A long-chain protic ionic liquid inside silica nanopores: Enhanced proton mobility due to efficient self-assembly and decoupled proton transport

We report enhanced protonic and ionic dynamics in an imidazole/protic ionic liquid mixture confined within the nanopores of silica particles. The ionic liquid is 1-octylimidazolium bis(trifluoromethanesulfonyl)imide ([HC8Im][TFSI]), while the silica particles are microsized and characterized by internal well connected nanopores. We demonstrate that the addition of imidazole is crucial to promote a proton motion decoupled from molecular diffusion, which occurs due to the establishment of new N-H⋯N hydrogen bonds and fast proton exchange events in the ionic domains, as evidenced by both infrared and1H NMR spectroscopy. An additional reason for the decoupled motion of protons is the nanosegregated structure adopted by the liquid imidazole/[HC8Im][TFSI] mixture, with segregated polar and non-polar nano-domains, as clearly shown by WAXS data. This arrangement, promoted by the length of the octyl group and thus by significant chain-chain interactions, reduces the mobility of molecules (Dmol) more than that of protons (DH), which is manifested by DH/Dmolratios greater than three. Once included into the nanopores of hydrophobic silica microparticles, the nanostructure of the liquid mixture is preserved with slightly larger ionic domains, but effects on the non-polar ones are unclear. This results in a further enhancement of proton motion with localised paths of conduction. These findings demonstrate significant progress in the design of proton conducting materials via tailor-made molecular structures as well as by smart exploitation of confinement effects. Compared to other imidazole-based proton conducting materials that are crystalline up to 90 \ub0C or above, the gel materials that we propose are useful for applications at room temperature, and can thus find applications in e.g. intermediate temperature proton exchange fuel cells

Solar Energy Conversion and Storage Using a Photocatalytic Fuel Cell Combined with a Supercapacitor

This work studies the production of electricity by a photocatalytic fuel cell and its storage in a supercapacitor. We propose a simple construction, where a third electrode bearing activated carbon is added to the device to form a supercapacitor electrode in combination with the supporting electrolyte of the cell. The photocatalytic fuel cell is based on a CdS-sensitized mesoporous TiO2 photoanode and an air cathode bearing only nanoparticulate carbon as an oxygen reduction electrocatalyst

Improvement of the photovoltaic parameters of perovskite solar cells using a reduced-graphene-oxide-modified titania layer and soluble copper phthalocyanine as a hole transporter

Graphene modified mesoporous titania for perovskite solar cells.</p

A Comparative Study of Various Pretreatment Approaches for Bio-Ethanol Production from Willow Sawdust, Using Co-Cultures and Mono-Cultures of Different Yeast Strains

The effect of different pretreatment approaches based on alkali (NaOH)/hydrogen peroxide (H2O2) on willow sawdust (WS) biomass, in terms of delignification efficiency, structural changes of lignocellulose and subsequent fermentation toward ethanol, was investigated. Bioethanol production was carried out using the conventional yeast Saccharomyces cerevisiae, as well as three non-conventional yeasts strains, i.e., Pichia stipitis, Pachysolen tannophilus, Wickerhamomyces anomalus X19, separately and in co-cultures. The experimental results showed that a two-stage pretreatment approach (NaOH (0.5% w/v) for 24 h and H2O2 (0.5% v/v) for 24 h) led to higher delignification (38.3 ± 0.1%) and saccharification efficiency (31.7 ± 0.3%) and higher ethanol concentration and yield. Monocultures of S. cerevisiae or W. anomalus X19 and co-cultures with P. stipitis exhibited ethanol yields in the range of 11.67 ± 0.21 to 13.81 ± 0.20 g/100 g total solids (TS). When WS was subjected to H2O2 (0.5% v/v) alone for 24 h, the lowest ethanol yields were observed for all yeast strains, due to the minor impact of this treatment on the main chemical and structural WS characteristics. In order to decide which is the best pretreatment approach, a detailed techno-economical assessment is needed, which will take into account the ethanol yields and the minimum processing cost

Study of a Thin Film Aluminum-Air Battery

A thin film aluminum-air battery has been constructed using a commercial grade Al-6061 plate as anode electrode, an air-breathing carbon cloth carrying an electrocatalyst as cathode electrode, and a thin porous paper soaked with aqueous KOH as electrolyte. This type of battery demonstrates a promising behavior under ambient conditions of 20 &deg;C temperature and around 40% humidity. It presents good electric characteristics when plain nanoparticulate carbon (carbon black) is used as electrocatalyst but it is highly improved when MnO2 particles are mixed with carbon black. Thus, the open-circuit voltage was 1.35 V, the short-circuit current density 50 mA cm&minus;2, and the maximum power density 20 mW cm&minus;2 in the absence of MnO2 and increased to 1.45 V, 60 mA cm&minus;2, and 28 mW cm&minus;2, respectively, in the presence of MnO2. The corresponding maximum energy yield during battery discharge was 4.9 mWh cm&minus;2 in the absence of MnO2 and increased to 5.5 mWh cm&minus;2 in the presence of MnO2. In the second case, battery discharge lasted longer under the same discharge conditions. The superiority of the MnO2-containing electrocatalyst is justified by electrode electrochemical characterization data demonstrating reduction reactions at higher potential and charge transfer with much smaller resistance