Preface

When the Soviet Union broke apart in 1991, the Russian Federation and the newly independent republics of the Baltics, the Caucasus and Central Asia engaged in redefining their national identity in a challenging regional and global context. The stances and policies towards the minorities living in these countries became part of the striving towards national independence and identity formation. Despite vastly different post-Soviet nation-building trajectories, the development and implementation of state policies towards minorities had similar relevance and importance across the region. Thirty years after the end of the USSR what is the situation of minorities and minority issues in the countries that emerged from that multi-ethnic state? How have the former republics – including Russia dealt with their minorities and minority affairs? To what protection and rights are minority communities entitled to? Studies of the dissolution of the USSR and of nation-building in the independent post-Soviet states have flourished over the past decades. However, despite the relevance of the theme, there is a dearth of specialist publications which address the many issues related to minority communities in the post-Soviet space. This volume attempts to fill this gap by providing a collection of essays covering some of the most relevant aspects of the contemporary status and situation of minorities in the area

A Combined Experimental and Theoretical Study on the Stereodynamics of Monoaza[5]helicenes: Solvent-Induced Increase of the Enantiomerization Barrier in 1-Aza-[5]helicene

Helicenes and heterohelicenes are attractive compounds with great potential in materials sciences to be used in optoelectronics as ligand backbones in enantioselective catalysis and as chiral sensors.[1] Synthetic protocols were developed to obtain helicenes with skeletons consisting of ortho-fused benzene rings or analogue structures incorporating a heteroatom, as in thiophene-, furane-, or pyridine-containing helicenes.[2] In recent years, a repertoire of synthetic strategies was developed to access all monoaza[5]helicenes as well as some diaza[ 5]helicenes.[3] The properties of these materials are related to the stereodynamics of these helical chiral compounds. By exploration of the unexpected broad range of physicochemical properties of aza[n]helicenes it was realized that there is an opportunity to modulate a specific property by controlled design of the position of the N atoms in the helical molecular frame. In this contribution, we show a complete stereodynamic characterization of monoaza[5]-helicenes combining enantioselective dynamic HPLC and DFT calculations. At variance with previous theoretical calculations[4], 1-aza[5]helicene shows a surprisingly high enantiomerization barrier, which is triggered by specific solvent interactions. [5] References [1] a) H. A. Staab, M. A. Zirnstein, C. Krieger, Angew. Chem. Int. Ed. Engl. 1989, 28, 86–88; Angew. Chem. 1989, 101, 73– 75;b) T. R. Kelly, Acc. Chem. Res. 2001, 34, 514 –522; c) T. J. Wigglesworth, D. Sud, T. B. Norsten, V. S. Lekhi, N. R. Branda, J. Am. Chem. Soc. 2005, 127, 7272 – 7273; d) L. Vyklicky´, S. H. Eichhorn, T. J. Katz, Chem. Mater. 2003, 15, 3594 –3601; e) M. Gingras, Chem. Soc. Rev. 2013, 42, 1051– 1095. [2] a) M. Gingras, Chem. Soc. Rev. 2013, 42, 968–1006; b) M. Gingras, G. F_lix, R. Peresutti, Chem. Soc. Rev. 2013, 42, 1007 –1050; c) Y. Shen, C.-F. Chen, Chem. Rev. 2012, 112, 1463– 1535. [3] a) C. Bazzini, S. Brovelli, T. Caronna, C. Gambarotti, M. Giannone, P. Macchi, F. Meinardi, A. Mele, W. Panzeri, F. Recupero, A. Sironi, Eur. J. Org. Chem. 2005, 1247 – 1257; b) S. Abbate, C. Bazzini, T. Caronna, F. Fontana, C. Gambarotti, F. Gangemi, G. Longhi, A. Mele, I. Natali Sora, W. Panzeri, Tetrahedron 2006, 62,139 –148; c) T. Caronna, F. Fontana, A. Mele, I. Natali Sora, W. Panzeri, L. Vigan_, Synthesis 2008, 413– 416; d) T. Caronna, S. Gabbiadini, A. Mele, F. Recupero, Helv. Chim. Acta 2002, 85, 1 –8; e) T. Caronna, F. Castiglione, F. Fontana, D. Mendola, I. Natali Sora, Molecules 2012, 17, 463 –479. [4] S. Abbate, C. Bazzini, T. Caronna, F. Fontana, F. Gangemi, F. Lebon, G. Longhi, A. Mele, I. Natali Sora, Inorg. Chim. Acta 2007, 360, 908 –912. [5] T. Caronna, A. Mele, A. Famulari, D. Mendola, F. Fontana, M. Juza, M. Kamuf, K. Zawatzky, and O. Trapp, Chem. Eur. J. 2015, 21, 1–7

