Characterization of Metal-Insulator-Transition (MIT) Phase Change Materials (PCM) for Reconfigurable Components, Circuits, and Systems

Many microelectromechanical systems (MEMS) use metal contact micro-switches as part of their reconfigurable device design. These devices utilize a mechanical component that can wear down and fail over time. Metal insulator transition (MIT) materials, also known as phase change materials (PCMs), exhibit a reversible transition that can be used to replace the mechanical component in reconfigurable devices. In the presence of a thermal or electric field stimuli, the PCMs will transition back and forth between a crystalline and amorphous state. During this transformation, the resistivity, reflectivity, and Young\u27s modulus of the material drastically change. This research effort focuses on characterizing the stimuli required to transition germanium telluride (GeTe) and vanadium oxide (VOx). To do this, test structures were designed and microfabricated in AFIT\u27s class 1000 cleanroom. The resistivity of the GeTe films underwent a volatile transition from 1.4E3Ohm-cm down to 2.28Ohm-cm and a nonvolatile transition from 1.4E3Ohm-cm to 2.43E-3Ohm-cm when a thermal stimulus was applied. The reflectivity of the film also changed significantly when crystallized, increasing over 30%. Lastly, the Young\u27s modulus was measured and showed a 28% change during crystallization. After the materials were characterized, reconfigurable devices were designed to utilize the phase change properties of the PCMs

Characterizing Metal-Insulator-Transition (MIT) Phase Change Materials (PCM) for RF and DC Micro-switching Elements

Metal-insulator transition (MIT) phase-change materials (PCM) are material compounds that have the ability to be either conductors or insulators depending on external stimuli. A micromachined test structure for applying external electric fields across MIT wire segments was designed and fabricated. Using this novel test structure, Germanium Telluride (GeTe) and Vanadium Oxide (VOx) were successfully transitioned from a conductor to an insulator. The resistivity of the GeTe wire segments increased three to five orders of magnitude with ∼40 V applied to the parallel plates of the test structure. The VOx wires exhibited an order of magnitude transition in resistivity with ∼20 V applied. Characterization of both RF and DC switching performance of these MIT wire segments was completed and GeTe and VOx appear to be viable materials for micro-switching

The Effect of Foreign Direct Investment and Rule of Law on Economic Growth

Thesis advisor: Robert G. MurphyRule of law has recently emerged as a possible solution for the promotion of functioning market economies and economic growth in developing countries. It has been argued that an established legal system provides individuals with a clear understanding of the law and consequently, should be more influential on the behavior and decisions of those individuals. This study explores the effects of an established rule of law environment on the relationship between foreign direct investment and economic growth. Several previous studies have analyzed the direct relationship between foreign investment and economic growth. However, none of these studies control for varying levels of legal incentives and property protection. Established legal institutions provide the type of stability that makes investment in a given country more attractive to foreign companies. I also test whether the combination of rule of law and FDI affect the estimated rate of GDP growth. The combination of these two effects would imply that FDI is more likely to create positive economic growth when applied to an economy with established legal institutions. Although the analysis does not fully support the effect of this rule of law—FDI interaction on growth, my analysis does suggest that FDI inflows are most efficient at promoting growth in countries with less legal development.Thesis (BA) — Boston College, 2008.Submitted to: Boston College. College of Arts and Sciences.Discipline: Economics.Discipline: College Honors Program.Discipline: Economics Honors Program

Liquid Crystal-Solid Interface Structure at the Antiferroelectric-Ferroelectric Phase Transition

Total Internal Reflection (TIR) is used to probe the molecular organization at the surface of a tilted chiral smectic liquid crystal at temperatures in the vicinity of the bulk antiferroelectric-ferroelectric phase transition. Data are interpreted using an exact analytical solution of a real model for ferroelectric order at the surface. In the mixture T3, ferroelectric surface order is expelled with the bulk ferroelectric-antiferroelectric transition. The conditions for ferroelectric order at the surface of an antiferroelectric bulk are presented

An Introduced Predator Alters Aleutian Island Plant Communities by Thwarting Nutrient Subsidies

