The effect of dopant and optical micro-cavity on the photoluminescence of Mn-doped ZnSe nanobelts

Pure and Mn-doped ZnSe nanobelts were synthesized by a convenient thermal evaporation method. Scanning electron microscopy, X-ray powder diffraction, energy dispersive X-ray spectroscopy and corresponding element mapping, and transmission electron microscope were used to examine the morphology, phase structure, crystallinity, composition, and growth direction of as-prepared nanobelts. Raman spectra were used to confirm the effective doping of Mn(2+) into ZnSe nanobelts. Micro-photoluminescence (PL) spectra were used to investigate the emission property of as-prepared samples. A dominant trapped-state emission band is observed in single ZnSe(Mn) nanobelt. However, we cannot observe the transition emission of Mn ion in this ZnSe(Mn) nanobelt, which confirm that Mn powder act as poor dopant. There are weak near-bandgap emission and strong (4)T(1) → (6)A(1) transition emission of Mn(2+) in single [Formula: see text] and [Formula: see text] nanobelt. More interesting, the (4)T(1) → (6)A(1) transition emission in [Formula: see text] nanobelt split into multi-bands. PL mapping of individual splitted sub-bands were carried out to explore the origin of multi-bands. These doped nanobelts with novel multi-bands emission can find application in frequency convertor and wavelength-tunable light emission devices

Effects of the Pinggan Qianyang Recipe on MicroRNA Gene Expression in the Aortic Tissue of Spontaneously Hypertensive Rats

The present study aimed to investigate the relationship between miRNAs and in spontaneously hypertensive rats (SHR) vascular remodeling and analyze the impact of the Pinggan Qianyang recipe (PQR) on miRNAs. Mammalian miRNA microarrays containing 509 miRNA genes were employed to analyze the differentially expressed miRNAs in the three groups. MiRNAs were considered to be up- or downregulated when the fluorescent intensity ratio between the two groups was over 4-fold. Validation of those miRNAs changed in SHR after PQR treatment was used by real-time quantitative RT-PCR (qRT-PCR). Compared with the normal group, a total of 32 miRNAs were differentially expressed by more than twofold; among these, 18 were upregulated and 14 were downregulated in the model group. Compared with the normal group, there were a number of 17 miRNAs which were significantly expressed by more than twofold in the different expressions of 32 miRNAs; among these, 10 were downregulated and 7 were upregulated in the PQR group. qRT-PCR verified that miR-20a, miR-145, miR-30, and miR-98 were significantly expressed in the three groups. These data show that PQR could exert its antihypertensive effect through deterioration of the vascular remodeling process. The mechanism might be associated with regulating differentially expressed miRNAs in aorta tissue

Dynamic responses analysis of submerged floating tunnel under impact load

Submerged floating tunnel (SFT) may be subjected to sudden impact loads such as submarine and shipwreck. Besides the local damage caused by impact, the overall transient dynamic response may also affect its driving safety. Based on the dynamic impact finite element software, the full-length model and the locally truncated accurate model with solid element of the SFT are established respectively. By applying different spring stiffness constraints on the boundary of the truncated model, its first three modes are consistent with the full-length model, thus their dynamic characteristics are basically the same. The truncated model is further used to simulate the impact of a massive object on the SFT under different impact velocities, impact mass, impact angles and impact positions. The velocity and mass of the impact object have positive influences on the peak contact force, the displacement amplitude of the tube and the length of the damaged area. When the impact angle is perpendicular to the SFT tube, the contact force, displacement amplitude and the damaged area are the largest. The change of the impact position has little effect on the contact force and the damage area, but it will affect the distribution of displacement amplitude

Corrosion Analysis and Corresponding Countermeasures of Steel Structures in Offshore Wind Farms

[Introduction] Strategies for preventing corrosion in steel structures at offshore wind farms, derived from a comprehensive study on the environmental conditions, symptoms, and mechanisms of corrosion in such structures, as well as an analysis on various causes were proposed, aiming to ensure safe operation throughout their lifecycle. [Method] The study focused on the grid-connected offshore wind farms and investigated corrosion observed in specific marine environmental conditions for different foundation types, structural components, materials, and parts. [Result] The results show that corrosion appears in various forms and progresses at varying rates among different foundation types, structural components, and parts in specific marine environmental conditions. Electrochemical corrosion is identified as the main form of corrosion, while internal and external stresses act as potential accelerators of corrosion in steel structures. Manufacturing quality control and the implementation of protective measures directly affect the rate of corrosion development.[Conclusion] In summary, it is crucial to identify various potential risks related to manufacturing characteristics, material properties, and environmental conditions of steel structures at offshore wind farms and take appropriate refined protection measures to eliminate underlying causes. In addition, protection levels should be increased for certain critical parts

