132 research outputs found
Experimental study on expansion characteristics of core-shell and polymeric microspheres
Traditional polymeric microsphere has several technical advantages in enhancing oil recovery. Nevertheless, its performance in some field application is unsatisfactory due to limited blockage strength. Since the last decade, novel core-shell microsphere has been developed as the next-generation profile control agent. To understand the expansion characteristic differences between these two types of microspheres, we conduct size measurement experiments on the polymeric and core-shell microspheres, respectively. The experimental results show two main differences between them. First, the core-shell microsphere exhibits a unimodal distribution, compared to multimodal distribution of the polymeric microsphere. Second, the average diameter of the core-shell microsphere increases faster than that of the polymeric microsphere in the early stage of swelling, that is, 0-3 days. These two main differences both result from the electrostatic attraction between core-shell microspheres with different hydration degrees. Based on the experimental results, the core-shell microsphere is suitable for injection in the early stage to block the near-wellbore zone, and the polymeric microsphere is suitable for subsequent injection to block the formation away from the well. A simple mathematical model is proposed for size evolution of the polymeric and core-shell microspheres.Pengxiang Diwu, Baoyi Jiang, Jirui Hou, Zhenjiang You, Jia Wang, Liangliang Sun, Ye Ju, Yunbao Zhang and Tongjing Li
From Yellow to Black: Dramatic Changes between Cerium(IV) and Plutonium(IV) Molybdates
New Strategies in Modeling Electronic Structures and Properties with Applications to Actinides
This chapter discusses contemporary quantum chemical methods and provides
general insights into modern electronic structure theory with a focus on
heavy-element-containing compounds. We first give a short overview of
relativistic Hamiltonians that are frequently applied to account for
relativistic effects. Then, we scrutinize various quantum chemistry methods
that approximate the -electron wave function. In this respect, we will
review the most popular single- and multi-reference approaches that have been
developed to model the multi-reference nature of heavy element compounds and
their ground- and excited-state electronic structures. Specifically, we
introduce various flavors of post-Hartree--Fock methods and optimization
schemes like the complete active space self-consistent field method, the
configuration interaction approach, the Fock-space coupled cluster model, the
pair-coupled cluster doubles ansatz, also known as the antisymmetric product of
1 reference orbital geminal, and the density matrix renormalization group
algorithm. Furthermore, we will illustrate how concepts of quantum information
theory provide us with a qualitative understanding of complex electronic
structures using the picture of interacting orbitals. While modern quantum
chemistry facilitates a quantitative description of atoms and molecules as well
as their properties, concepts of quantum information theory offer new
strategies for a qualitative interpretation that can shed new light onto the
chemistry of complex molecular compounds.Comment: 43 pages, 3 figures, Version of Recor
Switching Reversibility to Irreversibility in Glycogen Synthase Kinase 3 Inhibitors: Clues for Specific Design of New Compounds
Structure and Energetics of Ground-State Hypericin: Comparison of Experiment and Theory
Effect of low velocity non-Darcy flow on pressure response in shale and tight oil reservoirs
Low velocity non-Darcy flow in shale and tight oil reservoirs is described by nonlinear or nonhomogeneous models. These models, especially for well shut-in period, are usually solved by numerical method, since the traditional pressure superposition principle is no longer applicable. The current paper presents a modified pressure superposition principle, accounting for the pseudo Threshold Pressure Gradient (TPG), and its mathematical proof. The proposed principle indicates that the total change of bottom hole pressure (BHP) in shut-in period is equal to the superposition of BHP change in a real well with pseudo TPG and that in a virtual well without pseudo TPG. The new principle is applied to the derivation of an analytical solution to the nonhomogeneous problem during the well shut-in period. Type curves calculated from the analytical solution show that the pseudo TPG leads to curve up-warping in switch-on period but down-warping in shut-in period, which agree with previous numerical results, and can be explained by the moving-boundary theory. Throughout the switch-on period, a closed moving-boundary is generated when the pressure gradient is less than the pseudo TPG. The boundary is closer to the well with higher pseudo TPG. However, during the shut-in period, a supply moving-boundary, which was generated during previous production or injection period, is earlier to be reached for virtual well with higher pseudo TPG. The flow is steady state afterwards. Matching of field data by the analytical solution results in the pseudo TPG in the investigation zone. The interpretation of the field case shows that pseudo TPG equals 0.104 MPa/m, generating a pressure drop as high as 6.35 MPa across the investigation zone during the well testing period.Pengxiang Diwu, Tongjing Liu, Zhenjiang You, Baoyi Jiang, Jian Zho
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