Applicability of non-exhaustive extraction procedures with Tenax and HPCD

Chemical extraction techniques like non-exhaustive extraction with Tenax or hydroxypropyl--cyclodextrin (HPCD) have been shown to measure the biodegradable fraction of aromatic contaminants like PAHs in soil. However, there is little research on the chemical prediction of aliphatic hydrocarbon degradation. The aim of this study was to investigate the potential for HPCD and Tenax extractions to predict PAH and petroleum hydrocarbon biodegradation in soil. 11 historically contaminated soils with PAH concentrations between 74 and 680 mg/kg and concentrations of petroleum hydrocarbons from 330 to 4704 mg/kg were analysed. Both non-exhaustive extraction procedures showed promising results for estimating the available contaminant fraction of both contaminant groups concerning the feasibility, reproducibility and correlation with soil biodegradation applying single point testing. Both methods have the potential to be used to assess the biodegradable hydrophobic organic polluta nt fraction in contaminated soils. In a direct comparison of the two extraction procedures, Tenax extraction is assessed to be more time-consuming than HPCD extraction. Furthermore, a sufficient soil/Tenax ratio has to be considered

Bewertungsmastäbe zur Beurteilung von Schadstoffbelastungen in Böden anhand der Bioverfügbarkeit: Zielstellung des Verbundvorhabens BioRefine

Until now, assessment of contaminated sites is based on variable protection goals, whereby total contents and in part mobile contents are considered. Due to interactions of pollutants in soil and bound residues, total contents do not reflect the actual risk. In contrast an investigation based on availability/bioavailability of contaminants would enable a harmonization of the protection-goal-based evaluation and a closer-to-reality risk assessment for the individual location

A multiple-rendezvous, sample-return mission to two near-Earth asteroids

International audienceWe propose a dual-rendezvous mission, targeting near-Earth asteroids, including sample-return. The mission, Asteroid Sampling Mission (ASM), consists of two parts: (i) flyby and remote sensing of a Q-type asteroid, and (ii) sampling of a V-type asteroid. The targeted undifferentiated Q-type are found mainly in the near-Earth space, and to this date have not been the target of a space mission. We have chosen, for our sampling target, an asteroid from the basaltic class (V-type), as asteroids in this class exhibit spectral signatures that resemble those of the well-studied Howardite-Eucrite-Diogenite (HED) meteorite suite. With this mission, we expect to answer specific questions about the links between differentiated meteorites and asteroids, as well as gain further insight into the broader issues of early Solar System (SS) evolution and the formation of terrestrial planets. To achieve the mission, we designed a spacecraft with a dry mass of less than 3 tonnes that uses electric propulsion with a solar-electric power supply of 15 kW at 1 Astronomical Unit (AU). The mission includes a series of remote sensing instruments, envisages landing of the whole spacecraft on the sampling target, and employs an innovative sampling mechanism. Launch is foreseen to occur in 2018, as the designed timetable, and the mission would last about 10 years, bringing back a 150 g subsurface sample within a small re-entry capsule. This paper is a work presented at the 2008 Summer School Alpbach,"Sample return from the Moon, asteroids and comets" organized by the Aeronautics and Space Agency of the Austrian Research Promotion Agency. It is co-sponsored by ESA and the national space authorities of its Member and Co-operating States, with the support of the International Space Science Institute and Austrospace