131 research outputs found

    Effect of sulfate concentration and associated cation type on chloride-induced reinforcement corrosion

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    Effect of sulfate concentration and associated cation type on chloride-induced reinforcement corrosio

    Chloride-induced reinforcement corrosion in blended cement concretes expores to chloride-sulfate environments

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    This paper reports the results of a study conducted to investigate the influence of sulphate concentration and associated cation type on chloride-induced reinforcement corrosion in blended cement concretes. Reinforced concrete specimens were exposed to chloride plus sulphate solutions for a period of 1200 days. The exposure solutions contained a fixed concentration of 5% sodium chloride and the sulphate concentration was varied from 0 to 4% SO4 2 . The effect of cation type associated with sulphate ions, namely Naþ and Mgþþ, on chloride-induced reinforcement corrosion was also evaluated. Reinforcement corrosion was assessed by measuring corrosion potentials and corrosion current density at regular intervals. The results indicated that the presence of sulphate ions in the chloride solution increased the corrosion current density, but no significant effect on the time to initiation of reinforcement corrosion was noted. Further, the corrosion current density increased with increasing sulphate concentration and the period of exposure. The corrosion current density on steel in the blended cement concrete specimens was much less than that in the plain cement concrete specimens, indicating that the corrosion resistance of blended cements was much better than that of plain cements. The cation type associated with sulphate ions did not significantly influence either the initiation or rate of reinforcement corrosion

    Long-term effect of sulfate ions and associated cation type on chloride-induced reinforcement corrosion in Portland cement concretes

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    This paper reports the influence of sulfate concentration on chloride-induced reinforcement corrosion in Portland cement concretes (with C3A varying from 3.6% to 9.65%). The concrete specimens were exposed to mixed chloride and sulfate solutions for a period of 1200 days. The chloride was fixed at 5% NaCl for all solutions, while the sulfate concentration was varied to represent that noted in the sulfate-bearing soil and ground water. The study included an assessment of the effect of cation type associated with sulfate ions, namely Na+ and Mg2+, on chloride-induced reinforcement corrosion, an important factor that has received little attention. Reinforcement corrosion was evaluated by measuring corrosion potentials and corrosion current density at regular intervals. The results indicate that the presence of sulfate ions in the chloride solution did not influence the time to initiation of chloride-induced reinforcement corrosion, but the rate of corrosion increased with increasing sulfate concentration. Further, the rate of chloride-induced reinforcement corrosion in the concrete specimens exposed to sodium chloride plus magnesium sulfate solutions was more than that in the concrete specimens exposed to sodium chloride plus sodium sulfate solutions

    Effect of cement alkalinity on pore solution chemistry and chloride-induced reinforcement corrosion

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    This paper reports the results of a study conducted to evaluate the influence of cement alkalinity on the pore solution chemistry and chloride-induced reinforcement corrosion in ordinary and sulfate resisting Portland cement concretes. To evaluate the influence of cement alkalinity on the pore solution chemistry, cement paste specimens were prepared and admixed with fixed quantity of sodium chloride and various dosages of alkalinity (in the range of 0.4 to 1.4% Na2O equivalent). The pore solution was extracted and analyzed to determine the OH-, Cl- and SO4 -- concentrations. The influence of cement alkalinity on chloride-induced reinforcement corrosion was also assessed by measuring corrosion potentials and corrosion current density at regular intervals. The results indicated that the OH-, Cland SO4 -- concentrations of the pore solution increased with increasing alkali content of the cement. Further, the Cl-/OH- ratio decreased with increasing alkali content up to 0.8% Na2O and then increased with a further increase in the alkalinity. Furthermore, an improvement in the corrosion-resistance of the SRPC and OPC concrete specimens was noted with increasing alkali content of cement. However, the highest improvement was noted when the alkalinity was 0.8% Na2O equivalent

    Influence of cement composition on concrete durability in chloride-sulfate environments

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