Highly erosive glaciers on Mars - the role of water

International audiencePolewards of 30 • in each hemisphere, the surface of Mars hosts a suite of landforms reminiscent of glacial landscapes on Earth. Amongst these landforms are: 1) Viscous Flow Features (VFF), which resemble glaciers on Earth and are thought to contain large volumes of water ice, 2) martian gullies which are km-scale features resembling water-eroded gullies on Earth and 3) arcuate ridges thought to be moraines from previous glaciations. Gullies have been long-associated with a surface unit originally called "pasted-on terrain" and now often called the "latitude dependant mantle". Arcuate ridges are often found at the base of hillslopes with gullies, but are also found on hillslopes with pasted-on terrain and no gullies. We have found a systematic lowering of the slope of the bedrock exposure located topographically above the pasted-on terrain whether that same slope hosts gullies or not. The lowered bedrock exposures display a different surface texture from bedrock exposed on other parts of the crater wall and from fresh crater walls-it appears fragmented and has reduced relief. Using 1-m-digital elevation models from the High Resolution Imaging Science Experiment (HiRISE) we compared the slopes of eight "eroded" craters and seven unmodified craters. We estimated their age using the crater size-frequency distribution of small craters on their ejecta blankets. From this information we calculated bedrock retreat rates for the eroded craters and found they were up to ∼103 m Myr-1-equivalent to erosion rates of wet-based glaciers on Earth. This is several orders of magnitude higher than previous estimates of erosion by VFF (10-2-101 m Myr-1), which themselves are roughly equivalent to cold-based glaciers on Earth. Such erosion rates are sufficient to erase previously existing landforms, such as martian gullies. We hypothesise, therefore, that the pasted-on terrain is a glacial deposit, overturning its previous interpretation as an airfall deposit of ice nucleated on dust. We maintain the interpretation of the arcuate ridges as moraines, but further conclude that they are likely the result of glaciotectonic deformation of sub-marginal and proglacial sediment in the presence of sediment pore-water. We do not support the generation of large quantities of glacial meltwater because it would have broken-up and degraded the arcuate ridges and pasted-on terrain an produced a suite of landforms (e.g., hummocky moraine, lacustrine forms, outwash plains, eskers) which are not observed

Kondo temperature of magnetic impurities at surfaces

Based on the experimental observation, that only the close vicinity of a magnetic impurity at metal surfaces determines its Kondo behaviour, we introduce a simple model which explains the Kondo temperatures observed for cobalt adatoms at the (111) and (100) surfaces of Cu, Ag, and Au. Excellent agreement between the model and scanning tunneling spectroscopy (STS) experiments is demonstrated. The Kondo temperature is shown to depend on the occupation of the d-level determined by the hybridization between adatom and substrate with a minimum around single occupancy.Comment: 4 pages, 2 figure

Depolarisation cooling of an atomic cloud

We propose a cooling scheme based on depolarisation of a polarised cloud of trapped atoms. Similar to adiabatic demagnetisation, we suggest to use the coupling between the internal spin reservoir of the cloud and the external kinetic reservoir via dipolar relaxation to reduce the temperature of the cloud. By optical pumping one can cool the spin reservoir and force the cooling process. In case of a trapped gas of dipolar chromium atoms, we show that this cooling technique can be performed continuously and used to approach the critical phase space density for BECComment: 8 pages, 5 figure

The uniting of Europe and the foundation of EU studies: revisiting the neofunctionalism of Ernst B. Haas

This article suggests that the neofunctionalist theoretical legacy left by Ernst B. Haas is somewhat richer and more prescient than many contemporary discussants allow. The article develops an argument for routine and detailed re-reading of the corpus of neofunctionalist work (and that of Haas in particular), not only to disabuse contemporary students and scholars of the normally static and stylized reading that discussion of the theory provokes, but also to suggest that the conceptual repertoire of neofunctionalism is able to speak directly to current EU studies and comparative regionalism. Neofunctionalism is situated in its social scientific context before the theory's supposed erroneous reliance on the concept of 'spillover' is discussed critically. A case is then made for viewing Haas's neofunctionalism as a dynamic theory that not only corresponded to established social scientific norms, but did so in ways that were consistent with disciplinary openness and pluralism

