Fast Calculations in Nonlinear Collective Models of Beam/Plasma Physics

We consider an application of variational-wavelet approach to nonlinear collective models of beam/plasma physics: Vlasov/Boltzmann-like reduction from general BBGKY hierachy. We obtain fast convergent multiresolution representations for solutions which allow to consider polynomial and rational type of nonlinearities. The solutions are represented via the multiscale decomposition in nonlinear high-localized eigenmodes (waveletons).Comment: 3 pages, 2 figures, espcrc2.sty, Presented at VIII International Workshop on Advanced Computing and Analysis Techniques in Physics Research, Section III "Simulations and Computations in Theoretical Physics and Phenomenology", ACAT'2002, June 24-28, 2002, Mosco

Organocatalysis for versatile polymer degradation

The use of a simple, cheap and effective organocatalyst, tetramethylammonium methyl carbonate, has been exploited for the transesterification of a range of commercial polymer samples. PLA, PCL, PC and PET have been successfully broken down into useful products, with the repolymerisation of DMT to PET demonstrated, highlighting a truly circular economy approach

Cosmology and Fermion Confinement in a Scalar-Field-Generated Domain Wall Brane in Five Dimensions

We consider a brane generated by a scalar field domain wall configuration in 4+1 dimensions, interpolating, in most cases, between two vacua of the field. We study the cosmology of such a system in the cases where the effective four-dimensional brane metric is de Sitter or anti de Sitter, including a discussion of the bulk coordinate singularities present in the de-Sitter case. We demonstrate that a scalar field kink configuration can support a brane with dS$_4$ cosmology, despite the presence of coordinate singularities in the metric. We examine the trapping of fermion fields on the domain wall for nontrivial brane cosmology.Comment: 29 pages, 12 figures; minor changes, accepted by JHE

Exo-π-bonding to an ortho-carborane hypercarbon atom: systematic icosahedral cage distortions reflected in the structures of the fluoro-, hydroxy- and amino-carboranes, 1-X-2-Ph-1,2-C2B10H10 (X = F, OH or NH2) and related anions

The structures of derivatives of phenyl-ortho-carborane bearing on the second cage hypercarbon atom a pi-donor substituent (F, OH, O-, NH2, NH- and CH2-) were investigated by NMR, X-ray crystallography and computational studies. The molecular structures of these compounds, notably their cage C1-C2 distances and the orientations of their pi-donor substituents (OH, NH2, NH- and CH2-) show remarkable and systematic variations with the degree of exo pi-bonding, which varies as expected with the pi-donor characteristics of the substituent

Bioprospecting the thermal waters of the Roman Baths:Isolation of oleaginous species and analysis of the FAME profile for biodiesel production

The extensive diversity of microalgae provides an opportunity to undertake bioprospecting for species possessing features suited to commercial scale cultivation. The outdoor cultivation of microalgae is subject to extreme temperature fluctuations; temperature tolerant microalgae would help mitigate this problem. The waters of the Roman Baths, which have a temperature range between 39°C and 46°C, were sampled for microalgae. A total of 3 green algae, 1 diatom and 4 cyanobacterial species were successfully isolated into ‘unialgal’ culture. Four isolates were filamentous, which could prove advantageous for low energy dewatering of cultures using filtration. Lipid content, profiles and growth rates of the isolates were examined at temperatures of 20, 30, 40°C, with and without nitrogen starvation and compared against the oil producing green algal species, Chlorella emersonii. Some isolates synthesized high levels of lipids, however, all were most productive at temperatures lower than those of the Roman Baths. The eukaryotic algae accumulated a range of saturated and polyunsaturated FAMEs and all isolates generally showed higher lipid accumulation under nitrogen deficient conditions (Klebsormidium sp. increasing from 1.9% to 16.0% and Hantzschia sp. from 31.9 to 40.5%). The cyanobacteria typically accumulated a narrower range of FAMEs that were mostly saturated, but were capable of accumulating a larger quantity of lipid as a proportion of dry weight (M. laminosus, 37.8% fully saturated FAMEs). The maximum productivity of all the isolates was not determined in the current work and will require further effort to optimise key variables such as light intensity and media composition

Effective Lagrangian Approach to the Theory of Eta Photoproduction in the N∗(1535)N^{*}(1535) Region

