High-throughput in-situ characterization and modelling of precipitation kinetics in compositionally graded alloys

The development of new engineering alloy chemistries is a time consuming and iterative process. A necessary step is characterization of the nano/microstructure to provide a link between the processing and properties of each alloy chemistry considered. One approach to accelerate the identification of optimal chemistries is to use samples containing a gradient in composition, ie. combinatorial samples, and to investigate many different chemistries at the same time. However, for engineering alloys, the final properties depend not only on chemistry but also on the path of microstructure development which necessitates characterization of microstructure evolution for each chemistry. In this contribution we demonstrate an approach that allows for the in-situ, nanoscale characterization of the precipitate structures in alloys, as a function of aging time, in combinatorial samples containing a composition gradient. The approach uses small angle x-ray scattering (SAXS) at a synchrotron beamline. The Cu-Co system is used for the proof-of-concept and the combinatorial samples prepared contain a gradient in Co from 0% to 2%. These samples are aged at temperatures between 450{\textdegree}C and 550{\textdegree}C and the precipitate structures (precipitate size, volume fraction and number density) all along the composition gradient are simultaneously monitored as a function of time. This large dataset is used to test the applicability and robustness of a conventional class model for precipitation that considers concurrent nucleation, growth and coarsening and the ability of the model to describe such a large dataset.Comment: Published in Acta Materiali

Sea surface temperature of the coastal zones of France

Thermal gradients in French coastal zones for the period of one year were mapped in order to enable a coherent study of certain oceanic features detectable by the variations in the sea surface temperature field and their evolution in time. The phenomena examined were mesoscale thermal features in the English Channel, the Bay of Biscay, and the northwestern Mediterranean; thermal gradients generated by French estuary systems; and diurnal heating in the sea surface layer. The investigation was based on Heat Capacity Mapping Mission imagery

Sea surface temperature of the coastal zones of France

The results of an investigation to map the various thermal gradients in the coastal zones of France are presented. Paricular emphasis is given to the natural phenomena and man made thermal effluents. It is shown that a close correlation exist between wind speed direction and the offshore width of the effluent

Effects of Gas Compressibility and Piston Secondary Motion on Leakage in the Piston-Cylinder Clearance of Reciprocating Compressors

Leakage can significantly affect the performance of low-capacity reciprocating compressors, reducing the mass flow rate and increasing energy consumption. In reciprocating compressors, leakage takes place mainly in the piston-cylinder clearance and is brought about by the piston motion and pressure difference between the compression chamber and the shell internal environment. This paper reports a numerical analysis of leakage in the piston-cylinder clearance of a low-capacity reciprocating compressors based on the Reynolds equation for compressible fluid flow. A simulation model is developed and applied throughout the compression cycle to assess the effect of the clearance geometry, piston velocity and piston secondary motion on the leakage and compressor performance. A simplified version of the model considering the piston concentric in the cylinder is also adopted to assess the effect of the piston secondary motion on leakage. The results show that the compressibility effects are significant and have to be considered in the analysis and that the piston secondary motion can increase gas leakage by 90%

Hox genes and regional patterning of the vertebrate body plan

Several decades have passed since the discovery of Hox genes in the fruit fly Drosophila melanogaster. Their unique ability to regulate morphologies along the anteroposterior (AP) axis (Lewis, 1978) earned them well-deserved attention as important regulators of embryonic development. Phenotypes due to loss- and gain-of-function mutations in mouse Hox genes have revealed that the spatio-temporally controlled expression of these genes is critical for the correct morphogenesis of embryonic axial structures. Here, we review recent novel insight into the modalities of Hox protein function in imparting specific identity to anatomical regions of the vertebral column, and in controlling the emergence of these tissues concomitantly with providing them with axial identity. The control of these functions must have been intimately linked to the shaping of the body plan during evolution.Fundação para Ciência e a Tecnologia grants: (PTDC/BIA-BCM/71619/2006, POCTI-ISFL-4-664); National Institutes of Health grants: (DK071929, AR057018); Dutch NWO ALW; EU FP6 Network of Excellence: (“Cells into Organs”); Dutch Bsik programme: (“Stem Cells into Development and Disease”)

Implications of CP violating 2HDM in B physics

The charged fermion mass matrices are invariant under $U(1)^3$ symmetry linked to the fermion number transformation. Under the condition that the definition of this symmetry in arbitrary weak basis does not depend upon Higgs parameters such as ratio of vacuum expectation values, a class of two Higgs doublet models (2HDM) can be identified in which tree level flavor changing neutral currents normally present in 2HDM are absent. However unlike the type I or type II Higgs doublet models, the charged Higgs couplings in these models contain additional flavor dependent CP violating phases. These phases can account for the recent hints of the beyond standard model CP violation in the $B_d$ and $B_s$ mixing. In particular, there is a range of parameters in which new phases do not contribute to the $K$ meson CP violation but give identical new physics phases in the $B_d$ and $B_s$ meson mixing.Comment: 7 pages, 1 figure, Talk given by Bhavik P. Kodrani at 16th International Symposium on Particles, Strings and Cosmology, July 19th - 23rd, 2010, Valencia, Spai