1,086 research outputs found
Search for methylamine in high mass hot cores
We aim to detect methylamine, CHNH, in a variety of hot cores and
use it as a test for the importance of photon-induced chemistry in ice mantles
and mobility of radicals. Specifically, CHNH cannot be formed from atom
addition to CO whereas other NH-containing molecules such as formamide,
NHCHO, can. Submillimeter spectra of several massive hot core regions were
taken with the James Clerk Maxwell Telescope. Abundances are determined with
the rotational diagram method where possible. Methylamine is not detected,
giving upper limit column densities between 1.9 6.4 10
cm for source sizes corresponding to the 100 K envelope radius. Combined
with previously obtained JCMT data analyzed in the same way, abundance ratios
of CHNH, NHCHO and CHCN with respect to each other and
to CHOH are determined. These ratios are compared with Sagittarius B2
observations, where all species are detected, and to hot core models. The
observed ratios suggest that both methylamine and formamide are overproduced by
up to an order of magnitude in hot core models. Acetonitrile is however
underproduced. The proposed chemical schemes leading to these molecules are
discussed and reactions that need further laboratory studies are identified.
The upper limits obtained in this paper can be used to guide future
observations, especially with ALMA.Comment: 14 pages, 5 figures, accepted for publication in A&
Evidence for episodic warm outflowing CO gas from the intermediate mass young stellar object IRAS 08470-4321
We present a R=10,000 M-band spectrum of LLN19 (IRAS 08470-4321), a heavily
embedded intermediate-mass young stellar object located in the Vela Molecular
Cloud, obtained with VLT-ISAAC. The data were fitted by a 2-slab cold-hot model
and a wind model. The spectrum exhibits deep broad ro-vibrational absorption
lines of 12CO v=1<-0 and 13CO v=1<-0. A weak CO ice feature at 4.67 micron is
also detected. Differences in velocity indicate that the warm gas is distinct
from the cold millimeter emitting gas, which may be associated with the
absorption by cooler gas (45K). The outflowing warm gas at 300-400K and with a
mass-loss rate varying between 0.48E-7 and 4.2E-7 MSun /yr can explain most of
the absorption. Several absorption lines were spectrally resolved in subsequent
spectra obtained with the VLT-CRIRES instrument. Multiple absorption
substructures in the high-resolution (R=100,000) spectra indicate that the
mass-loss is episodic with at least two major events that occurred recently
(<28 years). The discrete mass-loss events together with the large turbulent
width of the gas (dv=10-12 km/s) are consistent with the predictions of the
Jet-Bow shock outflow and the wide-angle wind model. The CO gas/solid column
density ratio of 20-100 in the line-of-sight confirms that the circumstellar
environment of LLN~19 is warm. We also derive a 12C/13C ratio of 67 +/- 3,
consistent with previous measurements in local molecular clouds but not with
the higher ratios found in the envelope of other young stellar objects.Comment: 16 pages, 12 figures, accepted for publication in MNRA
Photodissociation and photoionisation of atoms and molecules of astrophysical interest
A new collection of photodissociation and photoionisation cross sections for
102 atoms and molecules of astrochemical interest has been assembled, along
with a brief review of the basic processes involved. These have been used to
calculate dissociation and ionisation rates, with uncertainties, in a standard
ultraviolet interstellar radiation field (ISRF) and wavelength-dependent
radiation fields. The new ISRF rates generally agree within 30% with our
previous compilations, with a few notable exceptions. The reduction of rates in
shielded regions was calculated as a function of dust, molecular and atomic
hydrogen, atomic C, and self-shielding column densities. The relative
importance of shielding types depends on the species in question and the dust
optical properties. The new data are publicly available from the Leiden
photodissociation and ionisation database.