We investigate eta photoproduction in the $N^{*}(1535)$ resonance region within the effective Lagrangian approach (ELA), wherein leading contributions to the amplitude at the tree level are taken into account. These include the nucleon Born terms and the leading $t$-channel vector meson exchanges as the non-resonant pieces. In addition, we consider five resonance contributions in the $s$- and $u$- channel; besides the dominant $N^{*}(1535)$, these are: $N^{*}(1440),N^{*}(1520),N^{*}(1650)$ and $N^{*}(1710)$. The amplitudes for the $\pi^\circ$ and the $\eta$ photoproduction near threshold have significant differences, even as they share common contributions, such as those of the nucleon Born terms. Among these differences, the contribution to the $\eta$ photoproduction of the $s$-channel excitation of the $N^{*}(1535)$ is the most significant. We find the off-shell properties of the spin-3/2 resonances to be important in determining the background contributions. Fitting our effective amplitude to the available data base allows us to extract the quantity $\sqrt{\chi \Gamma_\eta} A_{1/2}/\Gamma_T$, characteristic of the photoexcitation of the $N^{*}(1535)$ resonance and its decay into the $\eta$-nucleon channel, of interest to precise tests of hadron models. At the photon point, we determine it to be $(2.2\pm 0.2)\times 10^{-1} GeV^{-1}$ from the old data base, and $(2.2\pm 0.1) \times 10^{-1} GeV^{-1}$ from a combination of old data base and new Bates data. We obtain the helicity amplitude for $N^{*}(1535)\rightarrow \gamma p$ to be $A_{1/2}=(97\pm 7)\times 10^{-3} GeV^{-1/2}$ from the old data base, and $A_{1/2}=(97\pm 6)\times 10^{-3} GeV^{-1/2}$ from the combination of the old data base and new Bates data, compared with the results of the analysis of pion photoproduction yielding $74\pm 11$, in the same units.Comment: 43 pages, RevTeX, 9 figures available upon request, to appear in Phys. Rev.

Aminopiperidine based complexes for lactide polymerisation

A series of new ligands based on a 2-(aminomethyl)piperidine motif have been prepared. An interesting diversity in structure is observed, all complexes have been trialled for the polymerisation of rac-lactide.</p

Baryon number violation, baryogenesis and defects with extra dimensions

In generic models for grand unified theories(GUT), various types of baryon number violating processes are expected when quarks and leptons propagate in the background of GUT strings. On the other hand, in models with large extra dimensions, the baryon number violation in the background of a string is not trivial because it must depend on the mechanism of the proton stabilization. In this paper we argue that cosmic strings in models with extra dimensions can enhance the baryon number violation to a phenomenologically interesting level, if the proton decay is suppressed by the mechanism of localized wavefunctions. We also make some comments on baryogenesis mediated by cosmological defects. We show at least two scenarios will be successful in this direction. One is the scenario of leptogenesis where the required lepton number conversion is mediated by cosmic strings, and the other is the baryogenesis from the decaying cosmological domain wall. Both scenarios are new and have not been discussed in the past.Comment: 20pages, latex2e, comments and references added, to appear in PR

The Weak Charge of the Proton and New Physics

We address the physics implications of a precision determination of the weak charge of the proton, QWP, from a parity violating elastic electron proton scattering experiment to be performed at the Jefferson Laboratory. We present the Standard Model (SM) expression for QWP including one-loop radiative corrections, and discuss in detail the theoretical uncertainties and missing higher order QCD corrections. Owing to a fortuitous cancellation, the value of QWP is suppressed in the SM, making it a unique place to look for physics beyond the SM. Examples include extra neutral gauge bosons, supersymmetry, and leptoquarks. We argue that a QWP measurement will provide an important complement to both high energy collider experiments and other low energy electroweak measurements. The anticipated experimental precision requires the knowledge of the order alpha_s corrections to the pure electroweak box contributions. We compute these contributions for QWP, as well as for the weak charges of heavy elements as determined from atomic parity violation.Comment: 22 pages of LaTeX, 5 figure

A prototype model for evaluating SKA-LOW station calibration

The Square Kilometre Array telescope at low-frequency (SKA-Low) will be a phased array telescope supporting a wide range of science cases covering the frequency band 50 - 350 MHz, while at the same time asking for high sensitivity and excellent characteristics. These extremely challenging requirements resulted in a design using 512 groups of 256 log periodic dual polarized antennas each (where each group is called "station"), for a total of 131072 antennas. The 512 stations are randomly distributed mostly within a dense area around the centre of the SKA-Low, and then in 3 arms having 16 station clusters each. In preparation for the SKA Phase 1 (SKA1) System Critical Design Review (CDR), prototype stations were deployed at the Murchison Radio-astronomy Observatory (MRO) site (Western Australia) near the Murchison Widefield Array (MWA) radio telescope. The project involved multiple parties in an International collaboration building and testing different prototypes of the SKA1-Low station near the actual site. This resulted in both organisational and logistic challenges typical of a deployment of the actual telescope. The test set-up involved a phased build-up of the complex station of log-periodic antennas, by starting from the deployment of 48 antennas and related station signal processing (called AAVS1.5, where AAVS stands for Aperture Array Verification System), followed by expansion to a full station (AAVS2.0). As reference a station with dipole antennas EDA2 (EDA: Engineering Development Array) was deployed. This test set-up was used for an extensive test and evaluation programme. All test antenna configurations were simulated in detail by electromagnetic (EM) models, and the prediction of the models was further verified by appropriate tests with a drone-based radio frequency source. Astronomical observations on Sun and galaxy transit were performed with calibrated stations of both EDA2, AAVS1.5 and AAVS2.0. All 3 configurations were calibrated. EM modelling and calibration results for the full station AAVS2.0 and EM verification for the AAVS1.5 station are presented. The comparisons between the behaviour of the log-periodic antennas and the dipoles have advanced our understanding the calibration quality and the technological maturity of the future SKA1-Low array