The ramifying effects of top predators on food webs traditionally have been studied within the framework of trophic cascades. Trophic cascades are compelling because they embody powerful indirect effects of predators on primary production. Although less studied, indirect effects of predators may occur via routes that are not exclusively trophic. We quantified how the introduction of foxes onto the Aleutian Islands transformed plant communities by reducing abundant seabird populations, thereby disrupting nutrient subsidies vectored by seabirds from sea to land. We compared soil and plant fertility, plant biomass and community composition, and stable isotopes of nitrogen in soil, plants, and other organisms on nine fox-infested and nine historically fox-free islands across the Aleutians. Additionally, we experimentally augmented nutrients on a fox-infested island to test whether differences in plant productivity and composition between fox-infested and fox-free islands could have arisen from differences in nutrient inputs between island types. Islands with historical fox infestations had soils low in phosphorus and nitrogen and plants low in tissue nitrogen. Soils, plants, slugs, flies, spiders, and bird droppings on these islands had low δ15N values indicating that these organisms obtained nitrogen from internally derived sources. In contrast, soils, plants, and higher trophic level organisms on fox-free islands had elevated δ15N signatures indicating that they utilized nutrients derived from the marine environment. Furthermore, soil phosphorus (but not nitrogen) and plant tissue nitrogen were higher on fox-free than fox-infested islands. Nutrient subsidized fox-free islands supported lush, high biomass plant communities dominated by graminoids. Fox-infested islands were less graminoid dominated and had higher cover and biomass of low-lying forbs and dwarf shrubs. While δ15N profiles of soils and plants and graminoid biomass varied with island size and distance from shore, after accounting for these effects differences between fox-infested and fox-free islands still existed. Fertilization over four years caused a 24-fold increase in graminoid biomass and a shift toward a more graminoid dominated plant community typical of fox-free islands. These results indicate that apex predators can influence plant productivity and composition through complex interaction web pathways involving both top-down forcing and bottom-up nutrient exchanges across systems. Read More: http://www.esajournals.org/doi/abs/10.1890/05-049

HST Observations of SGR 0526-66: New Constraints on Accretion and Magnetar Models

Soft Gamma-ray Repeaters (SGRs) are among the most enigmatic sources known today. Exhibiting huge X- and Gamma-ray bursts and flares, as well as soft quiescent X-ray emission, their energy source remains a mystery. Just as mysterious are the Anomalous X-ray pulsars (AXPs), which share many of the same characteristics. Thanks to recent Chandra observations, SGR 0526-66, the first SGR, now appears to be a transition object bridging the two classes, and therefore observations of it have implications for both SGRs and AXPs. The two most popular current models for their persistent emission are accretion of a fossil disk or decay of an enormous (~10^15 G) magnetic field in a magnetar. We show how deep optical observations of SGR 0526-66, the only SGR with small enough optical extinction for meaningful observations, show no evidence of an optical counterpart. These observation place strong new constraints on both accretion disk and magnetar models, and suggest that the spectral energy distribution may peak in the hard-UV. Almost all accretion disks are excluded by the optical data, and a magnetar would require a ~10^15-10^16 G field.Comment: 23 pages, 5 figures. Accepted by Ap

BeppoSAX observation of PSR B1937+21

We present the results of a BeppoSAX observation of the fastest rotating pulsar known: PSR B1937+21. The ~200 ks observation (78.5 ks MECS/34 ks LECS on-source time) allowed us to investigate with high statistical significance both the spectral properties and the pulse profile shape. The pulse profile is clearly double peaked at energies > ~4 keV. Peak widths are compatible with the instrumental time resolution and the second pulse lags the main pulse 0.52 in phase, like is the case in the radio. In the 1.3-4 keV band we detect a ~45% DC component; conversely the 4-10 keV pulsed fraction is consistent with 100%. The on-pulse spectrum is fitted with an absorbed power-law of spectral index ~1.2, harder than that of the total flux which is ~1.9. The total unabsorbed (2-10 keV) flux is F_{2-10} = 4.1 10^-13 cgs, implying a luminosity of L_X = 5.0 10^31 \Theta (d/3.6 kpc)^2 erg s^-1 and a X-ray efficiency of \eta = 4.5 10^-5 \Theta, where \Theta is the solid angle spanned by the emission beam. These results are in agreement with those obtained by ASCA and a more recent Rossi-XTE observation. The hydrogen column density N_H ~2 10^22 cm^-2 is ~10 times higher than expected from the radio dispersion measure and average Galactic density of e-. Though it is compatible (within 2\sigma) with the Galactic (HI derived) value of ~1 10^22 cm^-2, inspection of dust extinction maps reveal that the pulsar falls in a highly absorbed region. In addition, 1.4 GHz radio map shows that the nearby (likely unrelated) HII source 4C21.53W is part of a circular emission region ~4' across.Comment: 8 pages, 5 figures; accepted for publication in A&