Electronic structure of Zr-Ni-Sn systems: role of clustering and nanostructures in Half-Heusler and Heusler limits

Half-Heusler and Heusler compounds have been of great interest for several decades for thermoelectric, magnetic, half-metallic and many other interesting properties. Among these systems, Zr-Ni-Sn compounds are interesting thermoelectrics which can go from semiconducting half-Heusler (HH) limit, ZrNiSn, to metallic Heusler (FH) limit, ZrNi$_2$Sn. Recently Makogo et al. [J. Am. Chem. Soc. 133, 18843 (2011)] found that dramatic improvement in the thermoelectric power factor of HH can be achieved by putting excess Ni into the system. This was attributed to an energy filtering mechanism due to the formation of FH nanostructures in the HH matrix. Using density functional theory we have investigated clustering and nanostructure formation in HH$_{1-x}$FH$_x$ systems near the HH and FH ends and found that excess Ni atoms in HH tend to stay close to each other and form nanoclusters of FH. On the other hand, there is competing interaction between Ni-vacancies in FH which prevent them from forming HH nano clusters. Effects of nano inclusions on the electronic structure at both HH and FH ends will be discussed.Comment: Published in J. Phys.: Condens. Matte

Smoke-free environment policy in Vietnam : what did people see and how did they react when they visited various public places?

Introduction. Since Vietnam has signed WHO framework on tobacco control (FCTC) in 2003 and has issued tobacco control law in 2013, there has been little research concerning about what impacts smoke-free regulations have had on public compliance. The objective of this study was to assess public exposure to secondhand smoke and reaction toward smoke-free policy regulations in Vietnam and the associated factor. Methods. Using the design of GATS (Global Adult Tobacco Survey), a nationally representative sample of 8,996 adults were approached for data collection. Logistic regression was used to examine the associated factor. Results. The study revealed that the prevalence of respondents exposed to secondhand smoke was much higher in bars/café/tea shops (90.07%) and restaurants (81.81%) than in any other public places, universities (36.70%), government buildings (31.12%), public transport (20.04%), healthcare facilities (17.85%) and schools (15.84%). 13.23% of respondents saw smokers violate smoke-free regulations. Among those who saw them violate smoke-free regulations, just onethird cautioned them to stop smoking. Strikingly, a higher rate of cautioning smokers to stop smoking was observed among the older, married, and better educated respondents. Respondents who were married, better educated and in lower economic status were more likely to remind smokers to stop smoking. Conclusions. The study has called for strengthening two of the six MPOWER (Monitor, Protect, Offer, Warn, Enforce and Raise) components of the tobacco free initiative introduced by WHO, Monitoring tobacco use and prevention policies and Protecting people from tobacco smoke. © 2019 Pacini Editore SPA. All rights reserved. **Please note that there are multiple authors for this article therefore only the name of the first 5 including Federation University Australia affiliate “Huy Nguyen” is provided in this record*

Nanotechnology companies in the United States:a web-based content analysis of companies and products for poverty alleviation

This study analyzes the goals, nanotechnology experience, corporate social responsibility and products of 50 USA-based companies  working with nanotechnology to see if they are developing products that help low-income populations. Out of the top 50 R&D companies that publish and patent nanotechnology research in agri-food, energy and water sectors, 18 of them do not mention nanotechnology on their websites. The other 32 companies discuss nanotechnology in varying degrees. However, only two of the companies relate their nanotechnology R&D to poverty alleviation. Even though few companies refer to poverty alleviation, 30 firms of the sample have some type of corporate social responsibility programs. From the study, we cannot definitively conclude that nanotechnology is a technology only for wealthy consumers, but we do find that the companies analyzed do not give much attention to pro-poor nanotechnology

Extraction and Quantification of Carpaine from Carica papaya Leaves of Vietnam

Our previous research indicated that carpaine and its derivative pseudocarpaine extracted from Carica papaya leaves had anti-cancer activity. In this study, we extracted the total alkaloid from Carica papaya leaves, then extracted carpaine and quantitative analyzed carpaine in the total alkaloid. Carica papaya leaves was crushed, and then extracted with EtOH to obtain the total extract. This extract was extracted with suitable solvent to obtain total alkaloid. Continued to extract the total alkaloid by using open column chromatography and crystallizing method to purify carpaine. The research result showed that the total alkaloid in Carica papaya leaves was 0.2% comparing with dried material. Quantitative analyze of purified carpaine by HPLC determined that carpaine was the main alkaloid with the content was 63% of the total alkaloid extracted from Carica papaya leaves