15,167 research outputs found
Ultrafast optical control using the Kerr nonlinearity in hydrogenated amorphous silicon microcylindrical resonators
Microresonators are ideal systems for probing nonlinear phenomena at low thresholds due to their small mode volumes and high quality (Q) factors. As such, they have found use both for fundamental studies of light-matter interactions as well as for applications in areas ranging from telecommunications to medicine. In particular, semiconductor-based resonators with large Kerr nonlinearities have great potential for high speed, low power all-optical processing. Here we present experiments to characterize the size of the Kerr induced resonance wavelength shifting in a hydrogenated amorphous silicon resonator and demonstrate its potential for ultrafast all-optical modulation and switching. Large wavelength shifts are observed for low pump powers due to the high nonlinearity of the amorphous silicon material and the strong mode confinement in the microcylindrical resonator. The threshold energy for switching is less than a picojoule, representing a significant step towards advantageous low power silicon-based photonic technologies
Fragmentation pathways of [Re₂(μ-OR)₃(CO)₆]– (R = H, Me) and ligand exchange reactions with oxygen donor ligands, investigated by electrospray mass spectrometry
The rhenium hydroxy and methoxy carbonyl complexes [Re₂(μOR)₃(CO)₆]⁻ (R = H or Me) have been studied by negative-ion electrospray mass spectrometry (ESMS). The complexes undergo facile exchange reactions with protic compounds, including alcohols and phenols. With dimethyl malonate, ester hydrolysis occurs giving carboxylate-containing complexes, and with H₂O₂ or ButOOH, oxidation to ReO₄⁻occurs. The feasibility and extent of these reactions can conveniently, rapidly, and unambiguously be determined by electrospray mass spectrometry, and is dependent on the acidity and steric bulk of the protic compound. The results also suggest that the complexes can be used as versatile starting materials for the synthesis of a wide range of analogous [Re₂(μ-OR)₃(CO)₆]⁻ complexes by simple reaction with an excess of the appropriate alcohol. By varying the applied cone voltage the fragmentation pathways have been investigated; the hydroxy complex undergoes dehydration followed by CO loss, whereas for the methoxy complex -hydride elimination (and CO loss) is observed, with confirmation provided by deuterium labelling studies. Under ESMS conditions, the neutral complexes [Re₂(μ-OR)₂(μ-dppf )(CO)₆] [R = H or Me; dppf = 1,1 -bis(diphenylphosphino)ferrocene] undergo substantial solvolysis and hydrolysis to give mainly mononuclear species; simple parent ions (e.g. [M + H]⁺) are not formed in appreciable abundance, probably due to the lack of an efficient ionisation pathway
From Light Nuclei to Nuclear Matter. The Role of Relativity?
The success of non-relativistic quantum dynamics in accounting for the
binding energies and spectra of light nuclei with masses up to A=10 raises the
question whether the same dynamics applied to infinite nuclear matter agrees
with the empirical saturation properties of large nuclei.The simple unambiguous
relation between few-nucleon and many-nucleon Hamiltonians is directly related
to the Galilean covariance of nonrelativistic dynamics. Relations between the
irreducible unitary representations of the Galilei and Poincare groups indicate
thatthe ``nonrelativistic'' nuclear Hamiltonians may provide sufficiently
accurate approximations to Poincare invariant mass operators. In relativistic
nuclear dynamics based on suitable Lagrangeans the intrinsic nucleon parity is
an explicit, dynamically relevant, degree of freedom and the emphasis is on
properties of nuclear matter. The success of this approach suggests the
question how it might account for the spectral properties of light nuclei.Comment: conference proceedings "The 11th International Conference on Recent
Progress in Many-Body Theories" to be published by World Scientifi
Superconducting On-chip Fourier Transform Spectrometer
The kinetic inductance effect is strongly nonlinear with applied current in NbTiN, TiN and NbN thin films. This can be utilized to realize novel devices. We present results from transmission lines made with these materials, where DC (current) control is used to modulate the phase velocity thereby enabling on-chip spectrometers. Utility of such compact spectrometers is discussed, along with their natural connection with parametric amplifiers
Total scattering descriptions of local and cooperative distortions in the oxide spinel (Mg,Cu)Cr2O4 with dilute Jahn-Teller ions
The normal spinel oxide MgCr2O4 is cubic at room temperature while the normal
spinel CuCr2O4 is tetragonal as a consequence of the Jahn-Teller nature of Cu2+
on the tetrahedral sites. Despite different end-member structures, complete
solid solutions of Mg_{1-x}Cu_xCr2O4 can be prepared that display a first-order
structural transition with composition x = 0.43 at room temperature. Reverse
Monte Carlo analysis of total neutron scattering on data acquired between 300 K
and 15 K on samples with x = 0.10, 0.20, and 0.43 provides unbiased local and
average structure descriptions of the samples, including an understanding of
the transition from local Jahn-Teller distortions in the cubic phase to
cooperative distortions that result in a tetragonal structure. Distributions of
continuous symmetry measures help to understand and distinguish distorted and
undistorted coordination around the tetrahedral site in the solid solutions.
