Enhancing copper infiltration into alumina using spark plasma sintering to achieve high performance Al2O3/Cu composites

Al2O3/Cu (with 30 wt% of Cu) composites were prepared using a combined liquid infiltration and spark plasma sintering (SPS) method using pre-processed composite powders. Crystalline structures, morphology and physical/mechanical properties of the sintered composites were studied and compared with those obtained from similar composites prepared using a standard liquid infiltration process without any external pressure. Results showed that densities of the Al2O3/Cu composites prepared without applying pressure were quite low. Whereas the composites sintered using the SPS (with a high pressure during sintering in 10 minutes) showed dense structures, and Cu phases were homogenously infiltrated and dispersed with a network from inside the Al2O3 skeleton structures. Fracture toughness of Al2O3/Cu composites prepared without using external pressure (with a sintering time of 1.5 hours) was 4.2 MPa·m1/2, whereas that using the SPS process was 6.5 MPa·m1/2. These toughness readings were increased by 18% and 82%, respectively, compared with that of pure alumina. Hardness, density and electrical resistivity of the samples prepared without pressure were 693 HV, 82.5% and 0.01Ω•m, whereas those using the SPS process were 842 HV, 99.1%, 0.002Ω•m, respectively. The enhancement in these properties using the SPS process are mainly due to the efficient pressurized infiltration of Cu phases into the network of Al2O3 skeleton structures, and also due to high intensity discharge plasma which produces fully densified composites in a short time

Experimental and theoretical analysis of microstructural evolution and deformation behaviors of CuW composites during equal channel angular pressing

CuW composites were synthesized using an equal channel angular pressing (ECAP) technique. Microstructural evolution during sintering process was investigated using both optical microscopy and transmission electron microscopy (TEM), and their deformation mechanisms were studied using finite element analysis (FEA). Results showed severe plastic deformation of the CuW composites and effective refinement of W grains after the ECAP process. TEM observation revealed that the ECAP process resulted in lamellar bands with high densities dislocations inside the composites. Effects of extrusion temperature and extrusion angles on stress-strain relationship and sizes of deformation zones after the ECAP process were investigated both theoretically and experimentally. When the extrusion angle was 90°, a maximum equivalent stress of ~1001 MPa was obtained when the extrusion test was done at room temperature of 22 °C, and this value was lower than compression strength of the CuW composites (1105.43 MPa). The maximum equivalent strains were varied between 0.5 and 0.7. However, when the extrusion temperature was increased to 550 °C and further to 900 °C, the maximum equivalent stresses were decreased sharply, with readings of 311 MPa and 68 MPa, respectively. When the extrusion angle was increased to 135°, the maximum equivalent stresses were found to be 716.9 MPa, 208 MPa, and 32 MPa for the samples extruded at temperatures of 22 °C, 550 °C and 900 °C, respectively. Simultaneously, the maximum equivalent strains were decreased to 0.2–0.4. Furthermore, results showed that the maximum equivalent stress was located on the sample's external surface and the stress values were gradually decreased from the surface to the center of samples, and the magnitudes of plastic deformation zones at the surface were much larger than those at the central part of the sintered samples. FEA simulation results were in good agreements with experimentally measured ones

Towards Effective Adversarial Textured 3D Meshes on Physical Face Recognition

Face recognition is a prevailing authentication solution in numerous biometric applications. Physical adversarial attacks, as an important surrogate, can identify the weaknesses of face recognition systems and evaluate their robustness before deployed. However, most existing physical attacks are either detectable readily or ineffective against commercial recognition systems. The goal of this work is to develop a more reliable technique that can carry out an end-to-end evaluation of adversarial robustness for commercial systems. It requires that this technique can simultaneously deceive black-box recognition models and evade defensive mechanisms. To fulfill this, we design adversarial textured 3D meshes (AT3D) with an elaborate topology on a human face, which can be 3D-printed and pasted on the attacker's face to evade the defenses. However, the mesh-based optimization regime calculates gradients in high-dimensional mesh space, and can be trapped into local optima with unsatisfactory transferability. To deviate from the mesh-based space, we propose to perturb the low-dimensional coefficient space based on 3D Morphable Model, which significantly improves black-box transferability meanwhile enjoying faster search efficiency and better visual quality. Extensive experiments in digital and physical scenarios show that our method effectively explores the security vulnerabilities of multiple popular commercial services, including three recognition APIs, four anti-spoofing APIs, two prevailing mobile phones and two automated access control systems

