Experimental and numerical signatures of dynamical crossover in orientationally disordered crystals

By means of NMR experiment and MD computer simulation we investigate the dynamical properties of a chloroadamantane orientationally disordered crystal. We find a plastic-plastic dynamical transition at T_x ~ 330 K in the pico-nanosecond regime. It is interpreted as the rotational analogue of the Goldstein crossing temperature between quasi-free diffusion and activated regime predicted in liquids. Below T_x, NMR experimental data are well described by a Frenkel model corresponding to a strongly anisotropic motion. At higher temperatures, a drastic deviation is observed toward quasi-isotropic rotational diffusion. Close to T_x, we observe that two-step relaxations emerge. An interpretation which is based on the present study of a specific heat anomaly detected by a recent calorimetric experiment is proposed.Comment: 4 pages, 4 figures; changed abstract and references; corrected figure

Controlling instabilities along a 3DVar analysis cycle by assimilating in the unstable subspace: a comparison with the EnKF

A hybrid scheme obtained by combining 3DVar with the Assimilation in the Unstable Subspace (3DVar-AUS) is tested in a QG model, under perfect model conditions, with a fixed observational network, with and without observational noise. The AUS scheme, originally formulated to assimilate adaptive observations, is used here to assimilate the fixed observations that are found in the region of local maxima of BDAS vectors (Bred vectors subject to assimilation), while the remaining observations are assimilated by 3DVar. The performance of the hybrid scheme is compared with that of 3DVar and of an EnKF. The improvement gained by 3DVar-AUS and the EnKF with respect to 3DVar alone is similar in the present model and observational configuration, while 3DVar-AUS outperforms the EnKF during the forecast stage. The 3DVar-AUS algorithm is easy to implement and the results obtained in the idealized conditions of this study encourage further investigation toward an implementation in more realistic contexts

The Origin of (90) Antiope From Component-Resolved Near-Infrared Spectroscopy

The origin of the similary-sized binary asteroid (90) Antiope remains an unsolved puzzle. To constrain the origin of this unique double system, we recorded individual spectra of the components using SPIFFI, a near-infrared integral field spectrograph fed by SINFONI, an adaptive optics module available on VLT-UT4. Using our previously published orbital model, we requested telescope time when the separation of the components of (90) Antiope was larger than 0.087", to minimize the contamination between components, during the February 2009 opposition. Several multi-spectral data-cubes in J band (SNR=40) and H+K band (SNR=100) were recorded in three epochs and revealed the two components of (90) Antiope. After developing a specific photometric extraction method and running an error analysis by Monte-Carlo simulations, we successfully extracted reliable spectra of both components from 1.1 to 2.4 um taken on the night of February 21, 2009. These spectra do not display any significant absorption features due to mafic mineral, ices, or organics, and their slopes are in agreement with both components being C- or Cb- type asteroids. Their constant flux ratio indicates that both components' surface reflectances are quite similar, with a 1-sigma variation of 7%. By comparison with 2MASS J, H, K color distribution of observed Themis family members, we conclude that both bodies were most likely formed at the same time and from the same material. The similarly-sized system could indeed be the result of the breakup of a rubble-pile proto-Antiope into two equal-sized bodies, but other scenarios of formation implying a common origin should also be considered.Comment: 46 pages, 1 table, 11 figures accepted for publication to Icaru

Analogy of the slow dynamics between the supercooled liquid and the supercooled plastic crystal states of difluorotetrachloroethane

Slow dynamics of difluorotetrachloroethane in both supercooled plastic crystal and supercooled liquid states have been investigated from Molecular Dynamics simulations. The temperature and wave-vector dependence of collective dynamics in both states are probed using coherent dynamical scattering functions $S(Q,t)$. Our results confirm the strong analogy between molecular liquids and plastic crystals for which $\alpha$-relaxation times and non-ergodicity parameters are controlled by the non trivial static correlations $S(Q)$ as predicted by the Mode Coupling Theory. The use of infinitely thin needles distributed on a lattice as model of plastic crystals is discussed

Perspectives de vaccination anti-dermatophytique chez les carnivores domestiques

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