Considerations on the hydrogen peroxide electrogeneration

This paper presents some results that may be used as previous considerations to a hydrogen peroxide electrogeneration process design. A kinetic study of oxygen dissolution in aqueous solution is carried out and rate constants for oxygen dissolution are calculated. Voltammetric experiments on vitreous carbon cathode shown that the low saturation concentration drives the oxygen reduction process to a mass transfer controlled process which exhibits low values of limiting currents. Results have shown that the hydrogen peroxide formation and its decomposition to water are separated by 400 mV on the vitreous carbon surface. Diffusion coefficients for oxygen and hydrogen peroxide are calculated using data taken from Levich and Tafel plots. In a series of bulk electrolysis experiments hydrogen peroxide was electrogenerated at several potential values, and concentration profiles as a function of the electrical charged passed were obtained. Data shown that, since limiting current plateaus are poorly defined onto reticulated vitreous carbon, cathodic efficiency may be a good criterion for choosing the potential value in which hydrogen peroxide electrogeneration should be carried out.25225

Electrolytic removal of metals using a flow-through cell with a reticulated vitreous carbon cathode

The aim of the present study was to establish an electrolytic method for the removal of metals from wastewater using a three dimensional, reticulated vitreous carbon cathode. During the development of the experimental set up, particular attention was paid to the electrolyte flow rate and to the cathode porosity. The electrolytic cell employed potential values in such a way that the metals reduction reaction occurred under mass transport control. These potentials were determined by hydrodynamic voltammetry on a vitreous carbon rotating disc electrode. The cell proved to be efficient in removing copper, zinc and lead and it was able to reduce the levels of these metals from 50 mg/L to 0.1 mg/L.O objetivo do presente trabalho foi estabelecer um processo eletrolítico para remover metais de efluentes aquosos usando um catodo tridimensional de carbono vítreo reticulado. Durante o desenvolvimento do trabalho foi estudado a influência do fluxo do eletrólito e da porosidade do eletrodo. A célula eletrolítica utilizou potenciais tais que a reação de redução ocorreu sob controle de transporte de massa. A célula demonstrou eficiência na remoção de chumbo, zinco e cobre, reduzindo a concentração desses metais de 50 mg.L-1 a 0,1 mg.L-1 em 20 min de recirculação da solução.48749

Considerações sobre a eletrogeração de peróxido de hidrogênio

This paper presents some results that may be used as previous considerations to a hydrogen peroxide electrogeneration process design. A kinetic study of oxygen dissolution in aqueous solution is carried out and rate constants for oxygen dissolution are calculated. Voltammetric experiments on vitreous carbon cathode shown that the low saturation concentration drives the oxygen reduction process to a mass transfer controlled process which exhibits low values of limiting currents. Results have shown that the hydrogen peroxide formation and its decomposition to water are separated by 400 mV on the vitreous carbon surface. Diffusion coefficients for oxygen and hydrogen peroxide are calculated using data taken from Levich and Tafel plots. In a series of bulk electrolysis experiments hydrogen peroxide was electrogenerated at several potential values, and concentration profiles as a function of the electrical charged passed were obtained. Data shown that, since limiting current plateaus are poorly defined onto reticulated vitreous carbon, cathodic efficiency may be a good criterion for choosing the potential value in which hydrogen peroxide electrogeneration should be carried out

Electrolytic removal of metals using a flow-through cell with a reticulated vitreous carbon cathode

The aim of the present study was to establish an electrolytic method for the removal of metals from wastewater using a three dimensional, reticulated vitreous carbon cathode. During the development of the experimental set up, particular attention was paid to the electrolyte flow rate and to the cathode porosity. The electrolytic cell employed potential values in such a way that the metals reduction reaction occurred under mass transport control. These potentials were determined by hydrodynamic voltammetry on a vitreous carbon rotating disc electrode. The cell proved to be efficient in removing copper, zinc and lead and it was able to reduce the levels of these metals from 50 mg/L to 0.1 mg/L

Comparative Study of Commercial Oxide Electrodes Performance in Electrochemical Degradation of Organics in Aqueous Solutions

In this paper the potentiality of two types of DSAâ commercial electrodes, for electrochemical treatment of effluents, is investigated. Oxide anodes, with nominal composition of 70TiO2/30RuO2 and 45IrO2/55Ta2O5, were used in a flow-cell reactor for the electrooxidation of phenol. Comparative results were presented as phenol concentration decay as a function of electrolysis time, as well as COD and TOC concentration reduction. The cell reactor was operated at current densities, ranging from 15 to 150 mA cm-2 and solution linear velocity was 0.24 m s-1. Results reported in this paper showed that phenol and quinones were degraded to a very low concentration, besides only a small portion of the organic carbon is reduced. Starting from 100 mg L-1, after five hours of electrolysis at 100 mA cm-2, concentrations reached 0.4 mg L-1 of phenol, 1 mg L-1 of hydroquinone, 7 mg L-1 of benzoquinone and TOC was reduced by 35%.Neste trabalho foi realizado um estudo visando a potencial aplicação de dois eletrodos comerciais tipo DSAâ no tratamento eletroquímico de efluentes aquosos. Anodos com composição superficial 70TiO2/30RuO2 e 45IrO2/55Ta2O5 foram usados num reator de fluxo com densidades de corrente de 15 a 150 mA.cm-2 e velocidade da solução de 0,24 m.s-1. Os resultados mostram que fenol e as quinonas são degradados até concentrações muito baixas, embora apenas uma pequena fração seja mineralizada. A partir de uma solução com 100 mg.L-1 de fenol, a 100 mA.cm-2, após cinco horas de eletrólise foram encontrados 0,4 mg.L-1 de fenol, 1 mg.L-1 de hidroquinona e 7 mg.L-1 de benzoquinona. TOC foi reduzido em 35%.606