1,090 research outputs found
Circuit Synthesis of Electrochemical Supercapacitor Models
This paper is concerned with the synthesis of RC electrical circuits from
physics-based supercapacitor models describing conservation and diffusion
relationships. The proposed synthesis procedure uses model discretisation,
linearisation, balanced model order reduction and passive network synthesis to
form the circuits. Circuits with different topologies are synthesized from
several physical models. This work will give greater understanding to the
physical interpretation of electrical circuits and will enable the development
of more generalised circuits, since the synthesized impedance functions are
generated by considering the physics, not from experimental fitting which may
ignore certain dynamics
Micro-scale graded electrodes for improved dynamic and cycling performance of Li-ion batteries
Li-ion battery cathodes based on LiFePO4 are fabricated by a layer-by-layer spray printing method with a continuous through thickness gradient of active material, conductive carbon, and binder. Compared with cathodes with the more usual homogeneous distribution, but with the same average composition, both C-rate and capacity degradation performance of the graded electrodes are significantly improved. For example at 2C, graded cathodes with an optimized material distribution have 15% and 31% higher discharge capacities than sprayed uniform or conventional slurry cast uniform cathodes, and capacity degradation rates are 40–50% slower than uniform cathodes at 2C. The improved performance of graded electrodes is shown to derive from a lower charge transfer resistance and reduced polarization at high C-rates, which suggests a more spatially homogeneous distribution of over-potential that leads to a thinner solid electrolyte interphase formation during cycling and sustains improved C-rate and long-term cycling performance
A low-cost way to reduce greenhouse effects
Oak wood precursor was used for preparing low-cost CO2 sorbents. Adsorption is proposed as a cheaper alternative to chemical absorption, which is uneconomical, thus reducing the cost associated with the capture step. The raw material has been carbonised either by pyrolysis or by a hydrothermal carbonisation (HTC). Resulting biochars were then activated using CO2 . Initial chars and their activated counterparts were characterised by SEM imaging and N2 sorption measurements at 77 K. A significant rise in the BET surface area, total pore volume and micropore volume (textural parameters) occurred for all of the pristine chars after the activation process. Fast CO2 sorption kinetics (saturation reached in 3 mins.) and CO2 uptakes of up to ca. 6 wt. % have been measured by thermogravimetric analysis (TGA) at 35 ºC and 1 atm. The activated carbons (ACs) thus synthesised showed competitive performances compared to a commercial AC standard. Although the sorbents’ performances decreased at higher temperatures, they were easily regenerated after the capture stage
Constrained optimal control of monotone systems with applications to battery fast-charging
Enabling fast charging for lithium ion batteries is critical to accelerating
the green energy transition. As such, there has been significant interest in
tailored fast-charging protocols computed from the solutions of constrained
optimal control problems. Here, we derive necessity conditions for a fast
charging protocol based upon monotone control systems theory
Exact solution, scaling behaviour and quantum dynamics of a model of an atom-molecule Bose-Einstein condensate
We study the exact solution for a two-mode model describing coherent coupling
between atomic and molecular Bose-Einstein condensates (BEC), in the context of
the Bethe ansatz. By combining an asymptotic and numerical analysis, we
identify the scaling behaviour of the model and determine the zero temperature
expectation value for the coherence and average atomic occupation. The
threshold coupling for production of the molecular BEC is identified as the
point at which the energy gap is minimum. Our numerical results indicate a
parity effect for the energy gap between ground and first excited state
depending on whether the total atomic number is odd or even. The numerical
calculations for the quantum dynamics reveals a smooth transition from the
atomic to the molecular BEC.Comment: 5 pages, 4 figure
Aizerman Conjectures for a class of multivariate positive systems
The Aizerman Conjecture predicts stability for a class of nonlinear control systems on the basis of linear system stability analysis. The conjecture is known to be false in general. Here, a number of Aizerman conjectures are shown to be true for a class of internally positive multivariate systems, under a natural generalisation of the classical sector condition and, moreover, guarantee positivity in closed loop. These results are stronger and/or more general than existing results. The paper relates the obtained results to other, diverse, results in the literature
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