9 research outputs found
Formation of a transient amorphous solid in low density aqueous charged sphere suspensions
Colloidal glasses form from hard spheres, nearly hard spheres, ellipsoids and
platelets or their attractive variants have been studied in detail.
Complementing and checking theoretical approaches and simulations, the many
different types of model systems have significantly advanced our understanding
of the glass transition in general. Despite their early prediction, however, no
experimental charged sphere glasses have been found at low density, where the
competing process of crystallization prevails. We here report the formation of
a transient amorphous solid formed from charged polymer spheres suspended in
thoroughly deionized water at volume fractions of 0.0002-0.01. From optical
experiments, we observe the presence of short-range order and an enhanced shear
rigidity as compared to the stable polycrystalline solid of body centred cubic
structure. On a density dependent time scale of hours to days, the amorphous
solid transforms into this stable structure. We further present preliminary
dynamic light scattering data showing the evolution of a second slow relaxation
process possibly pointing to a dynamic heterogeneity known from other colloidal
glasses and gels.We compare our findings to the predicted phase behaviour of
charged sphere suspensions and discuss possible mechanisms for the formation of
this peculiar type of colloidal glass.Comment: 6 figure
Universal scaling of flow curves: comparison between experiments and simulations
Yield stress materials form an interesting class of materials that behave
like solids at small stresses, but start to flow once a critical stress is
exceeded. It has already been reported both in experimental and simulation work
that flow curves of different yield stress materials can be scaled with the
distance to jamming or with the confining pressure. However, different scaling
exponents are found between experiments and simulations. In this paper we
identify sources of this discrepancy. We numerically relate the volume fraction
with the confining pressure and discuss the similarities and differences
between rotational and oscillatory measurements. Whereas simulations are
performed in the elastic response regime close to the jamming transition and
with very small amplitudes to calculate the scaling exponents, these conditions
are hardly possible to achieve experimentally. Measurements are often performed
far away from the critical volume fraction and at large amplitudes. We show
that these differences are the underlying reason for the different exponents
for rescaling flow curves
Ethyl cellulose nanoparticles as stabilizers for Pickering emulsions
Pickering emulsions stabilized by ethyl cellulose nanoparticles have recently received –great attention for their remarkable stability and numerous industrial applications. De- spite this, the exact stabilization mechanism of such Pickering emulsions is still not fully understood. Both the stabilization of the emulsion by particle adsorption at the inter- face and through network formation in the continuous phase (leading to a yield stress) have been suggested. In this work we study soybean oil-in-water emulsions stabilized by ethyl cellulose nanoparticles and find, by the use of confocal microscopy and interfa- cial tension measurements, that the main stabilization mechanism of this nanoparticle- stabilized emulsions is the adsorption of the particles at the interface, instead of forming a network in the continuous phase. At the same time, oscillatory rheology measurements reveal that the emulsions exhibit a yield stress well below the random close-packing limit for hard spheres, suggesting short-range interactions between the droplets caused by the presence of the particles at the interface. The presence of the particles at the interface in combination with the observed rheological behavior of an attractive emulsion gives a strong indication for a particle-bridged stabilized emulsions
Creep and drainage in the fast destabilization of emulsions
The destabilization of emulsions is important for many applications but remains incompletely understood. We perform squeeze flow measurements on oil-in-water emulsions, finding that the spontaneous destabilization of emulsions is generally very slow under normal conditions, with a characteristic time scale given by the drainage of the continuous phase and the coalescence of the dispersed phase. We show that if the emulsion is compressed between two plates, the destabilization can be sped up significantly; on the one hand, the drainage is faster due to the application of the squeezing force. On the other hand, creep processes lead to rearrangements that also contribute to the destabilization
Scaling of flow curves : Comparison between experiments and simulations
Yield-stress materials form an interesting class of materials that behave like solids at small stresses, but start to flow once a critical stress is exceeded. It has already been reported both in experimental and simulation work that flow curves of different yield-stress materials can be scaled with the distance to jamming or with the confining pressure. However, different scaling exponents are found between experiments and simulations. In this paper we identify sources of this discrepancy. We numerically relate the volume fraction with the confining pressure and discuss the similarities and differences between rotational and oscillatory measurements. Whereas simulations are performed in the elastic response regime close to the jamming transition and with very small amplitudes to calculate the scaling exponents, these conditions are hardly possible to achieve experimentally. Measurements are often performed far away from the critical volume fraction and at large amplitudes. We show that these differences are the underlying reason for the different exponents for rescaling flow curves
Emulsion Destabilization by Squeeze Flow
There is a large debate on the destabilization mechanism of emulsions. We present a simple technique using mechanical compression to destabilize oil-in-water emulsions. Upon compression of the emulsion, the continuous aqueous phase is squeezed out, while the dispersed oil phase progressively deforms from circular to honeycomb-like shapes. The films that separate the oil droplets are observed to thin and break at a critical oil/water ratio, leading to coalescence events. Electrostatic interactions and local droplet rearrangements do not determine film rupture. Instead, the destabilization occurs like an avalanche propagating through the system, starting at areas where the film thickness is smallest
Creep and drainage in the fast destabilization of emulsions
The destabilization of emulsions is important for many applications but remains incompletely understood. We perform squeeze flow measurements on oil-in-water emulsions, finding that the spontaneous destabilization of emulsions is generally very slow under normal conditions, with a characteristic time scale given by the drainage of the continuous phase and the coalescence of the dispersed phase. We show that if the emulsion is compressed between two plates, the destabilization can be sped up significantly; on the one hand, the drainage is faster due to the application of the squeezing force. On the other hand, creep processes lead to rearrangements that also contribute to the destabilization
Ethyl cellulose nanoparticles as stabilizers for Pickering emulsions
Pickering emulsions stabilized by ethyl cellulose nanoparticles have recently received –great attention for their remarkable stability and numerous industrial applications. De- spite this, the exact stabilization mechanism of such Pickering emulsions is still not fully understood. Both the stabilization of the emulsion by particle adsorption at the inter- face and through network formation in the continuous phase (leading to a yield stress) have been suggested. In this work we study soybean oil-in-water emulsions stabilized by ethyl cellulose nanoparticles and find, by the use of confocal microscopy and interfa- cial tension measurements, that the main stabilization mechanism of this nanoparticle- stabilized emulsions is the adsorption of the particles at the interface, instead of forming a network in the continuous phase. At the same time, oscillatory rheology measurements reveal that the emulsions exhibit a yield stress well below the random close-packing limit for hard spheres, suggesting short-range interactions between the droplets caused by the presence of the particles at the interface. The presence of the particles at the interface in combination with the observed rheological behavior of an attractive emulsion gives a strong indication for a particle-bridged stabilized emulsions
Emulsion Destabilization by Squeeze Flow
There is a large debate on the destabilization mechanism of emulsions. We present a simple technique using mechanical compression to destabilize oil-in-water emulsions. Upon compression of the emulsion, the continuous aqueous phase is squeezed out, while the dispersed oil phase progressively deforms from circular to honeycomb-like shapes. The films that separate the oil droplets are observed to thin and break at a critical oil/water ratio, leading to coalescence events. Electrostatic interactions and local droplet rearrangements do not determine film rupture. Instead, the destabilization occurs like an avalanche propagating through the system, starting at areas where the film thickness is smallest