High Temperature Corrosion Behaviors of the Superheater Materials

AbstractThe high temperature corrosion tests are performed on 20#steel, TP347H and superalloy C22. The high temperature corrosion behaviors of these superheater materials in the synthetic salt containing 80wt-%KCl+20wt-%K2SO4 have been investigated under the oxidizing atmosphere at a temperature of 650°C for 218hours. For comparison, the column diagram has been obtained by mass loss. The scanning electron microscopy (SEM) with energy dispersive spectrometer (EDS) is used to characterize the surface morphology and compositions of the corrosion products. The results have shown that the superalloy C22 exhibits the high corrosion resistance

2-[(1S,3S)-3-Acetyl-2,2-dimethyl­cyclo­butyl]-N-(m-tol­yl)acetamide

The title compound, C17H23NO2, contains two chiral centres and was synthesized from 2-(3-acetyl-2,2-dimethyl­cyclo­butyl)acetic acid and m-toluidine. The cyclobutane ring is not flat but flexed as though folded from the dimethyl-substituted C atom to the unsubstituted C atom, with a dihedral angle of 25.9°. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen-bonding inter­actions

SYNTHESIS OF CYCLOBUTANE ANALOGUES

2-(3-Acetyl-2,2-dimethylcyclobutyl)acetic acid (pinonic acid) was synthesized using α-pinene as raw material and potassium permanganate as oxidant. This compound reacted with substituted aniline to produce eight kinds of derivatives with cyclobutane moiety. The yields of the cyclobutane analogues ranged from 24.9 to 78.2 %. KEY WORDS: Cyclobutane analogues, Pinonic acid, Oxidation Bull. Chem. Soc. Ethiop. 2009, 23(1), 135-139

Isolation and characterization of a novel Bacillus subtilis WD23 exhibiting laccase activity from forest soil

The strain Bacillus sp. WD23 exhibiting laccase activity was screened from forest soil. The M9 medium containing Cu2+ was used for enriching and isolating bacterial strains capable of oxidizing syringaldazine. One isolated strain was identified as Bacillus subtilis WD23 based on the results of physiological and biochemical tests and 16S rDNA sequence analysis. The strain WD23 could grow at temperatures ranging from 20 to 55°C and showed optimum growth temperature and pH at 25°C and 7.0, respectively. The sporulation rate of the strain clearly correlated well with the laccase activity. The temperature half-life of the spore laccase was 2.5 h at 80°C and the pH half life time was 15 d at pH 9.0. Its spore laccase could decolorize 50 - 90% of Remazol brilliant blue R (RBBR), alizarin red, congo red, methyl orange and methyl violet, which suggests the potential application of spore laccase in dyestuff treatment.Keywords: Bacterial laccase, Bacillus subtilis, spore, decolorizationAfrican Journal of Biotechnology Vol. 9(34), pp. 5496-5502, 23 August, 201

The evolution of floral deception in Epipactis veratrifolia (Orchidaceae): from indirect defense to pollination

BACKGROUND: It is estimated that floral deception has evolved in at least 7500 species of angiosperms, of which two thirds are orchids. Epipactis veratrifolia (Orchidaceae) is a model system of aphid mimicry as aphidophagous hoverflies lay eggs on false brood sites on their flowers. To understand the evolutionary ecology of floral deception, we investigated the pollination biology of E. veratrifolia across 10 populations in the Eastern Himalayas. We reconstructed the phylogeny of Epipactis and mapped the known pollination systems of previously studied species onto the tree. RESULTS: Some inflorescences of E. veratrifolia were so infested with aphids while they were still in bud that the some larvae of hoverflies developed to the third instar while flower buds opened. This indicated that adult female hoverflies were partly rewarded for oviposition. Although flowers failed to secrete nectar, they mimicked both alarm pheromones and aphid coloring of to attract female hoverflies as their exclusive pollinators. Phylogenetic mapping indicate that pollination by aphidophagous hoverflies is likely an ancestral condition in the genus Epipactis. We suggest that the biological interaction of aphid (prey), orchid (primary producer) and hoverfly (predator) may represent an intermediate stage between mutualism and deception in the evolution of pollination-by-deceit in E. veratrifolia. CONCLUSIONS: Our analyses indicate that this intermediate stage may be used as a model system to interpret the origin of oviposition (brood site) mimicry in Epipactis. We propose the hypothesis that some deceptive pollination systems evolved directly from earlier (partly) mutualistic systems that maintained the fidelity of the original pollinator(s) even though rewards (nectar/ brood site) were lost

Storage of multiple single-photon pulses emitted from a quantum dot in a solid-state quantum memory

