peaks of BaFe2X3 are broad and exhibit two components, indicating
that itinerant and localized Fe 3d sites coexist similar to KxFe2-ySe2. The Fe
2p core-level peak of CsFe2Se3 is rather sharp and is accompanied by a
charge-transfer satellite. The insulating ground state of CsFe2Se3 can be
viewed as a Fe2+ Mott insulator in spite of the formal valence of +2.5. The
itinerant versus localized behaviors can be associated with the stability of
chalcogen p holes in the two-leg ladder structure.Comment: 5 pages, 5 figures, Accepted in publication for Physical Review
General covariant geometric momentum, gauge potential and a Dirac fermion on a two-dimensional sphere
For a particle that is constrained on an ()-dimensional ()
curved surface, the Cartesian components of its momentum in -dimensional
flat space is believed to offer a proper form of momentum for the particle on
the surface, which is called the geometric momentum as it depends on the mean
curvature. Once the momentum is made general covariance, the spin connection
part can be interpreted as a gauge potential. The present study consists in two
parts, the first is a discussion of the general framework for the general
covariant geometric momentum. The second is devoted to a study of a Dirac
fermion on a two-dimensional sphere and we show that there is the generalized
total angular momentum whose three cartesian components form the
algebra, obtained before by consideration of dynamics of the particle, and we
demonstrate that there is no curvature-induced geometric potential for the
fermion.Comment: 8 pages, no figure. Presentation improve
Crossover of magnetoresistance in the zerogap half-metallic Heusler alloy Fe2CoSi
This work reports on the band structure and magneto-transport investigations
of the inverse Heusler compound Fe2CoSi. The first-principles calculations
reveal that Fe2CoSi has a very peculiar band structure with a conducting
property in the majority spin channel and a nearly zero bandgap in the minority
spin channel. The synthesized Fe2CoSi sample shows a high-ordered inverse
Heusler structure with a magnetic moment of 4.88 {\mu}B at 5 K and a high Curie
temperature of 1038 K. With increasing temperature, a crossover from positive
to negative magnetoresistance (MR) is observed. Complemented with the Hall
effect measurements, we suggest the intriguing crossover of MR can be ascribed
to the dominant spin carriers changing from the gapless minority spin channel
to the majority spin channel at Fermi level.Comment: 16 pages, 5 figures, submitted for publicatio
Fine-grained climate classification for the Qaidam Basin
The Qaidam Basin is a sensitive climate transition zone revealing a wide spectrum of local climates and their variability. In order to obtain an objective and quantitative expression of local climate regions as well as avoid the challenge to pre-define the number of heterogeneous local climates, the ISODATA cluster method is employed to achieve the fine-grained climate divisions of the Qaidam Basin, which can heuristically alter the number of clusters based on the input of monthly temperature and precipitation data. The fine-grained climate classification extends the traditional Koppen climate classification and represents the complex climate transformation processes in terms of fine-grained climate clusters. The following results are observed: (i) The Qaidam Basin is divided into an arid desert basin area and the surrounding alpine mountainous areas. The climate distribution is affected by both the altitude and the dryness ratio, which, employing the Budyko framework, largely characterizes the local energy-water fluxes at the surface and the related vegetation regimes (biomes). The fine-grained climate classification successfully captures their causal relationships and represents them well by the local climates: the climatic spatial differentiation in the mountainous areas is highly consistent with the topography and reveals an elevation-dependent circular distribution from the edges to the center of the basin; the climate heterogeneity within the basin presents a west-to-east meridional distribution due to the combined effect of the mid-latitude westerlies and the Indian monsoon. (ii) The climate gradients are spatially different over the Qaidam Basin. The surrounding mountainous areas have a large climate gradient compared to the inner basin; the southern mountain edge is governed by a more severe climate change than the north-eastern one; and the climate gradient is larger in the eastern than in the western basin. (iii) The lake regions within the basin show an obvious lake effect and reveal a local lake climate. Spatially, a common structure emerges with a dryer-climate zone or watershed embedding a wetter lake-affected area, which appears to migrate eastward becoming stepwise wetter from the very dry center to the wet eastern boundary of the Qaidam basin. This provides a topographically induced insight of the wet climate expansion of initially arid climates and is crucial to improve the Qaidam Basin's ecological environment. Finally, although this work mainly focuses on the local-scale climates and their variability in the Qaidam Basin, the data-driven cluster methodology for climate refinement is transferable to regional- even global-scale climate studies, which offers broad application prospects
TIBETAN PLATEAU SNOW COVER VARYING WITH CLIMATE CHANGE: A REGIONAL CLIMATE PERSPECTIVE
The Tibetan Plateau (TP) is experiencing dramatic climate changes, which increases the geographical hazard risks affecting human lives and properties. As TP holding the largest cryosphere extent outside the polar region, frequent and serious snow disasters become the crucial topic in the TP disaster reduction and management. The primary task to cope with TP snow disasters is to understand the formation and evolution of snow cover as the basis to assess and predict geographical hazards. Considering time variability and spatial heterogeneity, the geographical detector analysis has been adopted to investigate the coupling relationships between snow cover and climate change in the different periods (1989-2018) and different geographical regions (Qaidam areas, Qiangtang areas and Hengduan Mountains). The following results are noted: (i) Regionalization provides a better climate explanation for snow cover compared with the non-regionalized whole plateau model, which verifies again that the snow cover distribution and its driving mechanism both have strong spatial heterogeneity. (ii) Temperature has a dominant influence on the snow cover in all three regions, showing that net surface energy flux balance is the major limitation to the snow cover so that temperature becomes the key factor of snow-related risk management. (iii) The impact of precipitation on snow cover is only significant in the Qaidam areas according to the interaction detector approach, where the combination of temperature and precipitation can explain more than 65% of the snow cover distribution. Thus the Qaidam areas requires risk monitoring related to both hydrological and thermal aspects
The Granular Phase Diagram
The kinetic energy distribution function satisfying the Boltzmann equation is
studied analytically and numerically for a system of inelastic hard spheres in
the case of binary collisions. Analytically, this function is shown to have a
similarity form in the simple cases of uniform or steady-state flows. This
determines the region of validity of hydrodynamic description. The latter is
used to construct the phase diagram of granular systems, and discriminate
between clustering instability and inelastic collapse. The molecular dynamics
results support analytical results, but also exhibit a novel fluctuational
breakdown of mean-field descriptions.Comment: 15 pages, 4 figure
Density of states and Fisher's zeros in compact U(1) pure gauge theory
We present high-accuracy calculations of the density of states using
multicanonical methods for lattice gauge theory with a compact gauge group U(1)
on 4^4, 6^4 and 8^4 lattices. We show that the results are consistent with weak
and strong coupling expansions. We present methods based on Chebyshev
interpolations and Cauchy theorem to find the (Fisher's) zeros of the partition
function in the complex beta=1/g^2 plane. The results are consistent with
reweighting methods whenever the latter are accurate. We discuss the volume
dependence of the imaginary part of the Fisher's zeros, the width and depth of
the plaquette distribution at the value of beta where the two peaks have equal
height. We discuss strategies to discriminate between first and second order
transitions and explore them with data at larger volume but lower statistics.
Higher statistics and even larger lattices are necessary to draw strong
conclusions regarding the order of the transition.Comment: 14 pages, 16 figure
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