Tuning Jeff = 1/2 Insulating State via Electron Doping and Pressure in Double-Layered Iridate Sr3Ir2O7

Sr3Ir2O7 exhibits a novel Jeff=1/2 insulating state that features a splitting between Jeff=1/2 and 3/2 bands due to spin-orbit interaction. We report a metal-insulator transition in Sr3Ir2O7 via either dilute electron doping (La3+ for Sr2+) or application of high pressure up to 35 GPa. Our study of single-crystal Sr3Ir2O7 and (Sr1-xLax)3Ir2O7 reveals that application of high hydrostatic pressure P leads to a drastic reduction in the electrical resistivity by as much as six orders of magnitude at a critical pressure, PC = 13.2 GPa, manifesting a closing of the gap; but further increasing P up to 35 GPa produces no fully metallic state at low temperatures, possibly as a consequence of localization due to a narrow distribution of bonding angles {\theta}. In contrast, slight doping of La3+ ions for Sr2+ ions in Sr3Ir2O7 readily induces a robust metallic state in the resistivity at low temperatures; the magnetic ordering temperature is significantly suppressed but remains finite for (Sr0.95La0.05)3Ir2O7 where the metallic state occurs. The results are discussed along with comparisons drawn with Sr2IrO4, a prototype of the Jeff = 1/2 insulator.Comment: five figure

Lawrence Head Volcanics and Dunnage Mélange, Newfoundland Appalachians: Origin by Ordovician Ridge Subduction or in Back-Arc Rift?

This paper reviews the geological setting and reports new geochemical trace element data from the Ordovician Lawrence Head Volcanics (LHV) and the underlying gabbro sills in the Exploits Group. In combination with existing published analyses and ages of these rocks, the volcanic rocks and sills are indistinguishable in composition and age, and the data are consistent with the hypothesis that they represent the same (mostly E-MORB composition) magmatic event in the early–mid Darriwilian (~465 ± 2 Ma). The LHV and their enclosing strata show regional evidence for: 1) upward decline of volume and grain size of arc-derived volcaniclastic materials over the uppermost interval of turbidite sedimentary strata below the LHV; 2) change to shallow marine conditions locally by the end of the LHV event, followed immediately by significant subsidence, and 3) no evidence of coarse-grained clastic input, nor of normal faulting, during or immediately after LHV magmatism. Ridge–trench interaction (ridge subduction) at a subduction system is consistent with all of these features and spatial distribution of related elements, but a rift (back-arc) origin over a subduction zone can only accommodate the compositions, and is inconsistent with the geological evidence. The Dunnage Mélange (DM) has been interpreted either as olistostromal in a developing back-arc rift basin, or as a subduction accretionary prism. Peraluminous intrusions in the mélange (Coaker Porphyry ― CP) are more readily explained by ridge subduction, and a previously reported zircon age (469 ± 4 Ma) is consistent with the age of the LHV and gabbro sills, also interpreted as products of ridge subduction. Localization of the CP in the eastern area of DM, and of most of the large LHV-derived volcanic blocks in the western DM, suggests a slightly younger age, and perhaps a different mechanism, for the origin of the western DM.SOMMAIRECet article passe en revue le contexte géologique et présente de nouvelles données géochimiques d’éléments traces des roches volcaniques ordoviciennes de Lawrence Head (LHV) et des filons-couches de gabbro sous-jacents du Groupe Exploits.  Considérant la combinaison des données d’analyse publiées et des datations de ces roches, les roches volcaniques et les filons-couches sont indiscernables tant en composition qu’en âge, et les données sont compatibles avec l’hypothèse selon laquelle ils représentent le même événement magmatique (principalement E-MORB) du Darriwilien précoce à moyen (~465 ± 2 Ma).  Les LHV ainsi que les strates de l’encaissant renferment des indices régionaux qui montrent : 1) que le volume et la granulométrie des matériaux volcanoclastiques d’arc diminuent vers le haut dans l’intervalle supérieur des strates de turbidites sédimentaires sous les LHV; 2) que le changement vers des milieux marins peu profonds localement vers la fin de l’événement des LHV a été suivi immédiatement par une subsidence importante, et 3) qu’il n’existe pas d’indices d’apports clastiques à gros grains, non plus que de formation de failles normales, durant ou immédiatement après le magmatisme des LHV.  L’interaction crête-fosse (subduction de la crête) au lieu d’un système de subduction concorde avec toutes ces caractéristiques et la répartition spatiale des éléments reliés, alors qu’une origine de crête (arrière-arc) au-dessus d’une zone de subduction ne peut expliquer que les compositions et qu’elle est incompatible avec l’évidence géologique.  Le Dunnage Mélange (DM) a été interprété soit comme un olistostome dans un bassin d’arrière-arc en développement, ou comme un prisme d’accrétion de subduction.  Les intrusions hyperalumineuses dans le mélange (Porphyre Coaker — CP), s’explique plus facilement par une subduction de crête, et un âge de datation sur zircon de (469 ± 4 Ma) correspond à l’âge des LHV et des filons-couche de gabbro, aussi interprétés comme produits d’une subduction de crête.  La localisation du CP dans la portion orientale du DM, et de la majeure partie des grands blocs volcaniques dérivés des LHV de la portion ouest du DM, suggère un âge légèrement plus jeune, et peut-être un mécanisme différent, pour l’origine de la portion ouest du DM