Quantum repeaters are critical components for distributing entanglement over long distances in presence of unavoidable optical losses during transmission. Stimulated by Duan-Lukin-Cirac-Zoller protocol, many improved quantum-repeater protocols based on quantum memories have been proposed, which commonly focus on the entanglement-distribution rate. Among these protocols, the elimination of multi-photons (multi-photon-pairs) and the use of multimode quantum memory are demonstrated to have the ability to greatly improve the entanglement-distribution rate. Here, we demonstrate the storage of deterministic single photons emitted from a quantum dot in a polarization-maintaining solid-state quantum memory; in addition, multi-temporal-mode memory with $1$, $20$ and $100$ narrow single-photon pulses is also demonstrated. Multi-photons are eliminated, and only one photon at most is contained in each pulse. Moreover, the solid-state properties of both sub-systems make this configuration more stable and easier to be scalable. Our work will be helpful in the construction of efficient quantum repeaters based on all-solid-state devicesComment: Published version, including supplementary materia

Characterization of Kepler targets based on medium-resolution LAMOST spectra analyzed with ROTFIT

In this work we present the results of our analysis of 16,300 medium-resolution LAMOST spectra of late-type stars in the Kepler field with the aim of determining the stellar parameters, activity level, lithium atmospheric content, and binarity. We have used a version of the code ROTFIT specifically developed for these spectra. We provide a catalog with the atmospheric parameters (Teff, log(g), and [Fe/H]), radial velocity (RV), and projected rotation velocity (vsini). For cool stars (Teff < 6500 K), we also calculated the H-alpha and LiI-6708 equivalent width, which are important indicators of chromospheric activity and evolutionary stage, respectively. We have derived the RV and atmospheric parameters for 14,300 spectra of 7443 stars. Literature data were used for a quality control of the results. The Teff and log(g) values are in good agreement with the literature. The [Fe/H] values appear to be overestimated for metal-poor stars. We propose a relation to correct the [Fe/H] values derived with ROTFIT. We were able to identify double-lined binaries, stars with variable RVs, lithium-rich giants, and emission-line objects. Based on the H-alpha flux, we found 327 active stars. We detected the LiI-6708 line and measure its equivalent width for 1657 stars, both giants and stars on the main sequence. Regarding the latter, we performed a discrete age classification based on the atmospheric lithium abundance and the upper envelopes of a few open clusters. Among the giants, we found 195 Li-rich stars, 161 of which are reported here for the first time. No relationship is found between stellar rotation and lithium abundance, which allows us to rule out merger scenarios as the predominant explanation of the enrichment of Li in our sample. The fraction of Li-rich giants, about 4%, is higher than expected.Comment: 32 pages, 34 figures; accepted for publication in Astronomy & Astrophysic

Immobilization of Acetobacter sp. CCTCC M209061 for efficient asymmetric reduction of ketones and biocatalyst recycling

BACKGROUND: The bacterium Acetobacter sp. CCTCC M209061 is a promising whole-cell biocatalyst with exclusive anti-Prelog stereoselectivity for the reduction of prochiral ketones that can be used to make valuable chiral alcohols such as (R)-4-(trimethylsilyl)-3-butyn-2-ol. Although it has promising catalytic properties, its stability and reusability are relatively poor compared to other biocatalysts. Hence, we explored various materials for immobilizing the active cells, in order to improve the operational stability of biocatalyst. RESULTS: It was found that Ca-alginate give the best immobilized biocatalyst, which was then coated with chitosan to further improve its mechanical strength and swelling-resistance properties. Conditions were optimized for formation of reusable immobilized beads which can be used for repeated batch asymmetric reduction of 4′-chloroacetophenone. The optimized immobilized biocatalyst was very promising, with a specific activity of 85% that of the free-cell biocatalyst (34.66 μmol/min/g dw of cells for immobilized catalyst vs 40.54 μmol/min/g for free cells in the asymmetric reduction of 4′-chloroacetophenone). The immobilized cells showed better thermal stability, pH stability, solvent tolerance and storability compared with free cells. After 25 cycles reaction, the immobilized beads still retained >50% catalytic activity, which was 3.5 times higher than degree of retention of activity by free cells reused in a similar way. The cells could be recultured in the beads to regain full activity and perform a further 25 cycles of the reduction reaction. The external mass transfer resistances were negligible as deduced from Damkohler modulus Da < <1, and internal mass transfer restriction affected the reduction action but was not the principal rate-controlling step according to effectiveness factors η < 1 and Thiele modulus 0.3<∅ <1. CONCLUSIONS: Ca-alginate coated with chitosan is a highly effective material for immobilization of Acetobacter sp. CCTCC M209061 cells for repeated use in the asymmetric reduction of ketones. Only a small cost in terms of the slightly lower catalytic activity compared to free cells could give highly practicable immobilized biocatalyst