HI and OH absorption in the lensing galaxy of MG J0414+0534

We report the detection of \HI 21-cm absorption in the $z=0.96$ early-type lensing galaxy towards MG J0414+0534 with the Green Bank Telescope. The absorption, with total $N_{\rm HI}=1.6 \times 10^{18} (T_{\rm s}/f) {\rm cm}^{-2}$, is resolved into two strong components, probably due to the two strongest lens components, which are separated by 0.4\arcsec. Unlike the other three lenses which have been detected in \HI, J0414+0534 does not exhibit strong OH absorption, giving a OH/\HI column density ratio of N_{\rm OH}/N_{\rm HI}\lapp10^{-6} (for $T_{\rm s}=100$ K, $T_{\rm x}=10$ K and $f_{\rm HI}=f_{\rm OH}=1$). This underabundance of molecular gas may indicate that the extreme optical--near-IR colour ($V-K=10.26$) along the line-of-sight is not due to the lens. We therefore suggest that despite the strong upper limits on molecular absorption at the quasar redshift, as traced by millimetre lines, the extinction occurs primarily in the quasar host galaxy.Comment: Accepted by MNRAS Letters, 5 (and a bit) pages, 5 figure

High-dimensional quantum dynamics of adsorption and desorption of H2_2 at Cu(111)

We performed high-dimensional quantum dynamical calculations of the dissociative adsorption and associative desorption of hydrogen on Cu(111). The potential energy surface (PES) is obtained from density functional theory calculations. Two regimes of dynamics are found, at low energies sticking is determined by the minimum energy barrier, at high energies by the distribution of barrier heights. Experimental results are well-reproduced qualitatively, but some quantitative discrepancies are identified as well.Comment: 4 two column pages, revtex, 4 figures, to appear in Phys. Rev. Let

Elastic and thermodynamic properties of the shape-memory alloy AuZn

The current work reports on the elastic shear moduli, internal friction, and the specific heat of the B2 cubic ordered alloy AuZn as a function of temperature. Measurements were made on single-crystal and polycrystalline samples using Resonant Ultrasound Spectroscopy (RUS), semi-adiabatic calorimetry and stress-strain measurements. Our results confirm that this alloy exhibits the shape-memory effect and a phase transition at 64.75 K that appears to be continuous (second-order) from the specific heat data. It is argued that the combination of equiatomic composition and a low transformation temperature constrain the chemical potential and its derivatives to exhibit behavior that lies at the borderline between that of a first-order (discontinuous) and a continuous phase transition. The acoustic dissipation does not peak at the transtion temperature as expected, but shows a maximum well into the low-temperature phase. The Debye temeprature value of 219 K, obtained from the low-temperature specific heat data is in favorable agreement with that determined from the acoustic data (207 K) above the transition.Comment: 25 pages, 6 figures, submitted to Phys. Rev.

You and Your Neighbor

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A Laboratory for Constraining Cosmic Evolution of the Fine Structure Constant: Conjugate 18 cm OH Lines Toward PKS 1413+135 at z=0.2467

We report the detection of the satellite 18 cm OH lines at 1612 and 1720 MHz in the z=0.2467 molecular absorption system toward the radio source PKS 1413+135. The two OH lines are conjugate; the 1612 MHz line is seen in absorption while the 1720 MHz line is seen in weak maser emission of equal, but negative, optical depth. We do not detect the main 18 cm OH lines at 1667 and 1665 MHz down to 1.1 mJy rms in 4.0 km/s channels. The detected and undetected 18 cm OH lines support a scenario of radiatively pumped stimulated absorption and emission with pumping dominated by the intraladder 119 micron line of OH, suggesting a column density N(OH) ~= 10^15 to 10^16 cm^-2. Combined with simultaneous HI 21 cm observations and published CO data, we apply the OH redshifts to measurements of cosmic evolution of the fine structure constant alpha = e^2/(hbar c). We obtain highly significant (~25 sigma) velocity offsets between the OH and HI lines and the OH and CO lines, but measurements of alpha-independent systematics demonstrate that the observed velocity differences are entirely attributable to physical velocity offsets between species rather than a change in alpha. The OH alone, in which conjugate line profiles guarantee that both lines originate in the same molecular gas, provides a weak constraint of Delta alpha/alpha_o = (+0.51 +/- 1.26) x 10^-5 at z=0.2467. Higher frequency OH line detections can provide a larger lever arm on Delta alpha and can increase precision by an order of magnitude. The OH molecule can thus provide precise measurements of the cosmic evolution of alpha that include quantitative constraints on systematic errors. Application of this technique is limited only by the detectability of |tau|~0.01 OH lines toward radio continuum sources and may be possible to z~5.Comment: AASTeX, 11 pages, 2 figures, accepted by Astrophysical Journa

Volume contraction at the Jahn-Teller transition of LaMnO3_3

We have studied the volume collapse of LaMnO$_3$ at the Jahn- Teller (JT) transition temperature T$_{JT}$=750 K which has recently been found in high temperature powder x- ray and neutron diffraction experiments. We construct a model Hamiltonian involving the pseudospin of Mn$^{3+}$ e$_g$ states, the staggered JT distortion and the volume strain coordinate. We show that the anharmonic coupling between these primary and secondary order parameters leads to the first order JT phase transition associated with a comparatively large reduction of the unit cell volume of $\Delta$V/V$\simeq$ 10$^{-2}$. We explain the temperature dependence of JT distortions and volume strain and discuss the volume change as function of the anharmonic coupling constant. A continuous change to a second order transition as function of model parameters is obtained. This behaviour is also observed under Ba doping.Comment: 5 pages, 4 figure