Microstructure evolution and enhanced properties of Cu–Cr–Zr alloys through synergistic effects of alloying, heat treatment and low-energy cyclic impact

In this paper, CuCr–Zr alloys prepared by vacuum melting with adding La and Ni elementswere heat-treated and aged, followed by plastic deformation using low-energy cyclic impact tests, to simultaneously improve their mechanical and electrical properties. Results showed that the grain size of the casted Cu–Cr–Zr alloys was significantly reduced after the solid-solution aging and plastic deformation process. There were a lot of dispersed Cr and Cu5Zr precipitates formed in the alloys, and the numbers of dislocations were significantly increased. Accordingly, the hardness was increased from 78 to 232 HV, and the tensile strength was increased from 225 to 691 MPa. Electrical conductivity has not been significantly affected after these processes. The enhancement of overall performance is mainly attributed to the combined effects of solid-solution hardening, fine grain hardening, and precipitation/dislocation strengthening

Controlled Interfacial Reactions and Superior Mechanical Properties of High Energy Ball Milled/Spark Plasma Sintered Ti–6Al–4V–Graphene Composite

Ball milling process has become one of the effective methods for dispersing graphene nanoplates (GNPs) uniformly into matrix; however, there are often serious issues of structural integrity and interfacial reactions of GNPs with matrix. Herein, GNPs/Ti‐6Al‐4V (GNPs/TC4) composites are synthesized using high energy ball milling (HEBM) and spark plasma sintering. Effects of ball milling on microstructural evolution and interfacial reactions of GNPs/TC4 composite powders during HEBM are investigated. As ball milling time increase, particles size of TC4 is first increased (e.g., ≈104.15 μm, 5 h), but then decreased to ≈1.5 μm (15 h), which is much smaller than that of original TC4 powders (≈86.8 μm). TiC phases are in situ formed on the surfaces of TC4 particles when ball milling time is 10Thinsp;h. GNPs/TC4 composites exhibit 36–103% increase in compressive yield strength and 57–78% increase in hardness than those of TC4 alloy, whereas the ductility is reduced from 28% to 7% with an increase of ball milling time (from 2 to 15 h). A good balance between high strength (1.9 GPa) and ductility (17%) of GNPs/TC4 composites is achieved when the ball milling time is 10 h, attributing to the synergistic effects of grain refinement strengthening, solid solution strengthening, and load transfer strengthening from GNPs and in situ formed TiC

Simultaneously enhancing the strength and ductility in titanium matrix composites via discontinuous network structure

In this study, titanium matrix composites reinforced with graphene nanoplates (GNPs) were successfully prepared via an in-situ processing strategy. Both TiC nanoparticles and TiC@GNPs strips are in-situ formed at the grain boundaries, and enhance interfacial bonding strength between GNPs and Ti matrix by acting as rivets in the microstructure. The GNPs can be retained in the center of TiC layer, which provides a shielding protection effect for the GNPs. These in-situ formed TiC nanoparticles are linked together to form a discontinuous and three-dimensional (3D) network structure. Due to the formation of 3D network architecture and improved interfacial bonding, the composites show both high strength and good ductility. The significant strengthening effect reinforced by the GNPs can be attributed to a homogeneous distribution of in-situ formed TiC nanoparticles and TiC@GNPs strips, resulting in TiC interface/particle strengthening and excellent interfacial load transfer capability

Advances in graphene reinforced metal matrix nanocomposites: Mechanisms, processing, modelling, properties and applications

Graphene has been extensively explored to enhance functional and mechanical properties of metal matrix nanocomposites for wide-range applications due to their superior mechanical, electrical and thermal properties. This article discusses recent advances of key mechanisms, synthesis, manufacture, modelling and applications of graphene metal matrix nanocomposites. The main strengthening mechanisms include load transfer, Orowan cycle, thermal mismatch, and refinement strengthening. Synthesis technologies are discussed including some conventional methods (such as liquid metallurgy, powder metallurgy, thermal spraying and deposition technology) and some advanced processing methods (such as molecular-level mixing and friction stir processing). Analytical modelling (including phenomenological models, semi-empirical models, homogenization models, and self-consistent model) and numerical simulations (including finite elements method, finite difference method, and boundary element method) have been discussed for understanding the interface bonding and performance characteristics between graphene and different metal matrices (Al, Cu, Mg, Ni). Key challenges in applying graphene as a reinforcing component for the metal matrix composites and the potential solutions as well as prospectives of future development and opportunities are highlighted

miR-216b Post-Transcriptionally Downregulates Oncogene KRAS and Inhibits Cell Proliferation and Invasion in Clear Cell Renal Cell Carcinoma

