Linkage isomerism of nitriles in rhodium half-sandwich metallacycles

A systematic analysis of the linkage isomerism of nitriles in half'sandwichfive-membered rhodacycles is presented for 15 nitriles of the general formula RCN. The hitherto elusive transition states connecting the two isomers have been located using advanced DFT methods

Cyclotrimerization reactions catalyzed by rRhodium(I) half-sandwich complexes: A mechanistic density functional study

We propose and examine a comprehensive mechanism of the [(eta(5)-C5H5)Rh]-catalyzed [2+2+2] cycloadditions of acetylene to benzene and of acetylene and acetonitrile to 2-methylpyridine, based on an extensive and detailed exploration of the potential energy surfaces using density functional theory. Both processes involve the formation of a coordinatively unsaturated 16-electron metallacycle, occurring after the replacement of the ancillary ligands L of the catalyst precursor of general formula [(eta(5)-C5H5)RhL2] (typically L = C2H4, CO, PH3 or L-2 = 1,5-cyclooctadiene) by two acetylene molecules. The facile coordination of a third acetylene molecule, and its subsequent addition to the pi electron system of the rhodacycle, leads to the formation of an intermediate, which is characterized by a six-membered arene ring coordinated to the metal in eta(4) fashion. The release of benzene occurs by stepwise addition of two acetylene molecules, which regenerates the catalyst. In the presence of acetonitrile, a nitrile molecule coordinates to the rhodacycle, and different stages are outlined for the process, leading to the eventual release of 2-methylpyridine. The steric and electronic effects of the pi ligand coordinated to the metal are also included in our exploration by addressing the whole mechanism of the [(eta(5)-C9H7)Rh]-catalyzed alkyne self-trimerization to benzene. The kinetic parameters, i.e., the energies in vacuum and in different solvents, and the geometries of the intermediates and of the transition states are analyzed in detail

Relative prices and inflation: new evidence from different inflationary contexts

This paper analyses the relationship between inflation and relative price variability, in the direction of the latter, in two countries with very different inflationary experiences: Argentina and Spain. To address this objective, using disaggregated price indexes (the Wholesale Price Index for Argentina and the Consumer Price Index for Spain), we delimitate different inflationary regimes and compute a set of regressions for each country. Our results suggest evidence in favour of the non-neutrality of inflation (mostly in hyperinflation periods) and do not support either the menu costs or the signal extraction approaches. We also detect significant structural changes in the relationship depending on the inflationary regime.