1,058 research outputs found

    Batch Adsorber based PSA Model for Rapid and Efficient Screening of Adsorbents in Post-Combustion CO2 Capture

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    The adsorption-based CO capture has shown promising potential overcoming the limitations posed by commercialised solvent amine-based systems. The choice of an adsorbent is critical to the design of pressure swing adsorption (PSA) processes. Since adsorption processes are cyclic, their design and optimization are computationally challenging. Hence, simple models that capture the essential process characteristics are required for rapid screening of adsorbents. The objective of this work is to come up with a simplified process design model for PSA process which could reliably screen the adsorbents at a faster rate. The model considers only a batch adsorber thereby significantly reducing the complexity, allowing for rapid computation. The model is used to estimate CO purity, recovery and energy consumption. The model results are compared with detailed process optimizations to develop a classification metric to identify adsorbents that satisfy U. S. Department of Energy’s requirement for CO capture processes. The model is then used to screen favourable adsorbents from a set of 100+ real and hypothetical adsorbents. The results indicate that the batch adsorber model can be used for screening a large database of adsorbents in a fast and efficient manner.Fil: Subramanian Balashankar, V.. University of Alberta; CanadáFil: De Pauw, R.. University of Alberta; CanadáFil: Rajagopalan, A. K.. University of Alberta; CanadáFil: Avila, Adolfo María. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Tucumán. Instituto de Química del Noroeste. Universidad Nacional de Tucumán. Facultad de Bioquímica, Química y Farmacia. Instituto de Química del Noroeste; ArgentinaFil: Rajendran, A.. University of Alberta; CanadáXXIX Interamerican Congress of Chemical EngineeringTorontoCanadáCanadian Society for Chemical Engineerin

    No differential susceptibility or diathesis stress to parenting in early adolescence: Personality facets predicting behaviour problems

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    This multi-sample study investigated the main and interactive effects of parenting (responsiveness, overreactivity) and young adolescents' personality traits (negative-affectivity: irritability and anxiety; and orienting-sensitivity) on behaviour problems during adolescence. Data from two samples (N1 = 222; girls 45.5%; Mean age = 11.54 years; N2 = 252; girls 50.4%; Mean age = 10.85 years) were analysed using a multivariate approach. Parenting and y

    Four cycles of BEP versus an alternating regime of PVB and BEP in patients with poor-prognosis metastatic testicular non-seminoma; a randomised study of the EORTC Genitourinary Tract Cancer Cooperative Group.

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    We have investigated whether an alternating induction chemotherapy regimen of PVB/BEP is superior to BEP in patients with poor-prognosis testicular non-seminoma. A total of 234 eligible patients were randomised to receive an alternating schedule of PVB/BEP for a total of four cycles or four cycles of BEP. Poor prognosis was defined as any of the following: lymph node metastases larger than 5 cm, lung metastases more than four in number or larger than 2 cm, haematogenic spread outside the lungs, such as in liver and bone, human chorionic gonadotrophin > 10,000 IU l-1 or alphafetoprotein > 1000 IU l-1. The complete response (CR) rates to PVB/BEP and BEP were similar, 76% and 72% respectively (P = 0.58). In addition, there was no significant difference in relapse rate, disease-free and overall survival at an average follow-up of 6 years. The 5-year progression-free and survival rates in both treatment groups were approximately 80%. The PVB/BEP regime was more toxic with regard to bone marrow function; the frequencies of leucocytes below 1000 microliters-1, leucocytopenic fever and platelets below 25,000 microliters-1, throughout four cycles were 28% vs 5% (P < 0.001), 16% vs 5% (P = 0.006), and 10% vs 1% (P = 0.001) respectively. Neuropathy also occurred more often in the PVB/BEP arm: 47% vs 25% (P = 0.001). This study shows that an alternating regimen of PVB/BEP is not superior to BEP and that it is more myelo- and neurotoxic

    Influence of simulated spring frost on growth and yield of three barley cultivars

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    Spring barley was sown on 4 dates between 28 April and 21 May to evaluate the effect of a simulated frost at the 2-leaf stage on growth and yield. A portable field freezing chamber was used to subject the plants to a -5.6 deg C stress. The frost caused 49, 64 and 68% injury to the leaves and delayed heading by 2.4, 1.4 and 2.4 days in cv. Galt, Atlas and Olli, resp. Frost also reduced the number of tillers/plant, ripe ears/plant and plants/plot in all cv. Although the late-maturing cv. Galt had the most leaf frost resistance, the av. yield reduction (13.8%) was similar in all 3 cv. Complete defoliation by clipping resulted in no further reduction in yield than that which occurred from partial defoliation by freezing. Delayed sowing reduced yield by 8.6%. Frost reduced yield by 9.8% at the 2 early sowing dates and by 17.1% at the 2 later sowing date
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