75 research outputs found
Total Column Density of Ozone at Coastal Station Devgad (16°24'N, 73°26'E) Measured using Portable Visible Spectrometer
Distortion Analysis of CMOS Based Analog Circuits
The amplifiers are the vital part of the analog circuit designs. The linearity of the CMOS is of most important concern in the design of many analog circuits. There are several aspects regarding nonlinear distortion analysis in analog circuits implemented in CMOS technology. Basically, the investigations visualize the nature of the total harmonic distortion (THD) dependence on the amplitude and frequency of the input signals. In this paper, the basic building blocks of analog integrated circuits such as Common source amplifier with diode connected load and Differential amplifier with current mirror load have been presented for distortion analysis. The MOSFET model used for simulation is BSIM3 SPICE model from 0.13-μm and BSIM4 SPICE model from 22-μm CMOS process technology. HSPICE circuit simulator tool is used for distortion analysis of CMOS circuits. It is evident that the above function gives remarkable insight of the nonlinear behavior of the considered circuits and it is worth considering for further investigations
Template-free sol–gel synthesis of high surface area mesoporous silica based catalysts for esterification of di-carboxylic acids
Metal-Substituted Microporous Aluminophosphates
This chapter aims to present the zeotypes aluminophosphates (AlPOs) as a complementary alternative to zeolites in the isomorphic incorporation of metal ions within all-inorganic microporous frameworks as well as to discuss didactically the catalytic consequences derived from the distinctive features of both frameworks. It does not intend to be a compilation of either all or the most significant publications involving metal-substituted microporous aluminophosphates. Families of AlPOs and zeolites, which include metal ion-substituted variants, are the dominant microporous materials. Both these systems are widely used as catalysts, in particular through aliovalent metal ions substitution. Here, some general description of the synthesis procedures and characterization techniques of the MeAPOs (metal-contained aluminophosphates) is given along with catalytic properties. Next, some illustrative examples of the catalytic possibilities of MeAPOs as catalysts in the transformation of the organic molecules are given. The oxidation of the hardly activated hydrocarbons has probably been the most successful use of AlPOs doped with the divalent transition metal ions Co2+, Mn2+, and Fe2+, whose incorporation in zeolites is disfavoured. The catalytic role of these MeAPOs is rationalized based on the knowledge acquired from a combination of the most advanced characterization techniques. Finally, the importance of the high specificity of the structure-directing agents employed in the preparation of MeAPOs is discussed taking N,N-methyldicyclohexylamine in the synthesis of AFI-structured materials as a driving force. It is shown how such a high specificity could be predicted and how it can open great possibilities in the control of parameters as critical in catalysis as crystal size, inter-and intracrystalline mesoporosity, acidity, redox properties, incorporation of a great variety of heteroatom ions or final environment of the metal site (surrounding it by either P or Al)
Georeferenced soil information system: assessment of database
Land-use planning is a decision-making process that
facilitates the allocation of land to different uses that
provide optimal and sustainable benefit. As land-use
is shaped by society–nature interaction, in land-use
planning different components/facets play a significant
role involving soil, water, climate, animal (ruminant/
non-ruminant) and others, including forestry
and the environment needed for survival of mankind.
At times these components are moderated by human
interference. Thus land-use planning being a dynamic
phenomenon is not guided by a single factor, but by a
complex system working simultaneously,which largely
affects the sustainability. To address such issues a
National Agricultural Innovation Project (NAIP) on
‘Georeferenced soil information system for land-use
planning and monitoring soil and land quality for
agriculture’ was undertaken to develop threshold
values of land quality parameters for land-use planning
through quantitative land evaluation and crop
modelling for dominant cropping systems in major
agro-ecological sub-regions (AESRs) representing
rice–wheat cropping system in the Indo-Gangetic
Plains (IGP) and deep-rooted crops in the black
soil regions (BSR). To assess the impact of landuse
change, threshold land quality indicator values
are used. A modified AESR map for agricultural landuse
planning is generated for effective land-use planning
Soil information system: use and potentials in humid and semi-arid tropics
The articles presented in this special section emanated from the researches of consortium members of the National Agricultural Innovative Project (NAIP, Component 4) of the Indian Council of Agricultural Research (ICAR), New Delhi. These researches have helped develop a soil information system (SIS). In view of the changing scenario all over the world, the need of the hour is to get assistance from a host of researchers specialized in soils, crops, geology, geography and information technology to make proper use of the datasets. Equipped with the essential knowledge of data storage and retrieval for management recommendations, these experts should be able to address the issues of land degradation, biodiversity, food security, climate change and ultimately arrive at an appropriate agricultural land-use planning. Moreover, as the natural resource information is an essential prerequisite for monitoring and predicting global environmental change with special reference to climate and land use options, the SIS needs to be a dynamic exercise to accommodate temporal datasets, so that subsequently it should result in the evolution of the soil information technology. The database developed through this NAIP would serve as an example of the usefulness of the Consortium and the research initiative of ICAR involving experts from different fields to find out the potentials of the soils of humid and semi-arid bioclimatic systems of the country
Low temperature preparation of β-alumina by an alkoxide route
β-Alumina has been prepared by the thermal decomposition of a mixture of sodium and aluminium isopropoxides followed by heating up to 1000° C. It has been found necessary to use sodium isopropoxide in excess (25-30%) for the complete formation ofβ-alumina at 1000° C. On the other hand one obtains a mixture ofβ-alumina andα-alumina when the starting materials are taken in the stoichiometric ratio Na2O:11Al2O3. DTA, TG and DTG studies of a mixture of sodium and aluminium isopropoxide showedβ-alumina formation at 1000° C
Thermal analysis of some metal alkoxides
The thermal decomposition of AI(OPri)3, Ca(OEt)2 and Mg(OEt)2 has been studied using differential thermal analysis and thermogravimetric techniques. The decomposition products have been isolated and identified by gas chromatography and mass spectrometry. Probable routes for the thermal decomposition of these alkoxides have been proposed
Low temperature preparation of stabilized zirconia
The preparation of stabilized zirconia by thermal decomposition of metal alkoxides is reported. Formation of stabilized zirconia takes place at 400° C. The a.c. conductivity of the samples has been measured from 400 to 1000° C. The best conductivity is found in ZrO2doped with 15 per cent CaO, which at 400° C is 2.37×10−6 Ω−1 cm−1 and at 1000° C is 1.26×10−2 Ω−1 cm−1, with an activation energy of 1.16eV. Transport number measurements show that stabilized zirconia prepared by this method is purely an oxygen ion conductor
- …