Saddles and softness in simple model liquids

We report a numerical study of saddles properties of the potential energy landscape for soft spheres with different softness, i.e. different power n of the interparticle repulsive potential. We find that saddle-based quantities rescale into master curves once energies and temperatures are scaled by mode-coupling temperature T_MCT, confirming and generalizing previous findings obtained for Lennard-Jones like models.Comment: 2 pages, 2 figure

Slow dynamics in a primitive tetrahedral network model

We report extensive Monte Carlo and event-driven molecular dynamics simulations of the fluid and liquid phase of a primitive model for silica recently introduced by Ford, Auerbach and Monson [J. Chem. Phys. 17, 8415 (2004)]. We evaluate the iso-diffusivity lines in the temperature-density plane to provide an indication of the shape of the glass transition line. Except for large densities, arrest is driven by the onset of the tetrahedral bonding pattern and the resulting dynamics is strong in the Angell's classification scheme. We compare structural and dynamic properties with corresponding results of two recently studied primitive models of network forming liquids -- a primitive model for water and a angular-constraint free model of four-coordinated particles -- to pin down the role of the geometric constraints associated to the bonding. Eventually we discuss the similarities between "glass" formation in network forming liquids and "gel" formation in colloidal dispersions of patchy particles.Comment: 9 pages, 10 figure

Landscapes and Fragilities

The concept of fragility provides a possibility to rank different supercooled liquids on the basis of the temperature dependence of dynamic and/or thermodynamic quantities. We recall here the definitions of kinetic and thermodynamic fragility proposed in the last years and discuss their interrelations. At the same time we analyze some recently introduced models for the statistical properties of the potential energy landscape. Building on the Adam-Gibbs relation, which connects structural relaxation times to configurational entropy, we analyze the relation between statistical properties of the landscape and fragility. We call attention to the fact that the knowledge of number, energy depth and shape of the basins of the potential energy landscape may not be sufficient for predicting fragility. Finally, we discuss two different possibilities for generating strong behavior.Comment: 17 pages, 10 figures; accepted version, minor correction

Identification and measurement of inefficiencies in leasing systems (An application of linear programming)

This study is directed toward developing procedures for identifying, measuring and appraising intratemporal dissociations between benefits and costs on rented farms. Development of these procedures is expected to provide further insight into the resource structure and operation of a firm in which multiple interests are present. Recent studies appear to have achieved a satisfactory agreement in defining the functions of a lease, thus providing a common starting point for economic analysis.3 Chryst and Timmons have summarizd the purposes of farm rent: 1. It helps allocate resources among particular kinds and amounts of uses in the productive process. 2. It distributes returns between landlord and tenant from the joint use of their combined resources. 3. It helps to keep landlords and tenants working together as teams, which is necessary in the continued joint use of their combined resources.

Linac4 DTL Prototype: Theoretical Model, Simulation and Low Energy Measurements

A one meter long hot prototype of the LINAC4 DTL, built in a collaboration with INFN Legnaro, was delivered to CERN in 2008. It was then copper plated at CERN is and is presently prepared for high-power testing at the CERN test stand in SM18. In this paper we present 2D/3D simulations and the first RF low-power measurements to verify the electromagnetic properties of the cavity and to tune it before the high-power RF tests. In particular, the influence of the post couplers was studied in order to guarantee stabilization of the accelerating field during operation. We present an equivalent circuit model of the DTL, together with a comparison of 3D simulations and measurement results for the hot model

Capgras-like syndrome in a patient with an acute urinary tract infection.

Delusional misidentification syndromes are a group of delusional phenomena in which patients misidentify familiar persons, objects, or themselves, believing that they have been replaced or transformed. In 25%-40% of cases, misidentification syndromes have been reported in association with organic illness. We report an acute episode of Capgras-like delusion lasting 8 days, focused on the idea that people were robots with human bodies, in association with an acute urinary infection. To our knowledge, this is the first case report associating urinary tract infection with Capgras-like syndrome. Awareness of the prevalence of delusional misidentification syndromes associated with acute medical illness should promote diligence on the part of clinicians in recognizing this disorder

On the return period and design in a multivariate framework

Abstract. Calculating return periods and design quantiles in a multivariate environment is a difficult problem: this paper tries to make the issue clear. First, we outline a possible way to introduce a consistent theoretical framework for the calculation of the return period in a multi-dimensional environment, based on Copulas and the Kendall's measure. Secondly, we introduce several approaches for the identification of suitable design events: these latter quantities are of utmost importance in practical applications, but their calculation is yet limited, due to the lack of an adequate theoretical environment where to embed the problem. Throughout the paper, a case study involving the behavior of a dam is used to illustrate the new concepts outlined in this work

Boosting infrared energy transfer in 3D nanoporous gold antennas

The applications of plasmonics to energy transfer from free-space radiation to molecules are currently limited to the visible region of the electromagnetic spectrum due to the intrinsic optical properties of bulk noble metals that support strong electromagnetic field confinement only close to their plasma frequency in the visible/ultraviolet range. In this work, we show that nanoporous gold can be exploited as a plasmonic material for the mid-infrared region to obtain strong electromagnetic field confinement, co-localized with target molecules into the nanopores and resonant with their vibrational frequency. The effective optical response of the nanoporous metal enables the penetration of optical fields deep into the nanopores, where molecules can be loaded thus achieving a more efficient light–matter coupling if compared to bulk gold. In order to realize plasmonic resonators made of nanoporous gold, we develop a nanofabrication method based on polymeric templates for metal deposition and we obtain antenna arrays resonating at mid-infrared wavelengths selected by design. We then coat the antennas with a thin (3 nm) silica layer acting as the target dielectric layer for optical energy transfer. We study the strength of the light–matter coupling at the vibrational absorption frequency of silica at 1240 cm−1 through the analysis of the experimental Fano lineshape that is benchmarked against identical structures made of bulk gold. The boost in the optical energy transfer from free-space mid-infrared radiation to molecular vibrations in nanoporous 3D nanoantenna arrays can open new application routes for plasmon-enhanced physical–chemical reactions

Infrared dust emission in the outer disk of M51

We examine faint infrared emission features detected in Spitzer Space Telescope images of M51, which are associated with atomic hydrogen in the outer disk and tidal tail at R greater than R_25 (4.9', ~14 kpc at d=9.6 Mpc). The infrared colors of these features are consistent with the colors of dust associated with star formation in the bright disk. However, the star formation efficiency (as a ratio of star formation rate to neutral gas mass) implied in the outer disk is lower than that in the bright disk of M51 by an order of magnitude, assuming a similar relationship between infrared emission and star formation rate in the inner and outer disks.Comment: 13 pages in manuscript form, 2 figures; download PDF of manuscript with original-resolution Figure 1 at http://www.eg.bucknell.edu/physics/thornley/thornleym51.pd