10Be in the Akademii Nauk ice core – first results for CE 1590-1950 and implications for future chronology validation

Temporal variations of the radionuclide 10Be are broadly synchronous across the globe and thus provide a powerful tool to synchronize ice core chronologies from different locations. We compared the 10Be record of the Akademii Nauk (AN) ice core (Russian Arctic) for the time period CE 1590–1950 to the 10Be records of two well-dated Greenland ice cores (Dye3 and NGRIP). A high correlation (r = 0.59) was found between the AN and Dye3 records whereas the correlation with NGRIP was distinctly lower (r = 0.45). Sources of deviations may include local fluctuations in the deposition of 10Be due to changes in the precipitation patterns, and artefacts due to the core-sampling strategy. In general, the existing age model was validated, confirming the AN ice core to be a unique and well-dated source of palaeoclimate parameters for the Russian Arctic. We further used numerical simulations to test the influence of the core-sampling strategy on the results and derived an optimized sampling strategy for the deeper parts of the ice core

The Akademii Nauk ice core and solar activity

Ice cores are well established archives for paleo-environmental studies, but this requires a reliable ice core chronology. The concentration of cosmogenic radionuclides in ice cores reflects the solar activity in the past and can be used as dating tool for ice cores. Accelerator mass spectrometry (AMS) allows the determination of nuclides in high resolution. Here we present results of a 10Be study in an ice core from Akademii Nauk (Severnaya Zemlya, Russian Arctic). AMS analyses of more than 500 samples were carried out using the 6 MV accelerator facility of the Ion Beam Centre of the Helmholtz-Zentrum Dresden-Rossendorf. For the time period 400 to 2000 CE the temporal variations of 10Be reflect the centennial variations of solar activity known from similar studies of Greenlandic ice cores and from 14C production reconstructions. The 10Be peak of 775 CE, today understood as result of the strongest known solar particle storm, was found by high resolution core analysis. This peak is used as tie point (additionally to volcanic reference horizons) for the development of the depth-age relationship of the Akademii Nauk ice core. Indications of the so called “Carrington Event” of 1859 CE, 20 to 30 times weaker than 775 CE, could also be detected in the core

Aromatic acids in a Eurasian Arctic ice core: a 2,600-year proxy record of biomass burning

Wildfires and their emissions have significant impacts on ecosystems, climate, atmospheric chemistry, and carbon cycling. Well-dated proxy records are needed to study the long-term climatic controls on biomass burning and the associated climate feedbacks. There is a particular lack of information about long-term biomass burning variations in Siberia, the largest forested area in the Northern Hemisphere. In this study we report analyses of aromatic acids (vanillic and para-hydroxybenzoic acids) over the past 2600 years in the Eurasian Arctic Akademii Nauk ice core. These compounds are aerosol-borne, semi-volatile organic compounds derived from lignin combustion. The analyses were made using ion chromatography with electrospray mass spectrometric detection. The levels of these aromatic acids ranged from below the detection limit (0.01 to 0.05 ppb; 1 ppb  =  1000 ng L−1) to about 1 ppb, with roughly 30 % of the samples above the detection limit. In the preindustrial late Holocene, highly elevated aromatic acid levels are observed during three distinct periods (650–300 BCE, 340–660 CE, and 1460–1660 CE). The timing of the two most recent periods coincides with the episodic pulsing of ice-rafted debris in the North Atlantic known as Bond events and a weakened Asian monsoon, suggesting a link between fires and large-scale climate variability on millennial timescales. Aromatic acid levels also are elevated during the onset of the industrial period from 1780 to 1860 CE, but with a different ratio of vanillic and para-hydroxybenzoic acid than is observed during the preindustrial period. This study provides the first millennial-scale record of aromatic acids. This study clearly demonstrates that coherent aromatic acid signals are recorded in polar ice cores that can be used as proxies for past trends in biomass burning

A method for continuous239Pu determinations in Arctic and Antarctic ice cores

Atmospheric nuclear weapons testing (NWT) resulted in the injection of plutonium (Pu) into the atmosphere and subsequent global deposition. We present a new method for continuous semi-quantitative measurement of 239Pu in ice cores, which was used to develop annual records of fallout from NWT in ten ice cores from Greenland and Antarctica. The 239Pu was measured directly using an Inductively Coupled Plasma – Sector Field Mass Spectrometer, thereby reducing analysis time and increasing depth-resolution with respect to previous methods. To validate this method, we compared our one year averaged results to published 239Pu records and other records of NWT. The 239Pu profiles from four Arctic ice cores reflected global trends in NWT and were in agreement with discrete Pu profiles from lower latitude ice cores. The 239Pu measurements in the Antarctic ice cores tracked low latitude NWT, consistent with previously published discrete records from Antarctica. Advantages of the continuous 239Pu measurement method are (1) reduced sample preparation and analysis time; (2) no requirement for additional ice samples for NWT fallout determinations; (3) measurements are exactly co-registered with all other chemical, elemental, isotopic, and gas measurements from the continuous analytical system; and (4) the long half-life means the 239Pu record is stable through time