Radiation Tolerance of Single-Sided Microstrip Detector with Si3N4Si_{3}N_{4} Insulator

The ALICE Collaboration is investigating the radiation tolerance and operation of silicon microstrip detectors for the inner tracking system. Detectors with and without an additional layer of Si3N4 insulator were made in one set, using the same thickness of SiO2 insulator. Measurements were made on both types of detectors after irradiation with 20 MeV electrons, using doses up to 2Mrad. The additional Si3N4 layer allows a coupling capacitor breakdown voltage larger than 100 V and capacitor yield larger than 99 percent. However, the leakage current for detectors with double layer insulator is about 20 nA per strip while the leakage current for the single layer SiO2 insulated detectors is only 0.5 nA. The 20 nA leakage current leads to 450 electrons noise when the ALICE 128C electronics with a peaking time of 1.4 microseconds is used. At a 1 nA leakage current the noise is 100 electrons. The ENC for an input capacitance of 5 pF is 300 electrons. Since all detectors show an increased leakage current after irradiation, the difference between the single and duoble layer insulation detectors becomes negligible when doses of the order of several hundreds of krad are applied

Valency of rare earths in RIn3 and RSn3: Ab initio analysis of electric-field gradients

In RIn3 and RSn3 the rare earth (R) is trivalent, except for Eu and Yb, which are divalent. This was experimentally determined in 1977 by perturbed angular correlation measurements of the electric-field gradient on a 111Cd impurity. At that time, the data were interpreted using a point charge model, which is now known to be unphysical and unreliable. This makes the valency determination potentially questionable. We revisit these data, and analyze them using ab initio calculations of the electric-field gradient. From these calculations, the physical mechanism that is responsible for the influence of the valency on the electric-field gradient is derived. A generally applicable scheme to interpret electric-field gradients is used, which in a transparent way correlates the size of the field gradient with chemical properties of the system.Comment: 10 page

Function of the fully conserved residues Asp99, Tyr52 and Tyr73 in phospholipase A2

In the active centre of pancreatic phospholipase A2 His48 is at hydrogen-bonding distance to Asp99. This Asp-His couple is assumed to act together with a water molecule as a catalytic triad. Asp99 is also linked via an extended hydrogen bonding system to the side chains of Tyr52 and Tyr73. To probe the function of the fully conserved Asp99, Tyr52 and Tyr73 residues in phospholipase A2, the Asp99 residue was replaced by Asn, and each of the two tyrosines was separately replaced by either a Phe or a Gln. The catalytic and binding properties of the Phe52 and Phe73 mutants did not change significantly relative to the wild-type enzyme. This rules out the possibility that either one of the two Tyr residues in the wild-type enzyme can function as an acyl acceptor or proton donor in catalysis. The Gln73 mutant could not be obtained in any significant amounts probably due to incorrect folding. The Gln52 mutant was isolated in low yield. This mutant showed a large decrease in catalytic activity while its substrate binding was nearly unchanged. The results suggest a structural role rather than a catalytic function of Tyr52 and Tyr73. Substitution of asparagine for aspartate hardly affects the binding constants for both monomeric and micellar substrate analogues. Kinetic characterization revealed that the Asn99 mutant has retained no less than 65% of its enzymatic activity on the monomeric substrate rac 1,2-dihexanoyldithio-propyl-3-phosphocholine, probably due to the fact that during hydrolysis of monomeric substrate by phospholipase A2 proton transfer is not the rate-limiting step. The Asp to Asn substitution decreases the catalytic rate on micellar 1,2-dioctanoyl-sn-glycero-3-phosphocholine 25-fold. To explain this remaining activity we suggest that in the mutant the Asn99 orients His48 in the same way as Asp99 orients His48 in native phospholipase A2 and that the lowered activity is caused by a reduced stabilization of the transition state