The Iron Catalyzed Reaction between Nitrosyl Disulfonate and Hydroxylamine Monosulfonate Ions

Potassium nitrosyl disulfonate, K2NO(SO3)2, is noteworthy because the solid salt is orange in color and diamagnetic while its neutral aqueous solutions are purple in color and paramagnetic. These neutral solutions hydrolyze slowly to form N2O and hydroxylamine sulfonates; on the addition of acid the rate of hydrolysis is markedly increased. The mechanism of the hydrolytic reaction is unexpectedly complex as was found by Murib and Ritter [1] and, independently, by us. In order to obtain a more comprehensive picture of the mechanism of the hydrolytic reaction we have explored additional reactions which may play a part in the hydrolysis

New Einstein-Sasaki Spaces in Five and Higher Dimensions

We obtain infinite classes of new Einstein-Sasaki metrics on complete and non-singular manifolds. They arise, after Euclideanisation, from BPS limits of the rotating Kerr-de Sitter black hole metrics. The new Einstein-Sasaki spaces L^{p,q,r} in five dimensions have cohomogeneity 2, and U(1) x U(1) x U(1) isometry group. They are topologically S^2 x S^3. Their AdS/CFT duals will describe quiver theories on the four-dimensional boundary of AdS_5. We also obtain new Einstein-Sasaki spaces of cohomogeneity n in all odd dimensions D=2n+1 \ge 5, with U(1)^{n+1} isometry.Comment: Revtex, 4 pages, metric regularity conditions are further refine

Early life growth patterns persist for 12 years and impact pulmonary outcomes in cystic fibrosis

BACKGROUND: In children with cystic fibrosis (CF), recovery from growth faltering within 2 years of diagnosis (Responders) is associated with better growth and less lung disease at age 6 years. This study examined whether these benefits are sustained through 12 years of age. METHODS: Longitudinal growth from 76 children with CF enrolled in the Wisconsin CF Neonatal Screening Project was examined and categorized into 5 groups: R12, R6, and R2, representing Responders who maintained growth improvement to age 12, 6, and 2 years, respectively, and I6 and N6, representing Non-responders whose growth did and did not improve during ages 2-6 years, respectively. Lung disease was evaluated by % predicted forced expiratory volume in one second (FEV1) and chest radiograph (CXR) scores. RESULTS: Sixty-two percent were Responders. Within this group, 47% were R12, 28% were R6, and 25% were R2. Among Non-responders, 76% were N6. CF children with meconium ileus (MI) had worse lung function and CXR scores compared to other CF children. Among 53 children with pancreatic insufficiency without MI, R12 had significantly better FEV1 (97-99% predicted) and CXR scores during ages 6-12 years than N6 (89-93% predicted). Both R6 and R2 experienced a decline in FEV1 by ages 10-12 years. CONCLUSIONS: Early growth recovery in CF is critical, as malnutrition during infancy tends to persist and catch-up growth after age 2 years is difficult. The longer adequate growth was maintained after early growth recovery, the better the pulmonary outcomes at age 12 years

Observation of accelerating parabolic beams

We report the first observation of accelerating parabolic beams. These accelerating parabolic beams are similar to the Airy beams because they exhibit the unusual ability to remain diffraction-free while having a quadratic transverse shift during propagation. The amplitude and phase masks required to generate these beams are encoded onto a single liquid crystal display. Experimental results agree well with theory

The molecular structure of isocyanic acid from microwave and infra-red absorption spectra

Experimental investigations of the infra-red and microwave spectra of the slightly asymmetric rotor, HNCO, have been made, and the structure of the molecule has been determined