Background/Aims: Increasing evidence has shown that miR-216b plays an important role in human cancer progression. However, little is known about the function of miR-216b in renal cell carcinoma. Methods: The expression levels of miR-216b in renal cell carcinoma tissues and cell lines were examined by qRT-PCR. The biological role of miR-216b in renal cell carcinoma proliferation and/or metastasis was examined in vitro and in vivo. The target of miR-216b was identified by a dual-luciferase reporter assay. The expression level of KRAS protein was measured by western blotting. Results: The expression of miR-216b was downregulated in clear cell renal cell carcinoma (ccRCC) cell lines and specimens compared to the adjacent normal tissues. Furthermore, miR-216b can bind to the 3’untranslated region (UTR) of KRAS and inhibit the expression of KRAS through translational repression. The in vitro study revealed that miR-216b attenuated ccRCC cell proliferation and invasion. Furthermore, in vivo study also showed that miR-216b suppressed tumor growth. MiR-216b exerted its tumor suppressor function through inhibiting the KRAS-related MAPK/ERK and PI3K/AKT pathways. Conclusion: Our findings provide, for the first time, significant clues regarding the role of miR-216b as a tumor suppressor by targeting KRAS in ccRCC

Ferroelectricity in layered bismuth oxide down to 1 nanometer

Atomic-scale ferroelectrics are of great interest for high-density electronics, particularly field-effect transistors, low-power logic, and nonvolatile memories. We devised a film with a layered structure of bismuth oxide that can stabilize the ferroelectric state down to 1 nanometer through samarium bondage. This film can be grown on a variety of substrates with a cost-effective chemical solution deposition. We observed a standard ferroelectric hysteresis loop down to a thickness of ~1 nanometer. The thin films with thicknesses that range from 1 to 4.56 nanometers possess a relatively large remanent polarization from 17 to 50 microcoulombs per square centimeter. We verified the structure with first-principles calculations, which also pointed to the material being a lone pair-driven ferroelectric material. The structure design of the ultrathin ferroelectric films has great potential for the manufacturing of atomic-scale electronic devices.This work was supported by the National Key Research and Development Program of China (2018YFA0703700, 2017YFE0119700, and 2020YFA0406202), the National Natural Science Foundation of China (21801013, 51774034, 51961135107, 62104140, 12175235, 22090042, 12074016, 11704041, and 12274009), the Fundamental Research Funds for the Central Universities (FRF-IDRY-19-007 and FRF-TP-19-055A2Z), the National Program for Support of Top-notch Young Professionals, the Young Elite Scientists Sponsorship Program by CAST (2019-2021QNRC), and Lingang Laboratory Open Research Fund (grant LG-QS-202202-11). Use of the Beijing Synchrotron Radiation Facility (1W1A beamlines, China) of the Chinese Academy of Sciences is acknowledged. Y.-W.F. acknowledges the support of Masaki Azuma’s group during his stay at the Tokyo Institute of Technology. Y.L. acknowledges the support of the Beijing Innovation Team Building Program (grant no. IDHT20190503), the Beijing Natural Science Foundation (Z210016), the Research and Development Project from the Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering (2022SX-TD001), and the General Program of Science and Technology Development Project of Beijing Municipal Education Commission (KM202110005003).Peer reviewe

Experimental Study on the Seismic Performance of Socket Bridge Piers

In order to accelerate the construction of bridge substructure, a socket joint construction that does not require interfaces roughening between the precast columns and the reserved cavity of the precast foundation is raised in this paper. The seismic performance of such fabricated bridge piers was investigated by carrying quasistatic tests on socket circular pier specimens of different embedment depths with a compared cast-in-place pier specimen. The experimental results showed that the prefabricated piers with the embedment length larger than 1.0 times the column diameter, featuring smooth interfaces that was free of roughening, had a failure mode of bending damage as well as the cast-in-place component. As the embedment depth increases, the seismic performance indexes of the socket bridge pier, including bearing capacity, ductility, and energy dissipation capacity, are improved. The seismic performance indexes of a socket bridge pier specimen with an embedment depth of 1.5 times the column’s diameter in the test are better than the cast-in-place one