Observation of a pressure-induced transition from interlayer ferromagnetism to intralayer antiferromagnetism in Sr4Ru3O10

Sr4Ru3O10 is a Ruddlesden-Popper compound with triple Ru-O perovskite layers separated by Sr-O alkali layers. This compound presents a rare coexistence of interlayer (c-axis) ferromagnetism and intralayer (basal-plane) metamagnetism at ambient pressure. Here we report the observation of pressure-induced, intralayer itinerant antiferromagnetism arising from the interlayer ferromagnetism. The application of modest hydrostatic pressure generates an anisotropy that causes a flattening and a tilting of RuO6 octahedra. All magnetic and transport results from this study indicate these lattice distortions diminish the c-axis ferromagnetism and basal-plane metamagnetism, and induce a basal-plane antiferromagnetic state. The unusually large magnetoelastic coupling and pressure tunability of Sr4Ru3O10 makes it a unique model system for studies of itinerant magnetism.Comment: 6 figure

Trade-offs between morphology and thermal niches mediate adaptation in response to competing selective pressures

The effects of climate change—such as increased temperature variability and novel predators—rarely happen in isolation, but it is unclear how organisms cope with mul- tiple stressors simultaneously. To explore this, we grew replicate Paramecium caudatum populations in either constant or variable temperatures and exposed half to predation. We then fit thermal performance curves (TPCs) of intrinsic growth rate (rmax) for each replicate population (N = 12) across seven temperatures (10°C–38°C). TPCs of P. caudatum exposed to both temperature variability and predation re- sponded only to one or the other (but not both), resulting in unpredictable outcomes. These changes in TPCs were accompanied by changes in cell morphology. Although cell volume was conserved across treatments, cells became narrower in response to temperature variability and rounder in response to predation. Our findings sug- gest that predation and temperature variability produce conflicting pressures on both thermal performance and cell morphology. Lastly, we found a strong correlation between changes in cell morphology and TPC parameters in response to predation, suggesting that responses to opposing selective pressures could be constrained by trade-offs. Our results shed new light on how environmental and ecological pressures interact to elicit changes in characteristics at both the individual and population levels. We further suggest that morphological responses to interactive environmen- tal forces may modulate population-level responses, making prediction of long-term responses to environmental change challenging

Trade-Offs Between Morphology and Thermal Niches Mediate Adaptation in Response to Competing Selective Pressures

Abstract The effects of climate change—such as increased temperature variability and novel predators—rarely happen in isolation, but it is unclear how organisms cope with multiple stressors simultaneously. To explore this, we grew replicate Paramecium caudatum populations in either constant or variable temperatures and exposed half to predation. We then fit thermal performance curves (TPCs) of intrinsic growth rate (rmax) for each replicate population (N = 12) across seven temperatures (10°C–38°C). TPCs of P. caudatum exposed to both temperature variability and predation responded only to one or the other (but not both), resulting in unpredictable outcomes. These changes in TPCs were accompanied by changes in cell morphology. Although cell volume was conserved across treatments, cells became narrower in response to temperature variability and rounder in response to predation. Our findings suggest that predation and temperature variability produce conflicting pressures on both thermal performance and cell morphology. Lastly, we found a strong correlation between changes in cell morphology and TPC parameters in response to predation, suggesting that responses to opposing selective pressures could be constrained by trade-offs. Our results shed new light on how environmental and ecological pressures interact to elicit changes in characteristics at both the individual and population levels. We further suggest that morphological responses to interactive environmental forces may modulate population-level responses, making prediction of long-term responses to environmental change challenging