Sensitivity of rates to variation of temperature and isotope, and cross
section uncertainties, are tested. Tests were conducted with an
interstellar-cloud chemical model, and find general agreement (within a factor
of two) with the previous iteration of the Leiden database for the ISRF, and
order-of-magnitude variations assuming various kinds of stellar radiation. The
newly parameterised dust-shielding factors makes a factor-of-two difference to
many atomic and molecular abundances relative to parameters currently in the
UDfA and KIDA astrochemical reaction databases. The newly-calculated cosmic-ray
induced photodissociation and ionisation rates differ from current standard
values up to a factor of 5. Under high temperature and cosmic-ray-flux
conditions the new rates alter the equilibrium abundances of abundant dark
cloud abundances by up to a factor of two. The partial cross sections for H2O
and NH3 photodissociation forming OH, O, NH2 and NH are also evaluated and lead
to radiation-field-dependent branching ratios.Comment: Corrected some inconsistent table/figure data. Significant change: Zn
photoionisation rate corrected. Accepted for publication by A&
Disk masses in the Orion Molecular Cloud-2: distinguishing time and environment
The mass evolution of protoplanetary disks is driven by both internal
processes and external factors, such as photoevaporation. Disentangling these
two effects, however, has remained difficult. We measure the dust masses of a
sample of 132 disks in the Orion Molecular Cloud (OMC)-2 region, and compare
them to (i) externally photoevaporated disks in the Trapezium cluster, and (ii)
disks in nearby low-mass star forming regions (SFRs). This allows us to test if
initial disk properties are the same in high- and low-mass SFRs, and enables a
direct measurement of the effect of external photoevaporation on disks. A ~
mosaic of 3 mm continuum observations from the Atacama Large
Millimeter/submillimeter Array (ALMA) was used to measure the fluxes of 132
disks and 35 protostars >0.5 pc away from the Trapezium. We identify and
characterize a sample of 34 point sources not included in the Spitzer catalog
on which the sample is based. Of the disks, 37 (28%) are detected, with masses
ranging from 7-270 M_e. The detection rate for protostars is higher at 69%.
Disks near the Trapezium are found to be less massive by a factor
, implying a mass loss rate of M_sun/yr.
Our observations allow us to distinguish the impact of time and environment on
disk evolution in a single SFR. The disk mass distribution in OMC-2 is
statistically indistinguishable from that in nearby low-mass SFRs, like Lupus
and Taurus. We conclude that age is the main factor determining the evolution
of these disks. This result is robust with respect to assumptions of dust
temperature, sample incompleteness and biases. The difference between the OMC-2
and Trapezium cluster samples is consistent with mass loss driven by
far-ultraviolet radiation near the Trapezium. Together, this implies that in
isolation, disk formation and evolution proceed similarly, regardless of cloud
mass.Comment: Accepted for publication in A&A. 16 pages, 6 figure
Astrochemical confirmation of the rapid evolution of massive YSOs and explanation for the inferred ages of hot cores
Aims. To understand the roles of infall and protostellar evolution on the
envelopes of massive young stellar objects (YSOs).
Methods. The chemical evolution of gas and dust is traced, including infall
and realistic source evolution. The temperatures are determined
self-consistently. Both ad/desorption of ices using recent laboratory
temperature-programmed-desorption measurements are included.
Results. The observed water abundance jump near 100 K is reproduced by an
evaporation front which moves outward as the luminosity increases. Ion-molecule
reactions produce water below 100 K. The age of the source is constrained to t
\~ 8 +/- 4 x 10^4 yrs since YSO formation. It is shown that the chemical
age-dating of hot cores at ~ few x 10^3 - 10^4 yr and the disappearance of hot
cores on a timescale of ~ 10^5 yr is a natural consequence of infall in a
dynamic envelope and protostellar evolution. Dynamical structures of ~ 350AU
such as disks should contain most of the complex second generation species. The
assumed order of desorption kinetics does not affect these results.Comment: Accepted by A&A Letters; 4 pages, 5 figure
On the origin of H_2CO abundance enhancements in low-mass protostars