Screening for CCNF Mutations in a Chinese Amyotrophic Lateral Sclerosis Cohort

Previous research has identified CCNF mutations in familial (FALS) and sporadic amyotrophic lateral sclerosis (SALS), as well as in frontotemporal dementia (FTD). The aim of our study was to measure the frequency of CCNF mutations in a Chinese population. In total, 78 FALS patients, 581 SALS patients and 584 controls were included. We found 19 missense mutations, nine synonymous mutations and two intron variants. According to the American College of Medical Genetics and Genomics (ACMG) standards and guidelines for the interpretation of sequence variants, eight variants were judged to be pathogenic or likely pathogenic variants. The frequency of such variants was 2.56% in FALS and 1.03% in SALS. In conclusion, CCNF mutations are common in FALS and SALS patients of Chinese origin, and further study is still needed

Experimental Research on Capacity Expansion of Large-Scale Offshore Wind Farm Under Multiple Wake Models

[Introduction] This article aims to study the optimal planned capacity setting of large-scale offshore wind farm. [Method] A series of numerical experiments were conducted on a single planned site with a capacity of 1 GW using three models with different unit capacities and three offshore wind farm wake models, combined with an offshore wind resource atlas, to gradually expand it to 2 GW. Power generation, wake effects and marginal utility of the whole site were analyzed. [Result] The results show that employing the wind turbine with larger single-unit capacity, the higher gaining of the power generation and slower growth of wake loss appear during the capacity expansion. Meanwhile, the larger effective expansion range which taking into account the safety of the wind turbine and the marginal utility exists. However, evaluation of effective expansion range may be affected by wake model selection. [Conclusion] This article shows that the optimal planned capacity of a single offshore wind farm can be slightly higher than the existing benchmark when multiple constraints, such as utilization of sea area, wind turbine safety and economical efficiency are met. Individual site needs to be subdivided scientifically and the optimal planned capacity should be reasonably set in the future planning of offshore wind farm bases with capacities in the tens of millions of kilowatts

Exploring the inorganic and organic nitrate aerosol formation regimes at a suburban site on the North China Plain

Nitrate-driven aerosol pollution frequently occurs during winter over the North China Plain (NCP). Extensive studies have focused on inorganic nitrate formation, but few have focused on organic nitrates in China, preduding a thorough understanding of the nitrogen cycle and nitrate aerosol formation. Here, the inorganic (NO3,inorg) and organic nitrate (NO3,org) formation regimes under aerosol liquid water (ALW) and aerosol acidity (pH) influences were investigated during winter over the NCP based on data derived from an Aerodyne high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). The campaign-averaged concentration of the total nitrate was 53 mu g m(3), with a 13% contribution from NO3,org, which exhibited a significantly decreased contribution with increasing haze episode evolution. The diurnal cycles of NO3,inorg and NO3,org were similar, with high concentrations during the nighttime at a high ALW level, revealing the important role of aqueous-phase processes. However, the correlations between the aerosol pH and NO3,inorg (R-2 = 0.13, P <0.01) and NO3,org (R-2 = 0.63, P <0.01) during polluted periods indicated a contrasting effect of aerosol pH on inorganic and organic nitrate formation. Our results provide a useful reference for smog chamber studies and promote a better understanding of organic nitrate formation via a nthropogenic emissions. (C) 2021 Elsevier B.V. All rights reserved.Peer reviewe

Two-year continuous measurements of carbonaceous aerosols in urban Beijing, China: temporal variations, characteristics and source analyses

Organic carbon (OC) and elemental carbon (EC) in the PM2.5 of urban Beijing were measured hourly with a semi-continuous thermal-optical analyzer from Jan 1, 2013 to Dec 31, 2014. The annual average OC and EC concentrations in Beijing were 17.0 ± 12.4 and 3.4 ± 2.0 μg/m3 for 2013, and 16.8 ± 14.5 and 3.5 ± 2.9 μg/m3 for 2014. It is obvious that the annual average concentrations of OC and EC in 2014 were not less than those in 2013 while the annual average PM2.5 concentration (89.4 μg/m3) in 2014 was slightly reduced as compared to that (96.9 μg/m3) in 2013. Strong seasonality of the OC and EC concentrations were found with high values during the heating seasons and low values during the non-heating seasons. The diurnal cycles of OC and EC characterized by higher values at night and in the morning were caused by primary emissions, secondary transformation and stable meteorological condition. Due to increasing photochemical activity, the OC peaks were observed at approximately noon. No clear weekend effects were observed. Interestingly, in the early mornings on weekends in the autumn and winter, the OC and EC concentrations were close to or higher than those on weekdays. Our data also indicate that high OC and EC concentrations were closely associated with their potential source areas which were determined based on the potential source contribution function analysis. High potential source areas were identified and were mainly located in the south of Beijing and the plain of northern China. A much denser source region was recorded in the winter than in the other seasons, indicating that local and regional transport over regional scales are the most important. These results demonstrate that both regional transport from the southern regions and local accumulation could lead to the enhancements of OC and EC and likely contribute to the severe haze pollution in Beijing