Evidence for Circumpolar Distribution of Planktonic Archaea in the Southern Ocean

Surveys using rRNA-targeted probes specific for the 3 domains of life (Eucarya, Archaea, and Bacteria) indicated the presence, and at times high abundance, of archaeal rRNA in a variety of water masses surrounding Antarctica. Hybridization signals of archaeal rRNA contributed significantly to that of total picoplankton rRNA both north and south of the Polar Front in Drake Passage. Late winter surface water populations collected around the South Shetland Islands also yielded relatively high archaeal rRNA hybridization signals, approaching 10% or greater of the total rRNA. Summer samples collected in the western region of the Antarctic Peninsula and at McMurdo Sound in the Ross Sea region of Antarctica yielded lower amounts of archaeal rRNA in the surface waters, and higher levels of archaeal rRNA at depth (150 to 500 m). The hybridization data were compared to biological, chemical, and hydrographic information when possible. In surface waters, archaeal rRNA and chlorophyll a varied inversely. The data presented here further supports the hypothesis that planktonic archaea are a common, widespread and likely ecologically important component of Antarctic picoplankton assemblages. The presence of these archaea in circumpolar deep water suggests a conduit for their circumpolar transport around Antarctica via the Antarctic Circumpolar Current, as well as their export to the deep sea, or to intermediate waters of the South Atlantic via mixing at the polar front

Meeting report : Ocean ‘omics science, technology and cyberinfrastructure : current challenges and future requirements (August 20-23, 2013)

© The Author(s), 2014. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Standards in Genomic Sciences 9 (2014): 1251-1258, doi:10.4056/sigs.5749944.The National Science Foundation’s EarthCube End User Workshop was held at USC’s Wrigley Marine Science Center on Catalina Island, California in August 2013. The workshop was designed to explore and characterise the needs and tools available to the community focusing on microbial and physical oceanography research with a particular focus on ‘omic research. The assembled researchers outlined the existing concerns regarding the vast data resources that are being generated, and how we will deal with these resources as their volume and diversity increases. Particular attention was focused on the tools for handling and analysing the existing data, and on the need for the construction and curation of diverse federated databases, as well as development of shared interoperable, “big-data capable” analytical tools. The key outputs from this workshop include (i) critical scientific challenges and cyberinfrastructure constraints, (ii) the current and future ocean ‘omics science grand challenges and questions, and (iii) data management, analytical and associated and cyber-infrastructure capabilities required to meet critical current and future scientific challenges. The main thrust of the meeting and the outcome of this report is a definition of the ‘omics tools, technologies and infrastructures that facilitate continued advance in ocean science biology, marine biogeochemistry, and biological oceanography.We gratefully acknowledge support for the Ocean ‘Omics EarthCube end-user workshop by the Geo-sciences Division of the U.S. National Science Foundation

proovframe: frameshift-correction for long-read (meta)genomics

Long-read sequencing technologies hold big promises for the genomic analysis of complex samples such as microbial communities. Yet, despite improving accuracy, basic gene prediction on long-read data is still often impaired by frameshifts resulting from small indels. Consensus polishing using either complementary short reads or to a lesser extent the long reads themselves can mitigate this effect but requires universally high sequencing depth, which is difficult to achieve in complex samples where the majority of community members are rare. Here we present proovframe, a software implementing an alternative approach to overcome frameshift errors in long-read assemblies and raw long reads. We utilize protein-to-nucleotide alignments against reference databases to pinpoint indels in contigs or reads and correct them by deleting or inserting 1-2 bases, thereby conservatively restoring reading-frame fidelity in aligned regions. Using simulated and real-world benchmark data we show that proovframe performs comparably to short-read-based polishing on assembled data, works well with remote protein homologs, and can even be applied to raw reads directly. Together, our results demonstrate that protein-guided frameshift correction significantly improves the analyzability of long-read data both in combination with and as an alternative to common polishing strategies. Proovframe is available from https://github.com/thackl/proovframe