The Dalradian rocks of the Shetland Islands, Scotland

Metasedimentary and metavolcanic rocks to the east of the Walls Boundary Fault on Shetland have lithological similarities to those of the Dalradian Supergroup of the Scottish mainland. In particular, the middle part of the succession, termed the Whiteness Group, includes numerous metalimestones and associated pelites in a shallow-marine succession that recalls the upper parts of the Appin Group and the Argyll Group of mainland Scotland. Metavolcanic rocks within the deeper water turbiditic sequence of the succeeding Clift Hills Group might be broadly coeval with those of the Southern Highland Group of Scotland. Beyond that, correlations with the established Dalradian succession are tenuous and are not possible at formation level. A local succession immediately west of the Walls Boundary Fault is of even more-dubious Dalradian affinity. The dominant structure is the regional-scale, downward- and east-facing East Mainland Mega-monocline. This has a vertical western limb, which youngs to the east, and an eastern top limb that dips to the north-west at 20–30°. Strata on the eastern limb are inverted on Mainland, Whalsay and Out Skerries but are right way up on the west side of Unst, having been folded around the tight Valla Field Anticline. The Shetland Ophiolite-complex has been thrust over the inverted limb of the Valla Field Anticline on the east side of Unst. The regional monocline folds earlier small- to medium-scale, tight to isoclinal folds with associated planar and linear structures, which are all assigned to a single ‘Main Deformation’. It also post-dates the regional metamorphism, which ranges from chlorite to garnet grade, with localized development of staurolite-kyanite, gneissose fabrics, and the emplacement of schistose granitic sheets in the Colla Firth Permeation Belt. The GCR sites have been selected mainly to be representative of the East Mainland Succession with its associated structures and metamorphism. Highlights include well-preserved sedimentary structures, high-grade gneisses permeated by granitic material, basaltic pillow lavas and serpentinized ultramafic rocks. Some of the latter contain enigmatic skeletal pseudomorphs after olivine and have been interpreted as former high-magnesium lavas

Do Movement Patterns of GPS-Tracked Cattle on Extensive Rangelands Suggest Independence among Individuals?

In behavioral studies, cattle within the same pasture are not considered as independent experimental units because of the potential confounding effects of the herd’s social interactions. However, evaluating cattle behavior on extensive rangelands is logistically challenging for researchers, and treating individual animals as independent experimental units may be beneficial for answering specific research questions. The objective of this study was to evaluate the association patterns among global positioning system (GPS)-tracked cattle at six different study sites in the western United States. A Half-Weight Index (HWI) association value was calculated for each pair of GPS-tracked cows (i.e., dyad) to determine the proportion of time that cattle were within 75 m and 500 m of each other. Cattle at two study sites exhibited relatively low mean HWI-association values (i.e., less than 0.23 HWI); whereas, cattle at other study sites tended to have greater mean HWI associations (i.e., greater than 0.35 HWI). Distinguishing features between study sites with low and high association values were the management of cattle prior to the study, herd size, pasture size, and the number of watering points. However, at all ranches except one, at least 75% of all dyadic associations had HWI values of less than 0.5 at 500 m, indicating that most of the GPS-tracked cows were greater than 500 m from each other for over 50% of tracking period. While interactions among cattle in the same pasture are often inevitable, our data suggests that under some situations, movement patterns of a sub-set of individual GPS-tracked cows may have levels of independence that are sufficient for analysis as individual experimental units. Understanding the level of independence among GPS-tracked cattle may provide options for analysis of grazing behavior for individual cattle within the same pasture

Dynamical fat link fermions

The use of APE smearing or other blocking techniques in fermion actions can provide many advantages. There are many variants of these fat link actions in lattice QCD currently, such as FLIC fermions. Frequently, fat link actions make use of the APE blocking technique in combination with a projection of the blocked links back into the special unitary group. This reunitarisation is often performed using an iterative maximisation of a gauge invariant measure. This technique is not differentiable with respect to the gauge field and thus prevents the use of standard Hybrid Monte Carlo simulation algorithms. The use of an alternative projection technique circumvents this difficulty and allows the simulation of dynamical fat link fermions with standard HMC and its variants.Comment: LHP '03 (Cairns) Proceeding

Manipulation of the Spatial Grazing Behaviour of Livestock in Extensive Grassland Systems

Spatial behaviour of livestock is a critical factor in grassland management. Recent and ongoing research suggests that new approaches can be used to manipulate where cattle graze. The combination of strategic supplement placement and low-stress herding can be used to target cattle grazing and potentially may be useful for managing fine fuels. A phenotype to genotype association study of cattle spatial behavior suggests that use of rugged terrain and areas far from water is inherited. Although more research is needed, selection for animals specifically adapted for mountainous terrain or extensive paddocks may be an alternative for managing grasslands in the near future

