Influence of crystal structure on charge carrier effective masses in BiFeO3_3

Ferroelectric-based photovoltaics have shown great promise as a source of renewable energy, thanks to their in-built charge separation capability, yet their efficiency is often limited by low charge carrier mobilities. In this work, we compare the photovoltaic prospects of various phases of the multiferroic material BiFeO$_3$ by evaluating their charge carrier effective masses using first-principles simulations. We identify a tetragonal phase with the promising combination of a large spontaneous polarisation and relatively light charge carriers. From a systematic study of the octahedral distortions present in BiFeO$_3$, we explain the relationship between structure and effective masses in terms of the changes to the orbital character and overlap at the band edges that result from changes in the geometry. The findings in this study provide some design principles to engineer desired effective masses in BiFeO$_3$ and similar materials through manipulation of their crystal structures in experimentally accessible ways.Comment: 12 pages, 10 figure

Roe v. Wade and American Fertility

We consider the effect of abortion legalization on births in the United States. A simple theoretical model demonstrates that the impact of abortion legalization on the birth rate is ambiguous, because both pregnancy and abortion decisions could be affected. We use variation in the timing of legalization across states in the early 1970's to estimate the effect of abortion on birth rates. Our findings indicate that states legalizing abortion experienced a 5% decline in births relative to other states. The decline among teens, women over 35, and nonwhite women was even greater: 13%, 8%, and 12% respectively. Out-of-wedlock births declined by twice as much as births in wedlock. If legalization in some states affected birth rates in neighboring states (through travel to obtain an abortion), comparing births between states will underestimate the actual reduction. Using more distant comparison states increases the estimated impact of abortion legalization on birth rates to about 8%. Applying this estimate to the current level of births, a complete recriminalization of abortion would result in 320,000 additional births per year.

Post-operative atrial fibrillation is influenced by beta-blocker therapy but not by pre-operative atrial cellular electrophysiology

We investigated whether post-cardiac surgery (CS) new-onset atrial fibrillation (AF) is predicted by pre-CS atrial cellular electrophysiology, and whether the antiarrhythmic effect of beta-blocker therapy may involve pre-CS pharmacological remodeling. Atrial myocytes were obtained from consenting patients in sinus rhythm, just prior to CS. Action potentials and ion currents were recorded using whole-cell patch-clamp technique. Post-CS AF occurred in 53 of 212 patients (25%). Those with post-CS AF were older than those without (67 ± 2 vs 62 ± 1 years, P = 0.005). In cells from patients with post-CS AF, the action potential duration at 50% and 90% repolarization, maximum upstroke velocity, and effective refractory period (ERP) were 13 ± 4 ms, 217 ± 16 ms, 185 ± 10 V/s, and 216 ± 14 ms, respectively (n = 30 cells, 11 patients). Peak L-type Ca2+ current, transient outward and inward rectifier K+ currents, and the sustained outward current were −5.0 ± 0.5, 12.9 ± 2.4, −4.1 ± 0.4, and 9.7 ± 1.0 pA/pF, respectively (13-62 cells, 7-19 patients). None of these values were significantly different in cells from patients without post-CS AF (P > 0.05 for each, 60-279 cells, 29-86 patients), confirmed by multiple and logistic regression. In patients treated >7 days with a beta-blocker pre-CS, the incidence of post-CS AF was lower than in non-beta-blocked patients (13% vs 27%, P = 0.038). Pre-CS beta-blockade was associated with a prolonged pre-CS atrial cellular ERP (P = 0.001), by a similar degree (∼20%) in those with and without post-CS AF. Conclusion: Pre-CS human atrial cellular electrophysiology does not predict post-CS AF. Chronic beta-blocker therapy is associated with a reduced incidence of post-CS AF, unrelated to a pre-CS ERP-prolonging effect of this treatment

A New Analysis of the Exoplanet Hosting System HD 6434

The current goal of exoplanetary science is not only focused on detecting but characterizing planetary systems in hopes of understanding how they formed, evolved, and relate to the Solar System. The Transit Ephemeris Refinement and Monitoring Survey (TERMS) combines both radial velocity (RV) and photometric data in order to achieve unprecedented ground-based precision in the fundamental properties of nearby, bright, exoplanet-hosting systems. Here we discuss HD 6434 and its planet, HD 6434b, which has a M_p*sin(i) = 0.44 M_J mass and orbits every 22.0170 days with an eccentricity of 0.146. We have combined previously published RV data with new measurements to derive a predicted transit duration of ~6 hrs, or 0.25 days, and a transit probability of 4%. Additionally, we have photometrically observed the planetary system using both the 0.9m and 1.0m telescopes at the Cerro Tololo Inter-American Observatory, covering 75.4% of the predicted transit window. We reduced the data using the automated TERMS Photometry Pipeline, developed to ensure consistent and accurate results. We determine a dispositive null result for the transit of HD 6434b, excluding the full transit to a depth of 0.9% and grazing transit due to impact parameter limitations to a depth of 1.6%Comment: 9 pages, 5 figures, 3 tables, accepted to A

Molecular characterization of freshwater snails in the genus Bulinus: a role for barcodes?

<p>Abstract</p> <p>Background</p> <p>Reliable and consistent methods are required for the identification and classification of freshwater snails belonging to the genus <it>Bulinus </it>(Gastropoda, Planorbidae) which act as intermediate hosts for schistosomes of both medical and veterinary importance. The current project worked towards two main objectives, the development of a cost effective, simple screening method for the routine identification of <it>Bulinus </it>isolates and the use of resultant sequencing data to produce a model of relationships within the group.</p> <p>Results</p> <p>Phylogenetic analysis of the DNA sequence for a large section (1009 bp) of the mitochondrial gene cytochrome oxidase subunit 1 (<it>cox1</it>) for isolates of <it>Bulinus </it>demonstrated superior resolution over that employing the second internal transcribed spacer <it>(its2</it>) of the ribosomal gene complex. Removal of transitional substitutions within <it>cox1 </it>because of saturation effects still allowed identification of snails at species group level. Within groups, some species could be identified with ease but there were regions where the high degree of molecular diversity meant that clear identification of species was problematic, this was particularly so within the <it>B. africanus </it>group.</p> <p>Conclusion</p> <p>The sequence diversity within <it>cox1 </it>is such that a barcoding approach may offer the best method for characterization of populations and species within the genus from different geographical locations. The study has confirmed the definition of some accepted species within the species groups but additionally has revealed some unrecognized isolates which underlines the need to use molecular markers in addition to more traditional methods of identification. A barcoding approach based on part of the <it>cox1 </it>gene as defined by the Folmer primers is proposed.</p

Roe v. Wade and American Fertility

We consider the effect of abortion legalization on births in the United States. A simple theoretical model demonstrates that the impact of abortion legalization on the birth rate is ambiguous, because both pregnancy and abortion decisions could be affected. We use variation in the timing of legalization across states in the early 1970\u27s to estimate the effect of abortion on birth rates. Our findings indicate that states legalizing abortion experienced a 5% decline in births relative to other states. The decline among teens, women over 35, and nonwhite women was even greater: 13%, 8%, and 12% respectively. Out-of-wedlock births declined by twice as much as births in wedlock. If legalization in some states affected birth rates in neighboring states (through travel to obtain an abortion), comparing births between states will underestimate the actual reduction. Using more distant comparison states increases the estimated impact of abortion legalization on birth rates to about 8%. Applying this estimate to the current level of births, a complete recriminalization of abortion would result in 320,000 additional births per year