8,550 research outputs found
nZVI particles production for the remediation of soil and water polluted by inorganic Lead
The present study deals with experiments of Pb removal by
nano-Zero Valent Iron (nZVI) in aqueous solution and in
soil. Synthetic Pb aqueous solutions were treated by nZVI,
at a fixed Pb concentration of 100 mg L-1
, varying
nanoparticles initial concentration in the range between 27
and 270 mg nZVI L-1
. A kinetic study was carried out: Pb
adsorption followed a first order kinetic, and half life times
between 11 and 26.66 min were determined. Soil samples
were first characterized, and Pb speciation and
concentration by sequential extractions was determined.
Adsorption tests were then carried out at three selected
amounts of nZVI, to allow Pb stabilization in the soil
matrix. To evaluate the treatment efficiency, sequential
extractions were also performed on the treated samples
A deeper insight into quantum state transfer from an information flux viewpoint
We use the recently introduced concept of information flux in a many-body
register in order to give an alternative viewpoint on quantum state transfer in
linear chains of many spins.Comment: 6 pages, 3 figures, RevTeX
An efficient flamelet progress-variable method for modeling non-premixed flames in weak electric fields
Combustion stabilization and enhancement of the flammability limits are
mandatory objectives to improve nowadays combustion chambers. At this purpose,
the use of an electric field in the flame region provides a solution which is,
at the same time, easy to implement and effective to modify the flame
structure. The present work describes an efficient flamelet progress-variable
approach developed to model the fluid dynamics of flames immersed in an
electric field. The main feature of this model is that it can use complex
ionization mechanisms without increasing the computational cost of the
simulation. The model is based on the assumption that the combustion process is
not directly influenced by the electric field and has been tested using two
chemi-ionization mechanisms of different complexity in order to examine its
behavior with and without the presence of heavy anions in the mixture. Using a
one- and two-dimensional numerical test cases, the present approach has been
able to reproduce all the major aspects encountered when a flame is subject to
an imposed electric field and the main effects of the different chemical
mechanisms. Moreover, the proposed model is shown to produce a large reduction
in the computational cost, being able to shorten the time needed to perform a
simulation up to 40 times.Comment: 26 pages, 13 figures, paper accepted for publication on Computers and
Fluid
Chromium recovery by membranes for process reuse in the tannery industry
Leather tanning is a wide common industry all over the
world. In leather processing, water is one of the most
important medium, almost 40-45 L water kg-1 raw-hide or
skin is used by tanneries for processing finished leathers.
The composition of tannery wastewater presents
considerable dissimilarities in the concentration range of
pollutants both of inorganic (chlorides, with concentration
ranging from several hundred to over 10,000 mg L-1 Cl–;
sulphate (VI), ammonium ions and sulphide ions,
exhibiting concentration that ranges from tens to several
hundred mg L-1) and organic (the COD value is usually
several thousand mg L-1 O2). Throughout the years, many
conventional processes have been carried out to treat
wastewater from tannery industry: unfortunately, in this
case, biological treatment methods give rise to an
excessive production of sludge, whereas physical and
chemical methods are too expensive in terms of energy and
reagent costs. In this work, a membrane process based on
NF membrane modules was adopted to treat the tannery
feedstock after primary conventional treatment. In a first
step, the determination of all boundary flux parameters, in
order to inhibit severe fouling formation during operation,
were performed. After this, experimental work was carried
out to validate the approach. The target of water
purification was reached, that is the legal discharge to
municipal sewer system in Italy of 90% of the initial
wastewater stream volume. This allows having an
immediate cost saving of 21%. Moreover, the developed
process leads to a second benefit, that is the production of
5% of the initial volume as a highly chromium-rich
concentrate at no cost suitable to tannery process recycle
and reuse. In this case, cost saving rates exceeds 40%. At
the end, scale-up of the investigated process will be
discussed from technical and economic point of view
Ligand-induced stabilization of the aptamer terminal helix in the add adenine riboswitch
Riboswitches are structured mRNA elements that modulate gene expression. They undergo conformational changes triggered by highly specific interactions with sensed metabolites. Among the structural rearrangements engaged by riboswitches, the forming and melting of the aptamer terminal helix, the so called P1 stem, is essential for genetic control. The structural mechanisms by which this conformational change is modulated upon ligand binding mostly remain to be elucidated. Here, we used pulling molecular dynamics simulations to study the thermodynamics of the P1 stem in the add adenine riboswitch. The P1 ligand-dependent stabilization was quantified in terms of free energy and compared with thermodynamic data. This comparison suggests a model for the aptamer folding in which direct P1-ligand interactions play a minor role on the conformational switch when compared with those related to the ligand-induced aptamer preorganization
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