First and second order magnetic and structural transitions in BaFe2(1−x)_{2(1-x)}Co2x_{2x}As2_{2}

We present here high resolution magnetization measurements on high-quality BaFe$_{2(1-x)}$Co$_{2x}$As$_{2}$, 0$\leq$x$\leq$0.046 as-grown single crystals. The results confirm the existence of a magnetic tricritical point in the ($x$,$T$) plane at x$^{m}_{tr}$$\approx$0.022 and reveal the emergence of the heat capacity anomaly associated with the onset of the structural transition at x$^{s}$$\approx$0.0064. We show that the samples with doping near x$^{m}_{tr}$ do not show superconductivity, but rather superconductivity emerges at a slightly higher cobalt doping, x$\approx$0.0315Comment: 4 pages, 5 figure

RXTE Observation of Cygnus X-1: Spectral Analysis

We present the results of the analysis of the broad-band spectrum of Cygnus X-1 from 3.0 to 200 keV, using data from a 10 ksec observation by the Rossi X-ray Timing Explorer. The spectrum can be well described phenomenologically by an exponentially cut-off power law with a photon index Gamma = 1.45 +/- 0.02 (a value considerably harder than typically found), e-folding energy E_fold = 162 +/- 9 keV, plus a deviation from a power law that formally can be modeled as a thermal blackbody with temperature kT_bb = 1.2 +/1 0.2 keV. Although the 3 - 30 keV portion of the spectrum can be fit with a reflected power law with Gamma = 1.81 +/- 0.01 and covering fraction f = 0.35 +/- 0.02, the quality of the fit is significantly reduced when the HEXTE data in the 30 - 100 keV range is included, as there is no observed hardening in the power law within this energy range. As a physical description of this system, we apply the accretion disc corona models of Dove, Wilms & Begelman (1997) --- where the temperature of the corona is determined self-consistently. A spherical corona with a total optical depth tau = 1.6 +/- 0.1 and an average temperature kT_c = 87 +/- 5 keV, surrounded by an exterior cold disc, does provide a good description of the data (reduced chi-squared = 1.55). These models deviate from the data by up to 7% in the 5 - 10 keV range, and we discuss possible reasons for these discrepancies. However, considering how successfully the spherical corona reproduces the 10 - 200 keV data, such ``photon-starved'' coronal geometries seem very promising for explaining the accretion processes of Cygnus X-1.Comment: Revised version (added content). 8 pages, 6 figures, 1 table.tex file, latex, uses mn.sty. Accepted for publication in MNRA

RXTE Observation of Cygnus X-1: II. Timing Analysis

We present timing analysis for a Rossi X-ray Timing Explorer observation of Cygnus X-1 in its hard/low state. This was the first RXTE observation of Cyg X-1 taken after it transited back to this state from its soft/high state. RXTE's large effective area, superior timing capabilities, and ability to obtain long, uninterrupted observations have allowed us to obtain measurements of the power spectral density (PSD), coherence function, and Fourier time lags to a decade lower in frequency and half a decade higher in frequency than typically was achieved with previous instruments. Notable aspects of our observations include a weak 0.005 Hz feature in the PSD coincident with a coherence recovery; a `hardening' of the high-frequency PSD with increasing energy; a broad frequency range measurement of the coherence function, revealing rollovers from unity coherence at both low and high frequency; and an accurate determination of the Fourier time lags over two and a half decades in frequency. As has been noted in previous similar observations, the time delay is approximately proportional to f^(-0.7), and at a fixed Fourier frequency the time delay of the hard X-rays compared to the softest energy channel tends to increase logarithmically with energy. Curiously, the 0.01-0.2 Hz coherence between the highest and lowest energy bands is actually slightly greater than the coherence between the second highest and lowest energy bands. We carefully describe all of the analysis techniques used in this paper, and we make comparisons of the data to general theoretical expectations. In a companion paper, we make specific comparisons to a Compton corona model that we have successfully used to describe the energy spectral data from this observation.Comment: To Be Published in the Astrophysical Journal. 18 pages. Uses emulatepaj.st

