Effect of activated alloys on hydrogen discharge kinetics of MgH2 nanocrystals

This is the post-print version of the final paper published in Journal of Alloys and Compounds. The published article is available from the link below. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. Copyright @ 2007 Elsevier B.V.Activated alloys synthesized by arc-melting were examined as catalysts for improving the hydrogen sorption characteristics of nanostructured magnesium hydride, proposed as a reversible hydrogen storage material. The MgH2-catalyst absorbing materials were prepared by ball milling of pure MgH2 with hydrided Zr47Ni53, Zr9Ni11, and other investigated alloys. The nanostructured MgH2-intermetallic systems were tested at 250 °C and catalyst addition of eutectoid Zr47Ni53 resulted in the fastest desorption time and highest initial desorption rate. Also, the catalyzed Mg-hydride with activated Zr9Ni11 and Zr7Ni10 phases showed fast desorption kinetics. Moreover, the results demonstrated that the composition of dispersed ZrxNiy catalysts has a strong influence on the amount of accumulated hydrogen and desorption rate of Mg-nanocomposite.National Research Council Canad

Experimental study on a metal hydride based hydrogen compressor

This is the post-print version of the final paper published in Journal of Alloys and Compounds. The published article is available from the link below. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. Copyright @ 2008 Elsevier B.V.A three-stage metal hydride based hydrogen compressor prototype was built. It has been designed for a hydrogen production facility using a low-pressure alkaline electrolyser. The compression system should transfer heat recovered from the electrolyser into the hydride beds to allow hydrogen desorption flow. The three-stage compressor achieves a compression ratio of 20:1 atm. It performs a thermal cycling of three AB5 hydrides between 20 and 80 °C. Its flow rate, for 25 g of each hydride bed, reaches about 20 l (NTP) of hydrogen per hour. The prototype is now operational. Some improvements in the heat transfer management system are also carried out before proceeding to the interconnection with the electrolyser and to the extent that the hydrogen produced satisfies the high purity requirement of the hydrides used in the compressor.Natural Resources Canada(NRCan), Ministère des Ressources Naturelles et de la Faune du Québec (MRNF), and Natural Sciences and Engineering Research Council of Canada

A Blockchain Protocol for Human-in-the-Loop AI

Intelligent human inputs are required both in the training and operation of AI systems, and within the governance of blockchain systems and decentralized autonomous organizations (DAOs). This paper presents a formal definition of Human Intelligence Primitives (HIPs), and describes the design and implementation of an Ethereum protocol for their on-chain collection, modeling, and integration in machine learning workflows.Comment: Trustworthy and Socially Responsible Machine Learning (TSRML) co-located with NeurIPS 202

Photovoltaic cells energy performance enhancement with down-converting photoluminescence phosphors

Phosphors, synthesized by the urea homo-precipitation method, were examined as ultraviolet-spectral down conversion materials for improving the light absorption and electrical characteristics of commercial single-junction silicon solar cells. The photovoltaic (PV) cells were coated with erbium and terbium doped gadolinium oxysulfide phosphors encapsulated in ethyl vinyl-acetate binder using blade screen printing technique, and the optimum concentration of phosphor in the composite resulted in the largest light conversion, and superior electrical output and energy transfer efficiency. Moreover, the results demonstrated that the composition of dispersed phosphors has a strong influence on the amount of ultraviolet-light converted and electron transition capacity of PV cells. The experimental results showed in an optimized PV cell, an enhancement of 0.54% (from 12.11% to 12.65%) in the energy conversion of a Si-based PV cell was achieved.Mr. Ben Parker of LOT-QuantumDesig