Magnetic exchange bias is observed in field-cooled hysteresis loops of samples
with dilute Cu2+ concentration and in samples with tetragonal--cubic phase
coexistence around 300 K.Comment: 10 pages, 14 figure
Effect of core size on nonlinear transmission in silicon optical fibers
The nonlinear transmission properties of two hydrogenated amorphous silicon fibers with core diameters of 5.7µm and 1.7µm are characterized. The measured Kerr nonlinearity, two-photon absorption and free-carrier parameters will be discussed in relation to device performance
Universality of residence-time distributions in non-adiabatic stochastic resonance
We present mathematically rigorous expressions for the residence-time and
first-passage-time distributions of a periodically forced Brownian particle in
a bistable potential. For a broad range of forcing frequencies and amplitudes,
the distributions are close to periodically modulated exponential ones.
Remarkably, the periodic modulations are governed by universal functions,
depending on a single parameter related to the forcing period. The behaviour of
the distributions and their moments is analysed, in particular in the low- and
high-frequency limits.Comment: 8 pages, 1 figure New version includes distinction between
first-passage-time and residence-time distribution
Thermopower as a Possible Probe of Non-Abelian Quasiparticle Statistics in Fractional Quantum Hall Liquids
We show in this paper that thermopower is enhanced in non-Abelian quantum
Hall liquids under appropriate conditions. This is because thermopower measures
entropy per electron in the clean limit, while the degeneracy and entropy
associated with non-Abelian quasiparticles enhance entropy when they are
present. Thus thermopower can potentially probe non-Abelian nature of the
quasiparticles, and measure their quantum dimension.Comment: 5 pages. Minor revisions in response to referee comments. Published
versio
Towards in-fiber silicon photonics
The state of the art of silicon optical fibers fabricated via the high pressure chemical deposition technique will be reviewed. The optical transmission properties of step index silicon optical fibers will be presented, including investigations of the nonlinearities that can be used for all-optical signal processing. In addition, alternative complex fiber geometries that permit sophisticated control of the propagating light will be introduced
Lattice congruences of the weak order
We study the congruence lattice of the poset of regions of a hyperplane
arrangement, with particular emphasis on the weak order on a finite Coxeter
group. Our starting point is a theorem from a previous paper which gives a
geometric description of the poset of join-irreducibles of the congruence
lattice of the poset of regions in terms of certain polyhedral decompositions
of the hyperplanes. For a finite Coxeter system (W,S) and a subset K of S, let
\eta_K:w \mapsto w_K be the projection onto the parabolic subgroup W_K. We show
that the fibers of \eta_K constitute the smallest lattice congruence with
1\equiv s for every s\in(S-K). We give an algorithm for determining the
congruence lattice of the weak order for any finite Coxeter group and for a
finite Coxeter group of type A or B we define a directed graph on subsets or
signed subsets such that the transitive closure of the directed graph is the
poset of join-irreducibles of the congruence lattice of the weak order.Comment: 26 pages, 4 figure
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