RXTE Observations of LMC X-1 and LMC X-3

Of all known persistent stellar-mass black hole candidates, only LMC X-1 and LMC X-3 consistently show spectra that are dominated by a soft, thermal component. We present results from long (170ksec) Rossi X-ray Timing Explorer (RXTE) observations of LMC X-1 and LMC X-3 made in 1996 December. The spectra can be described by a multicolor disk blackbody plus an additional high-energy power-law. Even though the spectra are very soft (Gamma is about 2.5), RXTE detected a significant signal from LMC X-3 up to energies of 50keV, the hardest energy at which the object was ever detected. Focusing on LMC X-3, we present results from the first year of an ongoing monitoring campaign with RXTE which started in 1997 January. We show that the appearance of the object changes considerably over its ~200d long cycle. This variability can either be explained by periodic changes in the mass transfer rate or by a precessing accretion disk analogous to Her X-1.Comment: 4 pages, 5 figures, also available at http://aitzu3.ait.physik.uni-tuebingen.de/publications/preprints1998.html to be published in "Highlights of X-Ray Astronomy, a symposium in honour of Joachim Truemper" (B. Aschenbach et al., eds.), MPE Repor

Failure mechanisms of graphene under tension

Recent experiments established pure graphene as the strongest material known to mankind, further invigorating the question of how graphene fails. Using density functional theory, we reveal the mechanisms of mechanical failure of pure graphene under a generic state of tension. One failure mechanism is a novel soft-mode phonon instability of the $K_1$-mode, whereby the graphene sheet undergoes a phase transition and is driven towards isolated benzene rings resulting in a reduction of strength. The other is the usual elastic instability corresponding to a maximum in the stress-strain curve. Our results indicate that finite wave vector soft modes can be the key factor in limiting the strength of monolayer materials

Effect of Soil Washing on Petroleum-Hydrocarbon Distribution on Sand Surfaces

A soil washing study was performed to evaluate the treatability of New River sand contaminated in the laboratory with a petroleum distillate. Unaltered and base-extracted sands were mixed with petroleum hydrocarbons, equilibrated, and washed with water or a surfactant at two different pH values (7 and 12). The surfactant had no significant effect on contaminant removal efficiencies at neutral pH. Treatment efficiencies of baseextracted sand particles were 10 to 13% higher than for the unaltered sands. Scanning electron microscopy (SEM) with elemental X-ray microprobe was used to determine the distribution of iron and carbon on the New River sand surface. Qualitative interpretations of the SEM/X-ray photomicrographs disclosed that iron oxides were associated with organic carbon on the sand surfaces, with sulfur believed to be a constituent of the petroleum contamination. Low petroleum removal efficiencies for New River sand observed in previous studies were believed to be influenced by the high iron oxide content of the sand and the affinity of these metal oxides to bind natural and petroleum-derived organic carbon

Phonon Band Structure and Thermal Transport Correlation in a Layered Diatomic Crystal

To elucidate the relationship between a crystal's structure, its thermal conductivity, and its phonon dispersion characteristics, an analysis is conducted on layered diatomic Lennard-Jones crystals with various mass ratios. Lattice dynamics theory and molecular dynamics simulations are used to predict the phonon dispersion curves and the thermal conductivity. The layered structure generates directionally dependent thermal conductivities lower than those predicted by density trends alone. The dispersion characteristics are quantified using a set of novel band diagram metrics, which are used to assess the contributions of acoustic phonons and optical phonons to the thermal conductivity. The thermal conductivity increases as the extent of the acoustic modes increases, and decreases as the extent of the stop bands increases. The sensitivity of the thermal conductivity to the band diagram metrics is highest at low temperatures, where there is less anharmonic scattering, indicating that dispersion plays a more prominent role in thermal transport in that regime. We propose that the dispersion metrics (i) provide an indirect measure of the relative contributions of dispersion and anharmonic scattering to the thermal transport, and (ii) uncouple the standard thermal conductivity structure-property relation to that of structure-dispersion and dispersion-property relations, providing opportunities for better understanding of the underlying physical mechanisms and a potential tool for material design.Comment: 30 pages, 10 figure