494 research outputs found
Controlled deposition of 2D-confined Pd or Ir nano-islands on Au(1 1 1) following Cu UPD, and their HER activity
Intermanifold similarities in partial photoionization cross sections of helium
Using the eigenchannel R-matrix method we calculate partial photoionization
cross sections from the ground state of the helium atom for incident photon
energies up to the N=9 manifold. The wide energy range covered by our
calculations permits a thorough investigation of general patterns in the cross
sections which were first discussed by Menzel and co-workers [Phys. Rev. A {\bf
54}, 2080 (1996)]. The existence of these patterns can easily be understood in
terms of propensity rules for autoionization. As the photon energy is increased
the regular patterns are locally interrupted by perturber states until they
fade out indicating the progressive break-down of the propensity rules and the
underlying approximate quantum numbers. We demonstrate that the destructive
influence of isolated perturbers can be compensated with an energy-dependent
quantum defect.Comment: 10 pages, 10 figures, replacement with some typos correcte
Resonance structure in the Li^- photodetachment cross section
We report on the first observation of resonance structure in the total cross
section for the photodetachment of Li^-. The structure arises from the
autodetaching decay of doubly excited ^1P states of Li^- that are bound with
respect to the 3p state of the Li atom. Calculations have been performed for
both Li^- and H^- to assist in the identification of these resonances. The
lowest lying resonance is a symmetrically excited intrashell resonance. Higher
lying asymmetrically excited intershell states are observed which converge on
the Li(3p) limit.Comment: 4 pages, 2 figure, 19 references, RevTeX, figures in ep
Mirror Position Determination for the Alignment of Cherenkov Telescopes
Imaging Atmospheric Cherenkov Telescopes (IACTs) need imaging optics with
large apertures to map the faint Cherenkov light emitted in extensive air
showers onto their image sensors. Segmented reflectors fulfill these needs
using mass produced and light weight mirror facets. However, as the overall
image is the sum of the individual mirror facet images, alignment is important.
Here we present a method to determine the mirror facet positions on a segmented
reflector in a very direct way. Our method reconstructs the mirror facet
positions from photographs and a laser distance meter measurement which goes
from the center of the image sensor plane to the center of each mirror facet.
We use our method to both align the mirror facet positions and to feed the
measured positions into our IACT simulation. We demonstrate our implementation
on the 4 m First Geiger-mode Avalanche Cherenkov Telescope (FACT).Comment: 11 figures, small ray tracing performance simulation, and
implementation demonstratio
FACT -- the First Cherenkov Telescope using a G-APD Camera for TeV Gamma-ray Astronomy (HEAD 2010)
Geiger-mode Avalanche Photodiodes (G-APD) bear the potential to significantly
improve the sensitivity of Imaging Air Cherenkov Telescopes (IACT). We are
currently building the First G-APD Cherenkov Telescope (FACT) by refurbishing
an old IACT with a mirror area of 9.5 square meters and construct a new, fine
pixelized camera using novel G-APDs. The main goal is to evaluate the
performance of a complete system by observing very high energy gamma-rays from
the Crab Nebula. This is an important field test to check the feasibility of
G-APD-based cameras to replace at some time the PMT-based cameras of planned
future IACTs like AGIS and CTA. In this article, we present the basic design of
such a camera as well as some important details to be taken into account.Comment: Poster shown at HEAD 2010, Big Island, Hawaii, March 1-4, 201
Onset of magnetism in B2 transition metals aluminides
Ab initio calculation results for the electronic structure of disordered bcc
Fe(x)Al(1-x) (0.4<x<0.75), Co(x)Al(1-x) and Ni(x)Al(1-x) (x=0.4; 0.5; 0.6)
alloys near the 1:1 stoichiometry, as well as of the ordered B2 (FeAl, CoAl,
NiAl) phases with point defects are presented. The calculations were performed
using the coherent potential approximation within the Korringa-Kohn-Rostoker
method (KKR-CPA) for the disordered case and the tight-binding linear
muffin-tin orbital (TB-LMTO) method for the intermetallic compounds. We studied
in particular the onset of magnetism in Fe-Al and Co-Al systems as a function
of the defect structure. We found the appearance of large local magnetic
moments associated with the transition metal (TM) antisite defect in FeAl and
CoAl compounds, in agreement with the experimental findings. Moreover, we found
that any vacancies on both sublattices enhance the magnetic moments via
reducing the charge transfer to a TM atom. Disordered Fe-Al alloys are
ferromagnetically ordered for the whole range of composition studied, whereas
Co-Al becomes magnetic only for Co concentration >0.5.Comment: 11 pages with 9 embedded postscript figures, to be published in
Phys.Rev.
Collinear helium under periodic driving: stabilization of the asymmetric stretch orbit
The collinear eZe configuration of helium, with the electrons on opposite
sides of the nucleus, is studied in the presence of an external electromagnetic
(laser or microwave) field. We show that the classically unstable "asymmetric
stretch" orbit, on which doubly excited intrashell states of helium with
maximum interelectronic angle are anchored, can be stabilized by means of a
resonant driving where the frequency of the electromagnetic field equals the
frequency of Kepler-like oscillations along the orbit. A static magnetic field,
oriented parallel to the oscillating electric field of the driving, can be used
to enforce the stability of the configuration with respect to deviations from
collinearity. Quantum Floquet calculations within a collinear model of the
driven two-electron atom reveal the existence of nondispersive wave packets
localized on the stabilized asymmetric stretch orbit, for double excitations
corresponding to principal quantum numbers of the order of N > 10.Comment: 13 pages, 12 figure
Multicentre evaluation of the Boehringer Mannheim / Hitachi 911 Analysis System
The analytical performance and practicability of the Boehringer Mannheim (BM)/mtaci 91 analysis system have been assessed in a multicentre evaluation, which involved six laboratories from European countries. Analytes commonly used in classical clinical chemistry were tested in a core programme, which mainlyfollowed lhe ECCLS guidelines. In addition, a satellite programme covered other analytes, such as proteins, drugs and urine analytes. In total, the study comprised more than 100 000 data items collected over a three-month period. The evaluation was supported with 'Computer Aided Evaluation' (CAEv) and telecommunications. Acceptance criteria for the results were established at the beginning ofthe study. Nearly all ofthe analytes met the imprecision limits.' within-run imprecision (as CVs) was 2l/ofor enzyme and substrate assays, l%for ISE methods and 5l/o for immunoassays; between-day imprecision was 3l/ofor enzyme and substrate assays, 2o//o for ISE methods and 10% for immunoassays
Production of volatile fatty acids from slaughterhouse blood by mixed-culture fermentation
The volatile fatty acids (VFA) production potential from animal blood and the factors affecting this process were investigated in this study. In order to simulate an industrial process different operation modes, batch, fed batch and semi-continuous, were also evaluated. Due to high ammonia concentration in fermentation broth, VFA concentration up to 100 g L-1 was achieved without addition of buffer and methanogen inhibitor. In general, acetic, n-butyric and iso-valeric acids were the most predominant species, although different operational conditions affected the VFA concentration, profile, production rate and yield. The microbial community analysis was conducted on the reactors with the best performance, revealing that 70-90% of the microbial population was from the Clostridiales order with a strong presence from the Sporanaerobacter genus. These results demonstrated the feasibility of a VFA-platform bio-refinery using high-protein wastes as substrate via mixed-culture fermentation under non-sterilised conditions
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