LOWER EXTREMITY LEAN MASS ASYMMETRY CORRELATED WITH FORCE AND POWER ASYMMETRY DURING JUMPING IN ADULTS

The purpose of the current study was to quantify the relationships between lower extremity lean mass asymmetry and force and power asymmetry during jumping in adults aged 18-75 years old. Forty younger adults (18-35 years of age), 28 middle-aged adults (36-55 years of age), and 34 older adult (56-75 years of age) participated in the study. Subjects underwent Dual Energy Xray Absorptiometry to assess lower extremity bilateral lean mass asymmetry. Subjects performed 3 trials of a counter movement jump on two force plates to measure lower extremity bilateral force and power asymmetry. Lower extremity lean mass asymmetry was significantly correlated with force and power asymmetry in younger and middle-aged adults, but not in older adults. Improving lean mass asymmetry might assist in correcting force asymmetry in younger and middle-aged adults

TOTAL AND LOWER EXTREMITY LEAN MASS PERCENTAGE POSITIVELY CORRELATES WITH JUMP PERFORMANCE

The current study investigated the relationship between the lower extremity and total body lean mass percentages and the peak vertical ground reaction force (VGRF), peak power, and jump height (JH) in a countermovement jump (CMJ). One hundred and two subjects diverse in age and fitness level underwent Dual Energy X-ray Absorptiometry to determine mass composition and then performed three countermovement jumps which were used to calculate peak VGRF, peak power, and JH; the first two normalized to subject bodyweight. Pearson correlation tests between lean mass percentage and jump performance indicated significant positive correlations (r > 0.56), which were consistent with previous literature. However, as not all variance in CMJ measures was accounted for by lean mass percentage, other variables should be taken into account

A Scalable Biomimetic Synthesis of Resveratrol Dimers and Systematic Evaluation of their Antioxidant Activities

An efficient synthetic route to the resveratrol oligomers quadrangularin A and pallidol is reported. It features a scalable biomimetic oxidative dimerization that proceeds in excellent yield and with complete regioselectivity. A systematic evaluation of the natural products and their synthetic precursors as radical‐trapping antioxidants has revealed that, contrary to popular belief, this mode of action is unlikely to account for their observed biological activity.Hartnäckigkeit zahlt sich aus: Eine kurze Synthese der Resveratrol‐Oligomere Quadrangularin A und Pallidol macht sich die Stabilität der von 2,6‐Di‐tert‐butylphenol abgeleiteten Radikal‐ und der Chinonmethid‐Zwischenstufe zunutze. Untersuchungen dieser Verbindungen als antioxidative Radikalfänger ergaben, dass diese Eigenschaft höchstwahrscheinlich nicht die Ursache ihrer beobachteten biologischen Aktivität ist.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/110868/1/3825_ftp.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/110868/2/ange_201409773_sm_miscellaneous_information.pd

Electrochemical Dimerization of Phenylpropenoids and the Surprising Antioxidant Activity of the Resultant Quinone Methide Dimers

A simple method for the dimerization of phenylpropenoid derivatives is reported. It leverages electrochemical oxidation of pâ unsaturated phenols to access the dimeric materials in a biomimetic fashion. The mild nature of the transformation provides excellent functional group tolerance, resulting in a unified approach for the synthesis of a range of natural products and related analogues with excellent regiocontrol. The operational simplicity of the method allows for greater efficiency in the synthesis of complex natural products. Interestingly, the quinone methide dimer intermediates are potent radicalâ trapping antioxidants; more so than the phenols from which they are derivedâ or transformed toâ despite the fact that they do not possess a labile Hâ atom for transfer to the peroxyl radicals that propagate autoxidation.Chinonmethidâ Dimere wurden durch milde anodische Oxidation vermittelt durch eine preiswerte und leicht verfügbare Aminbase mit exzellenter Ausbeute und Regiokontrolle hergestellt. Diese Strategie ermöglicht raschen Zugang zu Zwischenprodukten für die katalytische Synthese von Phenylpropenoidâ Oligomeren und bietet ein neues Werkzeug für die Totalsynthese dieser komplexen Moleküle.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/146959/1/ange201810870.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/146959/2/ange201810870_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/146959/3/ange201810870-sup-0001-misc_information.pd

Electrochemical Dimerization of Phenylpropenoids and the Surprising Antioxidant Activity of the Resultant Quinone Methide Dimers

A simple method for the dimerization of phenylpropenoid derivatives is reported. It leverages electrochemical oxidation of pâ unsaturated phenols to access the dimeric materials in a biomimetic fashion. The mild nature of the transformation provides excellent functional group tolerance, resulting in a unified approach for the synthesis of a range of natural products and related analogues with excellent regiocontrol. The operational simplicity of the method allows for greater efficiency in the synthesis of complex natural products. Interestingly, the quinone methide dimer intermediates are potent radicalâ trapping antioxidants; more so than the phenols from which they are derivedâ or transformed toâ despite the fact that they do not possess a labile Hâ atom for transfer to the peroxyl radicals that propagate autoxidation.Quinone methide dimers are prepared via mild anodic oxidation mediated by a cheap and readily available amine base with excellent yield and regiocontrol. This strategy provides rapid access to intermediates for the synthesis of phenylpropenoid oligomers in a catalytic fashion, providing a new tool for the total synthesis of these complex molecules.Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/147117/1/anie201810870-sup-0001-misc_information.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/147117/2/anie201810870_am.pdfhttps://deepblue.lib.umich.edu/bitstream/2027.42/147117/3/anie201810870.pd