High angular resolution H_2CO 218 GHz line observations have been carried out toward the low-mass protostars IRAS 16293-2422 and L1448-C using the Owens Valley Millimeter Array at ~2" resolution. Simultaneous 1.37 mm continuum data reveal extended emission which is compared with that predicted by model envelopes constrained from single-dish data. For L1448-C the model density structure works well down to the 400 AU scale to which the interferometer is sensitive. For IRAS 16293-2422 , a known proto-binary object, the interferometer observations indicate that the binary has cleared much of the material in the inner part of the envelope, out to the binary separation of ~800 AU. For both sources there is excess unresolved compact emission centered on the sources, most likely due to accretion disks ≾200 AU in size with masses of ≳0.02 M_☉ (L1448-C) and ≳0.1 M_☉ (IRAS 16293-2422). The H_2CO data for both sources are dominated by emission from gas close to the positions of the continuum peaks. The morphology and velocity structure of the H_2CO array data have been used to investigate whether the abundance enhancements inferred from single-dish modelling are due to thermal evaporation of ices or due to liberation of the ice mantles by shocks in the inner envelope. For IRAS 16293-2422 the H_2CO interferometer observations indicate the presence of rotation roughly perpendicular to the large scale CO outflow. The H_2CO distribution differs from that of C^(18)O, with C^(18)O emission peaking near MM1 and H_2CO stronger near MM2. For L1448-C, the region of enhanced H_2CO emission extends over a much larger scale >1" than the radius of 50-100 K (0."6-0".15) where thermal evaporation can occur. The red-blue asymmetry of the emission is consistent with the outflow; however the velocities are significantly lower. The H_2CO 3_(22)-2_(21)/3_(03)-2_(02) flux ratio derived from the interferometer data is significantly higher than that found from single-dish observations for both objects, suggesting that the compact emission arises from warmer gas. Detailed radiative transfer modeling shows, however, that the ratio is affected by abundance gradients and optical depth in the 3_(03)-2_(02) line. It is concluded that a constant H_2CO abundance throughout the envelope cannot fit the interferometer data of the two H_2CO lines simultaneously on the longest and shortest baselines. A scenario in which the H_2CO abundance drops in the cold dense part of the envelope where CO is frozen out but is undepleted in the outermost region provides good fits to the single-dish and interferometer data on short baselines for both sources. Emission on the longer baselines is best reproduced if the H_2CO abundance is increased by about an order of magnitude from ~ 10^(-10) to ~ 10^(-9) in the inner parts of the envelope due to thermal evaporation when the temperature exceeds ~50 K. The presence of additional H_2CO abundance jumps in the innermost hot core region or in the disk cannot be firmly established, however, with the present sensitivity and resolution. Other scenarios, including weak outflow-envelope interactions and photon heating of the envelope, are discussed and predictions for future generation interferometers are presented, illustrating their potential in distinguishing these competing scenarios
Results from a VLT-ISAAC survey of ices and gas around young stellar objects
General results from a 3-5 micron spectroscopic survey of nearby low-mass
young stellar objects are presented. L and M-band spectra have been obtained of
\~50 low mass embedded young stars using the ISAAC spectrometer mounted on
UT1-Antu at Paranal Observatory. For the first time, a consistent census of the
CO, H2O ices and the minor ice species CH3OH and OCN- and warm CO gas present
around young stars is obtained, using large number statistics and resolving
powers of up to R=10000. The molecular structure of circumstellar CO ices, the
depletion of gaseous CO onto grains in protoplanetary disks, the presence of
hot gas in the inner parts of circumstellar disks and in outflows and infalls
are studied. Furthermore, the importance of scattering effects for the
interpretation of the spectra have been addressed.Comment: To appear in the proceedings of the conference "Chemistry as a
Diagnostic of Star Formation", University of Waterloo, Canada, 21-23 August
200
The deuterium fractionation of water on solar-system scales in deeply-embedded low-mass protostars
(Abridged) The water deuterium fractionation (HDO/HO abundance ratio) has
traditionally been used to infer the amount of water brought to Earth by
comets. Measuring this ratio in deeply-embedded low-mass protostars makes it
possible to probe the critical stage when water is transported from clouds to
disks in which icy bodies are formed. We present sub-arcsecond resolution
observations of HDO in combination with HO from the PdBI toward the
three low-mass protostars NGC 1333-IRAS 2A, IRAS 4A-NW, and IRAS 4B. The
resulting HDO/HO ratio is for IRAS 2A,
for IRAS 4A-NW, and for IRAS
4B. Derived ratios agree with radiative transfer models within a factor of 2-4
depending on the source. Our HDO/HO ratios for the inner regions (where
K) of four young protostars are only a factor of 2 higher than those
found for pristine, solar system comets. These small differences suggest that
little processing of water occurs between the deeply embedded stage and the
formation of planetesimals and comets.Comment: 10 pages, 6 figures, accepted for publication in Astronomy and
Astrophysic
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