Minorities in the Post-Soviet Space Thirty Years After the Dissolution of the USSR

When the Soviet Union broke apart in 1991, the Russian Federation and the newly independent republics of the Baltics, the Caucasus and Central Asia engaged in redefining their national identity in a challenging regional and global context. The stances and policies towards the minorities living in these countries became part of the striving towards national independence and identity formation. Despite vastly different post-Soviet nation-building trajectories, the development and implementation of state policies towards minorities had similar relevance and importance across the region. Thirty years after the end of the USSR what is the situation of minorities and minority issues in the countries that emerged from that multi-ethnic state? How have the former republics – including Russia dealt with their minorities and minority affairs? To what protection and rights are minority communities entitled to? Studies of the dissolution of the USSR and of nation-building in the independent post-Soviet states have flourished over the past decades. However, despite the relevance of the theme, there is a dearth of specialist publications which address the many issues related to minority communities in the post-Soviet space. This volume attempts to fill this gap by providing a collection of essays covering some of the most relevant aspects of the contemporary status and situation of minorities in the area

Development of Methodologies and Tools—The HKKH Partnership Project

High mountains have sensitive social-ecological systems (SESs) characterized by fragility, complexity, and marginality. The local economies of these environments mainly rely on primary production, tourism, and leisure activities; thus human-ecosystem interactions are intricately linked. Many authors stress that this strict relationship must be assisted with a participatory approach involving interested stakeholders in the conceptualization, specification, and synthesis of knowledge and experience into useable information for the express purpose of addressing a problem complex. This paper presents experience garnered with a participatory modeling framework combining hard and soft methodology in 2 case studies: the Sagarmatha National Park and Buffer Zone (Nepal) and the Central Karakoram National Park (Pakistan). The modeling framework was developed based on local stakeholders' demands and needs; it consists of 5 modules, briefly presented here along with their conceptual background. In developing the framework, particular emphasis was given to considering the needs of decision-makers at the local level, rather than simply providing technical solutions to abstract problems. From the development of this modeling process, a need emerged to structure a management-oriented research module in order to generate management knowledge that is both stakeholderrelevant and evidence-based. The application of the framework in the 2 cases studies showed that the modeling can trigger valuable discussion among stakeholders as well as guidance for management-oriented research and feedback loops ensuring validation of knowledge. In addition, the resulting scenarios can help decision-makers in defining pathways for sustainable development in mountain areas, where people's livelihoods are closely dependent on ecosystems. The framework was developed in such a way that it can be replicated in other mountain areas with similar challenges

Experience With a Hard and Soft Participatory Modeling Framework for Social-ecological System Management in Mount Everest (Nepal) and K2 (Pakistan) Protected Areas

High mountains have sensitive social-ecological systems (SESs) characterized by fragility, complexity, and marginality. The local economies of these environments mainly rely on primary production, tourism, and leisure activities; thus human-ecosystem interactions are intricately linked. Many authors stress that this strict relationship must be assisted with a participatory approach involving interested stakeholders in the conceptualization, specification, and synthesis of knowledge and experience into useable information for the express purpose of addressing a problem complex. This paper presents experience garnered with a participatory modeling framework combining hard and soft methodology in 2 case studies: the Sagarmatha National Park and Buffer Zone (Nepal) and the Central Karakoram National Park (Pakistan). The modeling framework was developed based on local stakeholders' demands and needs; it consists of 5 modules, briefly presented here along with their conceptual background. In developing the framework, particular emphasis was given to considering the needs of decision-makers at the local level, rather than simply providing technical solutions to abstract problems. From the development of this modeling process, a need emerged to structure a management-oriented research module in order to generate management knowledge that is both stakeholder-relevant and evidence-based. The application of the framework in the 2 cases studies showed that the modeling can trigger valuable discussion among stakeholders as well as guidance for management-oriented research and feedback loops ensuring validation of knowledge. In addition, the resulting scenarios can help decision-makers in defining pathways for sustainable development in mountain areas, where people's livelihoods are closely dependent on ecosystems. The framework was developed in such a way that it can be replicated in other mountain areas with similar challenges

