Groundwater Contamination in Karst Areas of Southwestern China and Recommended Countermeasures

Approximately 33% of China is karstic. The most extensive karst areas are in southwestern China and cover approximate­ly 540,000 km2. Southwestern China hosts some of the most typical karst landforms in the world and has important high-quality karst water resources. Due to the rapid development of China, karst waters are threatened by various types of con­tamination. Detail field and laboratory investigations in five provinces including several cities in southwestern China were conducted in 2008 and 2009. Eighty-three springs and under­ground rivers were surveyed and water samples collected from eachfor laboratory analyses for major ions. Four main types of karst aquifer contamination were identified based on con­taminant sources: rural and agricultural pollution, pollution from urban development and industry, pollution from mining, and accidental groundwater pollution. Several representative instances for eachtype of contamination and their impacts on the environment are discussed in more detail. Contamination countermeasures of karst waters and a framework for overall management of karst water resources in southwestern China are provided

Vertical migration from surface soils to groundwater and source appointment of polycyclic aromatic hydrocarbons in epikarst spring systems, southwest China

Understanding the transfer process of polycyclic aromatic hydrocarbons (PAHs) in the karst terrain is of great importance to their ecological risk assessments, however, the impact of the vertical transfer of the soil PAHs on the underground water is largely unknown in the karst system. Here, the vertical distribution and the seasonal variation of 16 PAHs in the soils and the water of 4 epikarst spring catchments in Southwest China were investigated. The total concentration of the PAHs ranged within 61-3285 ng g in the soils, and 341-4969 ng L in the spring water. The vertical distribution of the PAHs in soils varied with ring numbers and altitude of the catchment. PAHs concentrations were linearly related with the total organic carbon (TOC) at different depths in the catchments 563-783 m above the sea level (A.S.L.). However, no correlation with TOC was observed in the catchment of a high altitude (2090 m A.S.L.), because the large water flux led to the fast migration of the 2-3 rings PAHs in soils. The PAHs in soils and springs were mainly derived from the combustion of grass/wood/coal, closely related with the primary fossil fuels used in this area. This study demonstrate that the groundwater was heavily polluted by PAHs in the karst terrains of Southwest China, due to the vertical transfer of PAHs from the surface soils, and effective protection was urgently needed

Characteristics and ecological risk assessment of polycyclic aromatic hydrocarbons in soil seepage water in karst terrains, southwest China

Concentrations of polycyclic aromatic hydrocarbons (PAHs) in soils and soil seepage waters were analyzed along with dissolved organic carbon (DOC) to investigate the ecological risks and factors controlling the subsurface transport of PAHs in karst terrain in southwest China. The concentrations of dissolved PAHs in soil seepage water increased with depth and the mean concentrations at a depth of 80 cm were relatively high (exceeding 1147 ng/L). PAH composition in soil seepage water was dominated by low molecular weight (LMW) PAHs, whereas those associated with soil matrix were dominated by high molecular weight (HMW) PAHs. The results revealed that HMW PAHs in soil seepage water were closer to the equilibrium of dissolution than LMW and medium molecular weight (MMW) PAHs. However, due to the carrier functions of dissolved organic matter (DOM) for HMW PAHs, all PAHs can be continuously dissolved in the soil seepage water from soil matrix as the water moved vertical downward through the profiles. During this process, dynamic sorption and desorption processes were occurring between constituents in the soil seepage water and the soil matrix. This study demonstrates soil seepage water has posed a high risk to the groundwater, and effective protection is urgently needed