Indium-Containing Visible-Light-Driven (VLD) Photocatalysts for Solar Energy Conversion and Environment Remediation

Indium-containing visible-light-driven (VLD) photocatalysts including indium-containing oxides, indium-containing sulfides, indium-containing hydroxides, and other categories have attracted more attention due to their high catalytic activities for oxidation and reduction ability under visible light irradiation. This chapter will therefore concentrate on indium-containing nano-structured materials that demonstrate useful activity under solar excitation in fields concerned with the elimination of pollutants, partial oxidation and the vaporization of chemical compounds, water splitting, and CO2 reduction processes. The indium-containing photocatalysts can extend the light absorption range and improve the photocatalytic activity by doping, heterogeneous structures, load promoter, and morphology regulation. A number of synthetic and modification techniques for adjusting the band structure to harvest visible light and improve the charge separation in photocatalysis are discussed. In this chapter, preparation, properties, and potential applications of indium-containing nano-structured materials used as photocatalysis will be systematically summarized, which is beneficial for understanding the mechanism and developing the potential applications

Ellipticity-dependent sequential over-barrier ionization of cold rubidium

We perform high-resolution measurements of momentum distribution on Rb$^{n+}$ recoil ions up to charge state $n=4$, where laser-cooled rubidium atoms are ionized by femtosecond elliptically polarized lasers with the pulse duration of 35 fs and the intensity of 3.3$\times$10$^{15}$ W/cm$^2$ in the over-barrier ionization (OBI) regime. The momentum distributions of the recoil ions are found to exhibit multi-band structures as the ellipticity varies from the linear to circular polarizations. The origin of these band structures can be explained quantitatively by the classical OBI model and dedicated classical trajectory Monte Carlo simulations with Heisenberg potential. Specifically, with back analysis of the classical trajectories, we reveal the ionization time and the OBI geometry of the sequentially released electrons, disentangling the mechanisms behind the tilted angle of the band structures. These results indicate that the classical treatment can describe the strong-field multiple ionization processes of alkali atoms

Transition of the generation mechanism of high-order harmonics in an extended neon system

Using a time-dependent density functional theory method, we perform a systematic numerical study of the transition of high-order harmonic generation in neon (Ne) systems from an isolated Ne atom to an extended Ne system of solid density. We show that ionized electrons wander in such extended systems until they meet a nearby ion and collide with it. The maximum energy edge for the main feature of the high-order harmonic spectrum in this “wandering electron” picture is determined as Eedge = Ip + 8Up, where Ip is the ionization energy of Ne and Up is the ponderomotive energy delivered by the driving laser. The factor of 8 comes from the maximum kinetic energy of an ionized electron in the driving laser field. Beyond the atomic limit of high-order harmonic spectra, a multiplatform feature is observed, corresponding to re-collisions of ionized electrons with their nearby ions. It is also shown that a Ne simple cubic lattice of appropriate size provides a selection condition for the direction of polarization of high-order harmonics beyond the atomic limit, which may be further used to manipulate the emitted radiation

Design, Synthesis and Antiproliferative Activity of Novel 2-Substituted-4-amino-6-halogenquinolines

Two series of novel 2-substituted-4-amino-6-halogenquinolines 8a–l and 13a–h were designed, synthesized and evaluated for their antiproliferative activity against H-460, HT-29, HepG2 and SGC-7901 cancer cell lines in vitro. The pharmacological results indicated that most compounds with 2-arylvinyl substituents exhibited good to excellent antiproliferative activity. Among them, compound 8e was a considered promising lead for further structural modifications with IC50 values of 0.03 μM, 0.55 μM, 0.33 μM and 1.24 μM, which was 2.5- to 186-fold more active than gefitinib and compound 1

Multiphoton double ionization of Ar and Ne close to Threshold

In kinematically complete studies we explore double ionization (DI) of Ne and Ar in the threshold regime (I>3×1013W/cm2) for 800 nm, 45 fs pulses. The basic differences are found in the two-electron momentum distributions-"correlation" (CO) for Ne and " anticorrelation" (ACO) for Ar-that can be partially explained theoretically within a 3D classical model including tunneling. Transverse electron momentum spectra provide insight into "Coulomb focusing" and point to correlated nonclassical dynamics. Finally, DI threshold intensities, CO as well as ACO regimes are predicted for both targets. © 2010 The American Physical Society

Genomic and Transcriptomic Insights into the Evolution and Divergence of MIKC-Type MADS-Box Genes in <i>Carica papaya</i>

MIKC-type MADS-box genes, also known as type II genes, play a crucial role in regulating the formation of floral organs and reproductive development in plants. However, the genome-wide identification and characterization of type II genes as well as a transcriptomic survey of their potential roles in Carica papaya remain unresolved. Here, we identified and characterized 24 type II genes in the C. papaya genome, and investigated their evolutional scenario and potential roles with a widespread expression profile. The type II genes were divided into thirteen subclades, and gene loss events likely occurred in papaya, as evidenced by the contracted member size of most subclades. Gene duplication mainly contributed to MIKC-type gene formation in papaya, and the duplicated gene pairs displayed prevalent expression divergence, implying the evolutionary significance of gene duplication in shaping the diversity of type II genes in papaya. A large-scale transcriptome analysis of 152 samples indicated that different subclasses of these genes showed distinct expression patterns in various tissues, biotic stress response, and abiotic stress response, reflecting their divergent functions. The hub-network of male and female flowers and qRT-PCR suggested that TT16-3 and AGL8 participated in male flower development and seed germination. Overall, this study provides valuable insights into the evolution and functions of MIKC-type genes in C. papaya

Electron correlation dynamics of strong-field double ionization of atoms below recollision threshold

In recent combined experimental and theoretical study we have explored nonsequential double ionization of neon and argon atoms in the infrared light field (800nm) below the recollision threshold. We find that the two-electron correlation dynamics depends on atomic structure- "side-by-side emission" (correlation) for Ne and "back-to-back emission" (anticorrelation) for argon atoms. This can be explained theoretically within our three dimensional classical model calculation including tunnelling effect. The multiple recollisions as well as recollision-induced-excitation-tunnelling (RIET) effect dominate the anticorrelation of argon, whereas the laser-assisted instantaneous recollision dominates the correlation of neon