MRI versus mammography plus ultrasound in women at intermediate breast cancer risk: study design and protocol of the MRIB multicenter, randomized, controlled trial

In women at high/intermediate lifetime risk of breast cancer (BC-LTR), contrast-enhanced magnetic resonance imaging (MRI) added to mammography ± ultrasound (MX ± US) increases sensitivity but decreases specificity. Screening with MRI alone is an alternative and potentially more cost-effective strategy. Here, we describe the study protocol and the characteristics of enrolled patients for MRIB feasibility, multicenter, randomized, controlled trial, which aims to compare MRI alone versus MX+US in women at intermediate breast cancer risk (aged 40-59, with a 15-30% BC-LTR and/or extremely dense breasts). Two screening rounds per woman were planned in ten centers experienced in MRI screening, the primary endpoint being the rate of cancers detected in the 2 arms after 5 years of follow-up. From July 2013 to November 2015, 1254 women (mean age 47 years) were enrolled: 624 were assigned to MX+US and 630 to MRI. Most of them were aged below 50 (72%) and premenopausal (45%), and 52% used oral contraceptives. Among postmenopausal women, 15% had used hormone replacement therapy. Breast and/or ovarian cancer in mothers and/or sisters were reported by 37% of enrolled women, 79% had extremely dense breasts, and 41% had a 15-30% BC-LTR. The distribution of the major determinants of breast cancer risk profiles (breast density and family history of breast and ovarian cancer) of enrolled women varied across centers

Le nuove minoranze in Lombardia

Il volume ha come obiettivo non solo di far conoscere l\u2019ampia e variegata realt\ue0 delle nuove minoranze residenti in Lombardia, ma anche di illustrare gli orientamenti delle scienze linguistiche, pedagogico-didattiche, religiose e giuridiche nelle ricerche sui fe\uacnomeni migratori e sull\u2019integrazione dei migranti. L\u2019approccio metodologico \ue8 quindi interdisciplinare, perch\ue9 trae beneficio da contributi che vanno dalla sociolinguistica alla glottodidattica, dalla pedagogia alla legislazione sulle minoranze. In questa prospettiva, il volume si propone di approfondire le problematiche di un tema complessivamente ancora poco studiato ma che offre un grande potenziale per trasformare la nostra comprensione sul ruolo che le comunit\ue0 migranti svolgono nella societ\ue0 italiana e, in particolare, nel contesto lombardo

Le nuove minoranze in Lombardia

Il volume ha come obiettivo non solo di far conoscere l\u2019ampia e variegata realt\ue0 delle nuove minoranze residenti in Lombardia, ma anche di illustrare gli orientamenti delle scienze linguistiche, pedagogico-didattiche, religiose e giuridiche nelle ricerche sui fe\uacnomeni migratori e sull\u2019integrazione dei migranti. L\u2019approccio metodologico \ue8 quindi interdisciplinare, perch\ue9 trae beneficio da contributi che vanno dalla sociolinguistica alla glottodidattica, dalla pedagogia alla legislazione sulle minoranze. In questa pro-spettiva, il volume si propone di approfondire le problematiche di un tema complessivamente ancora poco studiato ma che offre un grande potenziale per trasformare la nostra comprensione sul ruolo che le comunit\ue0 migranti svolgono nella societ\ue0 italiana e, in particolare, nel contesto lombardo

Chronicle of the International Conference "Minorities in the post-Soviet Space thirty years after the dissolution of USSR"

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